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公开(公告)号:US3847952A
公开(公告)日:1974-11-12
申请号:US15760871
申请日:1971-06-28
申请人: SMIRNOV V , SOLTOVETS G , KULNEVICH V , SEMCHENKO D
发明人: SOLTOVETS G , SEMCHENKO D , SMIRNOV V , KULNEVICH V
IPC分类号: C07D307/42 , C07D307/44 , C07D5/20
CPC分类号: C07D307/42 , C07D307/44
摘要: 1. A METHOD OF PRODUCING AN ALCOHOL OF THE FURAN SERIES HAVING THE FORMULA:
2-(HO-CH2-),5-R-FURAN
WHEREIN R IS H, CH3, CH2OH, CL OR BR, SAID METHOD COMPRISING FEEDING AN AQUEOUS SOLUTION OF AN ALDEHYDE OF THE FURAN SERIES HAVING THE FORMULA:
2-(H-CO-),5-R-FURAN
WHEREIN R IS DEFINED ABOVE AND CONTAINING FROM 2 TO 5% BY WT. OF AN INORGANIC OR ORGANIC ACID ONTO AN AMALGAM OF AN ALKALI METAL OF 0.1-3.0 N CONCENTRATION AT A RATE PROVIDING DECOMPOSITION OF THE AMALGAM OF FROM 800 TO 300 A./M.2 WHILE SATURATING THE ALDEHYDE SOLUTION WITH CARBON DIOXIDE TO NEUTRALIZE ALKALI DEVELOPED DURING AMALGAM DECOMPOSITON.