Polyester carbonate copolymer for optical lens and optical lens
    1.
    发明授权
    Polyester carbonate copolymer for optical lens and optical lens 有权
    聚酯碳酸酯共聚物用于光学透镜和光学透镜

    公开(公告)号:US08378055B2

    公开(公告)日:2013-02-19

    申请号:US13386472

    申请日:2010-07-16

    IPC分类号: C08G64/00 C08G63/02

    摘要: This invention is to provide a polyester carbonate copolymer suitable for an optical lens that has high refractivity and transparency and low birefringence and little optical strain, and optical lenses formed therefrom.This invention is a polyester carbonate copolymer for an optical lens, which comprises 67 to 95 mol % of a unit of the following formula (I) and 33 to 5 mol % of a unit of the following formula (II) and has a specific viscosity of 0.12 to 0.30, wherein Y in the formula (II) is a phenylene group or a naphthalenediyl group.

    摘要翻译: 本发明提供一种适用于光学透镜的聚酯碳酸酯共聚物,该聚酯碳酸酯共聚物具有高折射率和透明度,低折射率和很小的光学应变,以及由此形成的光学透镜。 本发明是一种用于光学透镜的聚酯碳酸酯共聚物,其包含67至95摩尔%的下式(I)的单元和33至5摩尔%的下式(II)的单元,并且具有比粘度 为0.12〜0.30,式(II)中的Y为亚苯基或萘二基。

    Process for producing pentaerythritol diphosphonates
    2.
    发明申请
    Process for producing pentaerythritol diphosphonates 审中-公开
    制备季戊四醇二膦酸盐的方法

    公开(公告)号:US20060116526A1

    公开(公告)日:2006-06-01

    申请号:US10541021

    申请日:2003-12-25

    IPC分类号: C07F9/02

    CPC分类号: C07F9/657181

    摘要: A process for producing a pentaerythritol diphosphonate represented by formula (5) characterized by (A) reacting phosphorus trichloride with pentaerythritol in the presence of an inert solvent to obtain pentaerythritol dichlorophosphite (reaction (a)), (B) reacting the pentaerythritol dichlorophosphite with an aralkyl alcohol to obtain a pentaerythritol diphosphite (reaction (b)), and (C) heat-treating the pentaerythritol diphosphite in the presence of a halogenated compound at a temperature of from 80 to 300° C. (reaction (c)): wherein Ar1 and Ar2, which may be the same as or different from each other, each represents a substituted or unsubstituted aryl group having from 6 to 20 carbon atoms, and R3, R4, R5 and R6, which may be the same as or different from each other, each represents a hydrogen atom, a substituted or unsubstituted aryl group having from 6 to 20 carbon atoms, or a saturated or unsaturated hydrocarbon group having from 1 to 20 carbon atoms.

    摘要翻译: 一种制备由式(5)表示的季戊四醇二膦酸酯的方法,其特征在于(A)在惰性溶剂存在下使三氯化磷与季戊四醇反应,得到季戊四醇二氯亚磷酸酯(反应(a)),(B)使季戊四醇二氯亚磷酸酯与 芳烷基醇,得到季戊四醇二亚磷酸酯(反应(b)),(C)在卤化物存在下,在80〜300℃的温度下,季戊四醇二亚磷酸酯进行热处理(反应(c)):其中 Ar 1和Ar 2彼此可以相同或不同,分别表示取代或未取代的碳原子数为6〜20的芳基,R R 4,R 4,R 5和R 6,其可以彼此相同或不同 各自表示氢原子,取代或未取代的碳原子数为6〜20的芳基或饱和或不饱和烃g 具有1至20个碳原子的糖。

    POLYESTER CARBONATE COPOLYMER FOR OPTICAL LENS AND OPTICAL LENS
    5.
    发明申请
    POLYESTER CARBONATE COPOLYMER FOR OPTICAL LENS AND OPTICAL LENS 有权
    用于光学透镜和光学透镜的聚酯碳酸酯共聚物

    公开(公告)号:US20120123083A1

    公开(公告)日:2012-05-17

    申请号:US13386472

    申请日:2010-07-16

    IPC分类号: G02B3/00 C08G64/38 C08G64/16

    摘要: This invention is to provide a polyester carbonate copolymer suitable for an optical lens that has high refractivity and transparency and low birefringence and little optical strain, and optical lenses formed therefrom.This invention is a polyester carbonate copolymer for an optical lens, which comprises 67 to 95 mol % of a unit of the following formula (I) and 33 to 5 mol % of a unit of the following formula (II) and has a specific viscosity of 0.12 to 0.30, wherein Y in the formula (II) is a phenylene group or a naphthalenediyl group.

    摘要翻译: 本发明提供一种适用于光学透镜的聚酯碳酸酯共聚物,该聚酯碳酸酯共聚物具有高折射率和透明度,低折射率和很小的光学应变,以及由此形成的光学透镜。 本发明是一种用于光学透镜的聚酯碳酸酯共聚物,其包含67至95摩尔%的下式(I)的单元和33至5摩尔%的下式(II)的单元,并且具有比粘度 为0.12〜0.30,式(II)中的Y为亚苯基或萘二基。