公开(公告)号：US20100284893A1

公开(公告)日：2010-11-11

申请号：US12685465

申请日：2010-01-11

Applicant: Ryan M. RICHARDS ,  Lifang Chen ,  Juncheng Hu

Inventor： Ryan M. RICHARDS ,  Lifang Chen ,  Juncheng Hu

IPC: C01G9/02 ,  C01B31/20 ,  C07C29/159

CPC classification number: C30B7/14 ,  B82Y30/00 ,  C01B32/50 ,  C01G9/02 ,  C01P2002/01 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/16 ,  C01P2004/61 ,  C01P2006/12 ,  C07C29/153 ,  C09C1/043 ,  C30B7/06 ,  C30B29/16 ,  C07C31/04

Abstract: ZnO structures comprising crystalline ZnO micro or nanorods and methods for making and using these ZnO structures are provided. The side surface of the central portion of each rod may comprise planes of the form {1 0 −1 0}, {0 1 −1 0}, {−1 1 0 0}, {−1 0 1 0}, {0 −1 1 0} or {1 −1 0 0}, with central edge regions including a crystallographic plane of the form {2 −1 −1 0} or {−2 1 1 0}. The tip of the rod may comprise planes of the form {1 0 −1 1} {0 1 −1 1}, {−1 1 0 1}, {−1 0 1 1}, {0 −1 1 1} or {1 −1 0 1} with tip edge regions including a crystallographic plane of the form {2 −1 −1 2} or {−2 1 1 2}. The rods may be joined at or near their bases to form a “flower-like” morphology. In an embodiment, a synthesis mixture is prepared by dissolving a zinc salt in an alcohol solvent, followed by addition of at least two additives. The zinc salt may be zinc nitrate hexahydrate, the first additive may be benzyl alcohol and the second additive may be urea.

Abstract translation: 提供了包含结晶ZnO微晶或纳米棒的ZnO结构以及制备和使用这些ZnO结构的方法。 每个杆的中心部分的侧表面可以包括{1 0 -1 0}，{0 1 -1 0}，{-1 1 0 0}，{-1 0 1 0}，{0 -1 1 0}或{1 -1 0 0}，其中心边缘区域包括形式为{2 -1 -1 0}或{-2 111}的晶体平面。 棒的尖端可以包括{1 0 -1 1} {0 1 -1 1}，{-1 1 0 1}，{-1 011}，{0 -1 1 1}或 {1 -1 0 1}具有包括{2 -1 -1 2}或{-2 111}形式的结晶平面的尖端边缘区域。 棒可以在其底部或附近连接以形成“花状”形态。 在一个实施方案中，通过将锌盐溶解在醇溶剂中，然后加入至少两种添加剂来制备合成混合物。 锌盐可以是硝酸锌六水合物，第一添加剂可以是苄醇，第二添加剂可以是尿素。

公开(公告)号：US08790614B2

公开(公告)日：2014-07-29

申请号：US12685465

申请日：2010-01-11

Applicant: Ryan M. Richards ,  Lifang Chen ,  Juncheng Hu

Inventor： Ryan M. Richards ,  Lifang Chen ,  Juncheng Hu

IPC: C01G9/02 ,  C01B31/20 ,  C07C29/159

CPC classification number: C30B7/14 ,  B82Y30/00 ,  C01B32/50 ,  C01G9/02 ,  C01P2002/01 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/16 ,  C01P2004/61 ,  C01P2006/12 ,  C07C29/153 ,  C09C1/043 ,  C30B7/06 ,  C30B29/16 ,  C07C31/04

Abstract: ZnO structures comprising crystalline ZnO micro or nanorods and methods for making and using these ZnO structures are provided. The side surface of the central portion of each rod may comprise planes of the form {1 0 −1 0}, {0 1 −1 0}, {−1 1 0 0}, {−1 0 1 0}, {0 −1 1 0} or {1 −1 0 0}, with central edge regions including a crystallographic plane of the form {2 −1 −1 0} or {−2 1 1 0}. The tip of the rod may comprise planes of the form {1 0 −1 1} {0 1 −1 1}, {−1 1 0 1}, {−1 0 1 1}, {0 −1 1 1} or {1 −1 0 1} with tip edge regions including a crystallographic plane of the form {2 −1 −1 2} or {−2 1 1 2}. The rods may be joined at or near their bases to form a “flower-like” morphology. In an embodiment, a synthesis mixture is prepared by dissolving a zinc salt in an alcohol solvent, followed by addition of at least two additives. The zinc salt may be zinc nitrate hexahydrate, the first additive may be benzyl alcohol and the second additive may be urea.

Abstract translation: 提供了包含结晶ZnO微晶或纳米棒的ZnO结构以及制备和使用这些ZnO结构的方法。 每个杆的中心部分的侧表面可以包括{1 0 -1 0}，{0 1 -1 0}，{-1 1 0 0}，{-1 0 1 0}，{0 -1 1 0}或{1 -1 0 0}，其中心边缘区域包括形式为{2 -1 -1 0}或{-2 111}的晶体平面。 棒的尖端可以包括{1 0 -1 1} {0 1 -1 1}，{-1 1 0 1}，{-1 011}，{0 -1 1 1}或 {1 -1 0 1}具有包括{2 -1 -1 2}或{-2 111}形式的结晶平面的尖端边缘区域。 棒可以在其底部或附近连接以形成“花状”形态。 在一个实施方案中，通过将锌盐溶解在醇溶剂中，然后加入至少两种添加剂来制备合成混合物。 锌盐可以是硝酸锌六水合物，第一添加剂可以是苄醇，第二添加剂可以是尿素。

公开(公告)号：US20110143088A1

公开(公告)日：2011-06-16

申请号：US12735610

申请日：2008-03-10

Applicant: Ryan Richards ,  Juncheng Hu

Inventor： Ryan Richards ,  Juncheng Hu

IPC: C01G53/04 ,  B32B3/24 ,  B32B9/00 ,  B82Y40/00 ,  B82Y30/00

CPC classification number: C01G53/04 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2002/85 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/20 ,  C01P2004/61 ,  C01P2006/40 ,  Y10T428/24306

Abstract: Method for preparing a NiO nanosheet structure possessing (111) crystallographic planes as a primary surface with hexagonal holes, comprising the following steps: a) preparing a methanol solution of a nickel salt selected from the group consisting of nickel nitrate, nickel sulphate, nickel chlorate, nickel acetate, and nickel phosphate or a mixture thereof; b) adding benzyl alcohol (BZ), optionally substituted with alkyl, nitro, halo or amino, or a mixture thereof and urea to the solution of (a) in a ratio of Ni to BZ or substituted BZ of at least 1; c) solvent removal and calcination in air of the mixture, plate-like NiO nanosheet precursors therefore, NiO nanosheet structures obtainable by that method as well as various novel uses thereof.

Abstract translation: 制备具有（111）晶面作为具有六角孔的主表面的NiO纳米片结构的方法，包括以下步骤：a）制备选自硝酸镍，硫酸镍，氯酸镍的镍盐的甲醇溶液 ，乙酸镍和磷酸镍或其混合物; b）将任选地被烷基，硝基，卤素或氨基或其混合物和尿素取代的苄醇（BZ）加入到（a）的比例的Ni与BZ或取代的BZ的比率为至少1的溶液中; c）在混合物的空气中溶剂的去除和煅烧，板状NiO纳米片前体因此，可以通过该方法获得的NiO纳米片结构及其各种新用途。