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1.发明申请METHOD FOR PRODUCING STRONGLY ACIDIC ZIRCONIUM PARTICLES, PROTON CONDUCTING MATERIAL, METHOD FOR PRODUCING PROTON CONDUCTING MEMBRANE, PROTON CONDUCTING MEMBRANE, ELECTRODE FOR FUEL CELL, MEMBRANE ELECTRODE ASSEMBLY, FUEL CELL 审中-公开用于制造强酸性锆英宝石的方法，导体材料，制造导电膜的方法，导体导电膜，燃料电池用电极，膜电极组件，燃料电池公开(公告)号：US20120196206A1
公开(公告)日：2012-08-02
申请号：US13390091
申请日：2010-03-25
CPC分类号： H01B1/122 , C01G25/00 , C01G25/02 , C01G25/06 , C01P2002/72 , C01P2002/85 , C01P2002/88 , C01P2004/03 , C01P2006/60 , C07F9/3834 , H01M4/8663 , H01M4/8668 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/106 , H01M8/1062 , H01M8/1081 , H01M2008/1095 , Y02P70/56
摘要： The disclosed methods enable zirconium sulfophenyl phosphonate, zirconium sulfate, or zirconia sulfate, which has high performance as a proton conducting material and high catalytic activity, to be produced at low temperature by reaction by adding sulfophenyl phosphonic acid or sulfuric acid to zirconium nanoparticles, the zirconium nanoparticles being a precursor of strongly acidic zirconium particles obtained by reacting zirconium alkoxide with zirconium butoxide as a chelating agent and nitric acid as a catalyst in isopropyl alcohol as a solvent.
摘要翻译： 所公开的方法使得通过向磺酸钠纳米颗粒中加入磺基苯基膦酸或硫酸的反应在低温下产生具有高性能的质子传导材料和高催化活性的磺基苯基膦酸锆，硫酸锆或硫酸氧锆， 锆纳米颗粒是通过使烷氧基锆与作为螯合剂的丁醇锆反应获得的强酸性锆颗粒的前体，硝酸作为在异丙醇中作为溶剂的催化剂。
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2.发明授权Proton conductive hybrid material, and catalyst layer for fuel cell using the same 失效质子导电混合材料，以及使用其的燃料电池用催化剂层公开(公告)号：US08632701B2
公开(公告)日：2014-01-21
申请号：US12064224
申请日：2005-10-03
IPC分类号： H01L31/0264 , H01M4/86 , H01M4/96 , H01M8/02
CPC分类号： H01B1/122 , H01M4/86 , H01M8/0289 , H01M8/1023 , H01M8/1048 , H01M8/1051 , H01M2300/0091
摘要： This invention provides an organic-inorganic hybrid material, which can exhibit high proton conductivity in a wide temperature range of a low temperature to a high temperature, a proton conductive material, which has a small particle diameter, that is, has a particle diameter capable of reaching pores of primary particles of carbon powder or the like, and has controlled particle diameters, a catalyst layer containing these materials for a fuel cell and an electrolyte film containing these materials for a fuel cell, and a fuel cell. The proton conductive hybrid material comprises proton conductive inorganic nanoparticles and a proton conductive polymer, wherein the Stokes particle diameter of the proton conductive hybrid material by dynamic light scattering is not more than 20 nm.
摘要翻译： 本发明提供一种有机 - 无机杂化材料，其在低温到高温的宽温度范围内可以表现出高质子传导性，具有小粒径的质子传导材料，即具有能够 达到碳粉末等的一次粒子的孔隙，并且具有受控的粒径，包含这些用于燃料电池的材料的催化剂层和含有这些燃料电池用材料的电解质膜和燃料电池。 质子传导性杂化材料包括质子传导性无机纳米粒子和质子传导性聚合物，其中通过动态光散射的质子传导混合材料的斯托克斯粒径不大于20nm。
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3.发明申请PROTON CONDUCTIVE HYBRID MATERIAL, AND CATALYST LAYER FOR FUEL CELL USING THE SAME 失效原子导电混合材料和催化剂层用于燃料电池公开(公告)号：US20090220840A1
公开(公告)日：2009-09-03
申请号：US12064224
申请日：2005-10-03
CPC分类号： H01B1/122 , H01M4/86 , H01M8/0289 , H01M8/1023 , H01M8/1048 , H01M8/1051 , H01M2300/0091
摘要： This invention provides an organic-inorganic hybrid material, which can exhibit high proton conductivity in a wide temperature range of a low temperature to a high temperature, a proton conductive material, which has a small particle diameter, that is, has a particle diameter capable of reaching pores of primary particles of carbon powder or the like, and has controlled particle diameters, a catalyst layer containing these materials for a fuel cell and an electrolyte film containing these materials for a fuel cell, and a fuel cell. The proton conductive hybrid material comprises proton conductive inorganic nanoparticles and a proton conductive polymer, wherein the Stokes particle diameter of the proton conductive hybrid material by dynamic light scattering is not more than 20 nm.
摘要翻译： 本发明提供一种有机 - 无机杂化材料，其在低温到高温的宽温度范围内可以表现出高质子传导性，具有小粒径的质子传导材料，即具有能够 达到碳粉末等的一次粒子的孔隙，并且具有受控的粒径，包含这些用于燃料电池的材料的催化剂层和含有这些燃料电池用材料的电解质膜和燃料电池。 质子传导性杂化材料包括质子传导性无机纳米粒子和质子传导性聚合物，其中通过动态光散射的质子传导混合材料的斯托克斯粒径不大于20nm。
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