Process for producing alcohols of the furan series
    1.
    发明授权
    Process for producing alcohols of the furan series 失效
    生产FURAN系列酒精的方法

    公开(公告)号:US3847952A

    公开(公告)日:1974-11-12

    申请号:US15760871

    申请日:1971-06-28

    CPC分类号: C07D307/42 C07D307/44

    摘要: 1. A METHOD OF PRODUCING AN ALCOHOL OF THE FURAN SERIES HAVING THE FORMULA:

    2-(HO-CH2-),5-R-FURAN

    WHEREIN R IS H, CH3, CH2OH, CL OR BR, SAID METHOD COMPRISING FEEDING AN AQUEOUS SOLUTION OF AN ALDEHYDE OF THE FURAN SERIES HAVING THE FORMULA:

    2-(H-CO-),5-R-FURAN

    WHEREIN R IS DEFINED ABOVE AND CONTAINING FROM 2 TO 5% BY WT. OF AN INORGANIC OR ORGANIC ACID ONTO AN AMALGAM OF AN ALKALI METAL OF 0.1-3.0 N CONCENTRATION AT A RATE PROVIDING DECOMPOSITION OF THE AMALGAM OF FROM 800 TO 300 A./M.2 WHILE SATURATING THE ALDEHYDE SOLUTION WITH CARBON DIOXIDE TO NEUTRALIZE ALKALI DEVELOPED DURING AMALGAM DECOMPOSITON.