公开(公告)号：US08785362B2

公开(公告)日：2014-07-22

申请号：US13430769

申请日：2012-03-27

申请人： Josef Penninger ,  Birgit Glüsen

发明人： Josef Penninger ,  Birgit Glüsen

IPC分类号： C11D3/00

CPC分类号： C11D3/349 ,  C11D3/0021

摘要： Washing products comprising a dye transfer inhibitor selected from triazine derivatives of the general formulae T(NH—Ar(SO3Na)a)bHalc (I), X(NH-T(NH—Ar(SO3Na)a)eHalf)2 (II), X(NH-T(NH—Ar(SO3Na)d—NH-T(NH—Ar(SO3Na)a)Hal)Hal)7 (III) and combinations thereof, wherein T represents a 1,3,5-triazinyl; each Ar independently represents a naphthalene or benzene; X represents a divalent hydrocarbyl selected from linear or branched C1-20 hydrocarbon groups optionally including one or more —N(H)— carbon chain interruptions, stilbene and biphenyl groups which may optionally be mono- or poly-SO3Na-substituted; each Hal independently represents a halogen selected chlorine, bromine, and iodine; each of a and d independently represents 1, 2 or 3; b and c each represent 1 or 2 such that b+c=3; e represents 1 or 2 and f represents 0 or 1 such that e+f=2; and wherein the triazinyl substituents are located at the 2, 4 and 6 positions of the 1,3,5-triazinyl.

摘要翻译： 洗涤产物，其包含选自通式T（NH-Ar（SO 3 Na）a）b Halc（I），X（NH-T（NH-Ar（SO 3 Na）a）eHalf）2（II）的三嗪衍生物的染料转移抑制剂 ，X（NH-T（NH-Ar（SO 3 Na）d -NH-T（NH-Ar（SO 3 Na）a）Hal）Hal）7（III）及其组合，其中T表示1,3,5-三嗪基 ; 每个Ar独立地表示萘或苯; X表示选自直链或支链C 1-20烃基的二价烃基，任选地包括一个或多个-N（H） - 碳链中断，二苯乙烯和联苯基团，其可任选地被单或多SO 3 N 3取代; 每个Hal独立地表示卤素选择的氯，溴和碘; a和d各自独立地表示1,2或3; b和c各自表示1或2，使得b + c = 3; e表示1或2，f表示0或1，使e + f = 2; 并且其中三嗪基取代基位于1,3,5-三嗪基的2,4和6位。

公开(公告)号：US08263541B2

公开(公告)日：2012-09-11

申请号：US12064107

申请日：2006-08-05

申请人： Josef Penninger ,  Birgit Gluesen

发明人： Josef Penninger ,  Birgit Gluesen

IPC分类号： C11D3/37 ,  C11D7/18 ,  C11D3/00 ,  D06L1/04

CPC分类号： C11D3/349 ,  C11D3/0021

摘要： Washing products which comprise a dye transfer inhibitor selected from the group consisting of triazine derivatives of the general formulae I, II, III and combinations thereof: T(NH—Ar(SO3Na)a)bHalc  (I) X(NH-T(NH—Ar(SO3Na)a)eHalf)2  (II) X(NH-T(NH—Ar(SO3Na)d—NH-T(NH—Ar(SO3Na)a)Hal)Hal)2  (III) wherein T represents a 1,3,5-triazinyl residue; each Ar independently represents a naphthalene or benzene moiety; X represents a divalent hydrocarbyl moiety selected from the group consisting of linear or branched C1-20 hydrocarbon groups which may optionally include one or more —N(H)— carbon chain interruptions, stilbene groups and biphenyl groups which may optionally be mono- or poly-SO3Na-substituted; each Hal independently represents a halogen selected from the group consisting of chlorine, bromine, and iodine; each of a and d independently represents 1, 2 or 3; b and c each represent 1 or 2 such that b+c=3; e represents 1 or 2 and f represents 0 or 1 such that e+f=2; and wherein the triazinyl residue substituents are located at the 2, 4 and 6 positions of the 1,3,5-triazinyl residue.

摘要翻译： 包含选自通式I，II，III的三嗪衍生物及其组合的染料转移抑制剂的洗涤产品：T（NH-Ar（SO 3 Na）a）b氢化（I）X（NH-T（NH -Ar（SO3Na）a）eHalf）2（II）X（NH-T（NH-Ar（SO3Na）d-NH-T（NH-Ar（SO3Na）a）Hal）Hal）2（III）其中T表示 1,3,5-三嗪基残基; 每个Ar独立地表示萘或苯部分; X表示选自直链或支链C 1-20烃基的二价烃基部分，其可以任选地包括一个或多个-N（H） - 碳链中断，二苯乙烯基团和联苯基团，其可任选地是单或多 -SO 3 Na-取代的 每个Hal独立地表示选自氯，溴和碘的卤素; a和d各自独立地表示1,2或3; b和c各自表示1或2，使得b + c = 3; e表示1或2，f表示0或1，使e + f = 2; 并且其中三嗪基残基取代基位于1,3,5-三嗪基残基的2,4和6位。

公开(公告)号：US20090069210A1

公开(公告)日：2009-03-12

申请号：US12282610

申请日：2007-02-08

申请人： Josef Penninger ,  Birgit Glusen

发明人： Josef Penninger ,  Birgit Glusen

IPC分类号： C11D3/28

CPC分类号： C11D3/28 ,  C11D3/0021

摘要： Detergent compositions comprising a color transfer inhibitor and optionally surfactant(s), the color transfer inhibitor comprising one or more compounds selected from the group consisting of triazine derivatives corresponding to general formulae I and II: T(NH—Ar(CO2M)a)bHalc  (I) X—NH—CH2CH2—(NY—CH2CH2—)nNH—X  (II) wherein T represents a 1,3,5-triazinyl group; Ar represents a phenyl group; each M independently represents a substituent selected from the group consisting of H, Na, Li, and K; each Hal independently represents a halogen selected from the group consisting of Cl, Br, and I; each a independently represents 1, 2 or 3; b and c each represent 1 or 2 wherein b+c=3; each X represents a T(NH—Ar(CO2M)a)bHalc−1 group; each Y independently represents H or X; and n represents a number of 0 to 50, and uses therefor in washing and treating dyed and/or undyed textiles.

摘要翻译： 包含颜色转移抑制剂和任选的表面活性剂的洗涤剂组合物，所述颜色转移抑制剂包含一种或多种选自对应于通式I和II的三嗪衍生物的化合物：<？in-line-formula description =“In “公式”end =“lead”？> T（NH-Ar（CO2M）a）bHalc（I）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in -line-formula description =“In-line Formulas”end =“lead”？X-NH-CH2CH2-（NY-CH2CH2-）nNH-X（II）<？in-line-formula description =“In-line 式“end =”tail“？>其中T表示1,3,5-三嗪基; Ar表示苯基; 每个M独立地表示选自H，Na，Li和K的取代基; 每个Hal独立地表示选自Cl，Br和I的卤素; 每个独立地代表1,2或3; b和c各自表示1或2，其中b + c = 3; 每个X表示T（NH-Ar（CO 2 M）a）b Halc-1基团; 每个Y独立地表示H或X; n表示0〜50的数，用于洗涤和/或未染色染色纺织品。

公开(公告)号：US07316995B2

公开(公告)日：2008-01-08

申请号：US11200678

申请日：2005-08-10

申请人： Josef Penninger

发明人： Josef Penninger

IPC分类号： C11D3/06 ,  C11D3/10 ,  C11D3/08 ,  C11D3/36

CPC分类号： C11D3/3942 ,  C11D3/0026 ,  C11D3/0036 ,  C11D3/225 ,  C11D11/00 ,  C11D11/0017 ,  C11D17/0039 ,  D06M15/09 ,  D06M2200/00

摘要： A builder-containing laundry detergent or cleaning composition comprising: (1) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 5% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (2) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise only water-soluble builders.

摘要翻译： 1.一种含助洗剂的洗衣洗涤剂或清洁组合物，其包含：（1）水溶性助洗剂块，其包含：a）5重量％至35重量％的柠檬酸，碱金属柠檬酸盐，碱金属碳酸盐， 和/或碱金属碳酸氢盐，b）至多5重量％的模量为1.8至2.5的碱金属硅酸盐，c）至多2重量％的膦酸和/或碱金属磷酸盐， d）至多50重量％的碱金属磷酸盐，和e）至多10重量％的聚羧酸多元醇，其中组分b），c），d）和e）中的至少两种以大于0的量存在 重量％，和（2）可释放污垢的烷基或羟烷基纤维素衍生物。 当纤维素衍生物用于仅包含水溶性助洗剂的洗衣洗涤剂或清洁组合物中时，具有特别明显的作用。

公开(公告)号：US20070089244A1

公开(公告)日：2007-04-26

申请号：US11546962

申请日：2006-10-12

申请人： Josef Penninger

发明人： Josef Penninger

IPC分类号： C11D3/00

CPC分类号： C11D3/227 ,  C11D3/001

摘要： A textile care product comprising quaternary nitrogen containing cellulose ether, for protecting textiles. The product can be used in order to reduce fluffing, to reduce pilling, to reduce creasing, for smoothing and to improve soft touch, in addition to facilitating ironing of a flat textile sheet material.

摘要翻译： 一种包含含有季氮的纤维素醚的纺织品护理产品，用于保护纺织品。 除了促进扁平纺织品片材的熨烫之外，可以使用该产品以减少绒毛，减少起球，减少皱纹，平滑和改善柔软的触感。

公开(公告)号：US20060147427A1

公开(公告)日：2006-07-06

申请号：US10567167

申请日：2004-08-04

申请人： Josef Penninger ,  Urs Eriksson

发明人： Josef Penninger ,  Urs Eriksson

IPC分类号： A61K35/14 ,  C12N5/08

CPC分类号： C12N5/0639 ,  A61K35/15 ,  A61K49/0008 ,  A61K2039/5154 ,  C12N2501/052 ,  C12N2501/056 ,  C12N2501/185 ,  C12N2501/52 ,  G01N33/5047 ,  G01N33/564 ,  G01N2800/24

摘要： A method for making dendritic cells reactive to an antigen comprises obtaining a sample of dendritic cells and contacting the cells with the antigen and at least one Toll-like receptor stimulant. Dendritic cells activated by this method provide a means for treating tumors and for creating animal models of autoimmune diseases.

摘要翻译： 制备与抗原反应的树突状细胞的方法包括获得树突状细胞的样品并使细胞与抗原和至少一种Toll样受体兴奋剂接触。 通过该方法活化的树突细胞提供治疗肿瘤和产生自身免疫性疾病的动物模型的手段。

公开(公告)号：US20060046950A1

公开(公告)日：2006-03-02

申请号：US11200750

申请日：2005-08-10

申请人： Josef Penninger ,  Thorsten Bastigkeit

发明人： Josef Penninger ,  Thorsten Bastigkeit

IPC分类号： C11D3/37

CPC分类号： D06M15/09 ,  C11D3/0036 ,  C11D3/225 ,  C11D11/00 ,  C11D17/0039 ,  D06M2200/00

摘要： A detergent for cleaning textile materials is compried of a combination of a soil release-capable alkyl or hydroxyalkyl cellulose derivative and a hygroscopic polymer selected from the group consisting of polypeptides, hydrogels, polyvinyl alcohol, the polyalkylene glycols, the homopolymers of acrylic acid, methacrylic acid, and maleic acid, copolymers of acrylic acid, methacrylic acid, and maleic acid and mixtures of the homo and copolymers. The use of the hygroscopic polymers in combination with the cellulose derivatives results in improved cleaning performance.

摘要翻译： 用于清洁纺织材料的洗涤剂由具有污垢释放性的烷基或羟烷基纤维素衍生物和选自多肽，水凝胶，聚乙烯醇，聚亚烷基二醇，丙烯酸均聚物，甲基丙烯酸酯的吸湿性聚合物的组合组成 酸和马来酸，丙烯酸，甲基丙烯酸和马来酸的共聚物以及均聚物和共聚物的混合物。 使用吸湿性聚合物与纤维素衍生物结合可以改善清洁性能。

公开(公告)号：US20060035805A1

公开(公告)日：2006-02-16

申请号：US11201261

申请日：2005-08-10

申请人： Josef Penninger

发明人： Josef Penninger

IPC分类号： C11D3/22

CPC分类号： C11D11/0017 ,  C11D3/0036 ,  C11D3/225 ,  C11D3/3942 ,  C11D11/00 ,  C11D17/0039 ,  D06M15/09 ,  D06M2200/00

摘要： Textile materials comprised at least partially of cotton are cleaned with a laundry detergent comprising bleach and an alkylated and/or hydroxyalkylated soil release-capable cellulose derivative having an average of from 0.5 to 2.5 alkyl groups and/or from 0.02 to 0.5 hydroxyalkyl groups per anhydroglycose monomer unit. The textile materials are cleaned more effectively with a laundry detergent containing the alkylated and/or hydroxyalkylated soil release-capable cellulose derivative.

摘要翻译： 至少部分由棉花组成的纺织材料用洗涤剂和包含平均0.5至2.5个烷基和/或每个每个脱水糖基0.02至0.5个羟基烷基的烷基化和/或羟基烷基化的具有去污力的可脱土的纤维素衍生物 单体单元。 用含有烷基化和/或羟基烷基化的具有污垢释放能力的纤维素衍生物的衣物洗涤剂更有效地清洁纺织材料。

公开(公告)号：US20060035801A1

公开(公告)日：2006-02-16

申请号：US11200679

申请日：2005-08-10

申请人： Josef Penninger

发明人： Josef Penninger

IPC分类号： C11D3/20

CPC分类号： C11D3/225 ,  C11D3/0026 ,  C11D3/0036 ,  C11D3/3942 ,  C11D17/0039 ,  D06M15/09 ,  D06M2200/00

摘要： A builder-containing laundry detergent or cleaning composition is comprised of: (1) alkali metal percarbonate; (2) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 10% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (3) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise alkali metal percarbonates and contain only water-soluble builders.

摘要翻译： 含有助洗剂的洗衣洗涤剂或清洁组合物包括：（1）碱金属过碳酸盐; （2）水溶性助洗剂块，其包含：a）5重量％至35重量％的柠檬酸，碱金属柠檬酸盐，碱金属碳酸盐和/或碱金属碳酸氢盐，b） 至多10重量％的模量为1.8至2.5的碱金属硅酸盐，c）至多2重量％的膦酸和/或碱金属磷酸盐，d）至多50重量％的碱金属 磷酸盐和e）高达10重量％的聚羧酸多酯，其中组分b），c），d）和e）中的至少两种以大于0重量％的量存在，和（3）污垢释放 可能的烷基或羟烷基纤维素衍生物。 当纤维素衍生物用于洗衣洗涤剂或包含碱金属过碳酸盐并且仅含水溶性助洗剂的清洁组合物中时，纤维素衍生物的具有污垢释放作用特别明显。

公开(公告)号：US06342472B1

公开(公告)日：2002-01-29

申请号：US09555147

申请日：2000-08-15

申请人： Dieter Legel ,  Josef Penninger ,  Theodor Voelkel

发明人： Dieter Legel ,  Josef Penninger ,  Theodor Voelkel

IPC分类号： C11D337

CPC分类号： C11D3/042 ,  C11D3/3726 ,  C11D3/3765 ,  C11D17/003

摘要： Low-concentration, highly viscous liquid detergents which maintain their degree of viscosity in storage in a range of climatic conditions, do not undergo any phase separation or agglomerate separation, and maintain their color under the influence of light. Liquid detergents with the desired properties contain 0.2 to 5 wt. % of a polyurethane or modified polyacrylate, 0.5 to 7 wt. % of a boron compound and 1 to 8 wt. % of a complexer.

摘要翻译： 在气候条件范围内保持其粘度的低浓度，高粘度液体洗涤剂不经历任何相分离或附聚分离，并在光影响下保持其颜色。 具有所需性质的液体洗涤剂含有0.2至5wt。 ％的聚氨酯或改性聚丙烯酸酯，0.5至7wt。 ％的硼化合物和1至8wt。 一个复杂的百分比。