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1.发明授权
公开(公告)号：US4675375A
公开(公告)日：1987-06-23
申请号：US744201
申请日：1985-06-13
申请人： Fritz E. Kempter , Juergen Nieberle
发明人： Fritz E. Kempter , Juergen Nieberle
摘要： Essentially phenol-free phenol resol ethers which are bonded via o,o'-methylene ether groups are prepared by a process in whichA. where the process is carried out beginning with the methylolation in an aqueous medium, the methylolation is carried out in the presence of 0.5-10% by weight, based on the phenol employed, of Me.sup.++ ions, the latter are then removed as a sparingly soluble salt, the water present as a solvent in the reaction mixture is removed at 30.degree.-80.degree. C. in the presence or absence of one or more monohydric, dihydric or trihydric alcohols and an entraining agent, and the water of reaction formed during the etherification is separated off at 45.degree.-120.degree. C., andB. where the process is carried out beginning with the methylolation in a non-polar organic solvent, the methylolation is carried out in the presence of 0.1-0.3% by weight, based on the phenol employed, of Me.sup.++ ions, the etherification is effected at 95.degree.-120.degree. C. in the presence of one or more monohydric, dihydric or trihydric alcohols, with or without recycling of the distillate which passes over, and finally residual phenol in the products prepared by A. or B. is removed by evaporation in a thin film evaporator until the phenol content is less than 1% by weight.The phenol resol ethers prepared according to the invention are useful for the preparation of coating systems and for adhesives.
摘要翻译： 通过o，o-亚甲基醚基团结合的基本上不含苯酚的酚甲醚是通过一种方法制备的，其中在水介质中开始以羟甲基化反应进行该方法，其中甲氧基化在 以所用苯酚为基准，存在0.5〜10重量％的Me ++离子，后者作为微溶盐除去，在反应混合物中作为溶剂存在的水在30〜80℃下除去。 在存在或不存在一种或多种一元，二元或三元醇和夹带剂的情况下，在醚化期间形成的反应水在45°-120℃和B处分离，其中进行该方法 以非极性有机溶剂中的羟甲基化反应开始，在0.1-0.3重量％存在下，基于所用的苯酚Me ++离子进行羟甲基化反应，醚化在95℃-120℃下进行。 在一种或多种单氢的存在下 ic，二元或三元醇，有或没有循环使用过的馏出物，最后通过在薄膜蒸发器中蒸发除去由A.或B.B制备的产物中的残余苯酚，直到苯酚含量小于1％ 重量。 根据本发明制备的酚醛树脂醚可用于制备涂料体系和粘合剂。
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2.发明授权
公开(公告)号：US4395535A
公开(公告)日：1983-07-26
申请号：US308981
申请日：1981-10-06
IPC分类号： C08G8/04
CPC分类号： C08G8/04
摘要： A process for the manufacture of condensation products of phenols and isobutyraldehyde by reacting the phenols and isobutyraldehyde at elevated temperature in a mole ratio of 0.5:1 to 1.5:1 in the presence of acid or compounds hydrolyzable to acids as catalysts, subsequent neutralization and removal of the resultant reaction water by distillation wherein the reaction products obtained in this manner are also subjected to a water-vapor distillation.
摘要翻译： 在酸或作为催化剂可酸化的化合物的存在下，以0.5:1至1.5:1的摩尔比在高温下使苯酚和异丁醛反应来制备苯酚和异丁醛的缩合产物的方法，随后的中和和去除 通过蒸馏得到的反应水，其中以这种方式获得的反应产物也进行水蒸气蒸馏。
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公开(公告)号：US4777194A
公开(公告)日：1988-10-11
申请号：US744204
申请日：1985-06-13
CPC分类号： C09D5/4496
摘要： A heat-curable aqueous coating agent contains, as a binder, a mixture or precondensate of(A) a resin possessing basic nitrogen groups and(B) a phenol resin based on a resol ether which is bonded via 0,0'-methylene ether groups and whose p-positions predominantly carry hydrogen and/or methylolalkyl ether groups.After protonation with an acid, the said coating agent is particularly useful as a binder for the cathodic electrocoating of metal articles.
摘要翻译： 可热固化的水性涂料含有作为粘合剂的（A）具有碱性氮基团的树脂的混合物或预缩合物，和（B）基于通过0'-亚甲基醚键合的甲阶酚醛树脂的酚醛树脂 基团并且其p-位主要携带氢和/或羟甲基烷基醚基团。 用酸质子化后，所述涂层剂特别可用作金属制品的阴极电涂层的粘合剂。
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公开(公告)号：US4731430A
公开(公告)日：1988-03-15
申请号：US883691
申请日：1986-07-09
申请人： Fritz E. Kempter , Juergen Nieberle
发明人： Fritz E. Kempter , Juergen Nieberle
IPC分类号： C08G8/00 , C08G8/04 , C08G8/28 , C08L21/00 , C08L61/14 , C09D5/44 , C09J201/00 , C08G14/08 , C08G8/36
CPC分类号： C08L21/00 , C08G8/04 , C08G8/28 , C08L61/14 , C09D5/4488 , C09J201/00 , Y10T428/31942
摘要： Phenol resins which are modified with compounds possessing amide and/or imide groups and are based on phenol resol ethers bonded via o,o'-methylene ether groups, and a process for their preparation.The novel modified phenol resol ethers are useful for the preparation of coating systems, in particular as crosslinking agents for cathodic electrocoating binders, and for the preparation of adhesives and rubber assistants.
摘要翻译： 用具有酰胺和/或酰亚胺基团的化合物改性的苯酚树脂，其基于通过o，o-亚甲基醚基团键合的酚甲醚，及其制备方法。 新型改性酚醛树脂醚可用于制备涂料体系，特别是用于阴极电泳涂料粘合剂的交联剂，以及制备粘合剂和橡胶助剂。
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公开(公告)号：US4996270A
公开(公告)日：1991-02-26
申请号：US267714
申请日：1988-11-04
CPC分类号： C08G59/1472 , C08G59/063
摘要： Vinyl ester resins possess unsaturated terminal groups and are based on polyphenols of the formulaC(ArOH).sub.m (R').sub.p --(CR.sub.2).sub.n --C(ArOH).sub.m (R").sub.p (I)or(ArOH)--CH.sub.2 --Ar--CH.sub.2 --[(ArOH)--CH.sub.2 --Ar--CH.sub.2 ].sub.n --(ArOH) (II)wherein R, R' and R" may be identical or different and are each H or CH.sub.3, Ar is phenylene which is unsubstituted or substituted by methyl or methoxy, n is 0, 1 or 2, m is 1 or 2 and p is 3-m.
摘要翻译： 乙烯基酯树脂具有不饱和端基，并且基于式C（ArOH）m（R'）p（CR 2）n C（ArOH）m（R“'）p（I）或（ArOH）-CH 2 - Ar-CH 2 - [（ArOH）-CH 2 Ar-CH 2] n - （ArOH）（II）其中R，R'和R“可以相同或不同，各自为H或CH 3，Ar为亚苯基， 或被甲基或甲氧基取代，n为0,1或2，m为1或2，p为3-m。
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公开(公告)号：US4190547A
公开(公告)日：1980-02-26
申请号：US909193
申请日：1978-05-25
申请人： Harald Mahnke , Juergen Nieberle , Volker Trautz , Heinz Weber
发明人： Harald Mahnke , Juergen Nieberle , Volker Trautz , Heinz Weber
CPC分类号： C04B26/122 , Y10S428/921 , Y10T428/2933 , Y10T428/2998 , Y10T428/31667 , Y10T428/31942
摘要： Non-flammable insulating materials having good fire resistance and a density of from 80 to 230 g/l, which materials compriseA. from 99 to 80% by weight of inorganic lightweight particles, preferably expanded perlite or vermiculite,B. from 0 to 20% by weight of fibrous or granular inorganic additives andC. from 1 to 20% by weight of a heat-resistant organic high molecular weight binder, preferably a phenol-formaldehyde condensate,and which contain, as an additional binder C' to prevent water absorption, from 0.2 to 4% by weight of an alkylphenol/phenyl/formaldehyde condensate.The materials may be used as heat insulating materials or building materials.
摘要翻译： 不燃性绝缘材料具有良好的耐火性和密度为80至230g / l，该材料包含：A至99％至80％重量的无机轻质颗粒，优选膨胀珍珠岩或蛭石，B为0至20 重量％的纤维状或颗粒状无机添加剂和C.1〜20重量％的耐热有机高分子量粘合剂，优选苯酚 - 甲醛缩合物，并且其含有作为附加粘合剂C'以防止水 吸收，0.2至4重量％的烷基酚/苯基/甲醛缩合物。 这些材料可以用作隔热材料或建筑材料。
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