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公开(公告)号:US06667363B2
公开(公告)日:2003-12-23
申请号:US09802766
申请日:2001-03-09
IPC分类号: C08L5302
CPC分类号: C08L23/10 , C08L23/0815 , C08L25/04 , C08L25/06 , C08L51/06 , C08L71/12 , C08L2666/04
摘要: A material for liquid keeping containers comprising a resin composition which contains a syndiotactic polystyrene resin and a polypropylene resin and includes a compatibilized structure of the syndiotactic polystyrene resin phase and the polypropylene resin phase, the proportion of these phases being 90-10/10-90 (weight ratio).
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公开(公告)号:US5296540A
公开(公告)日:1994-03-22
申请号:US982124
申请日:1992-11-25
申请人: Yoshikuni Akiyama , Ken Mizushiro
发明人: Yoshikuni Akiyama , Ken Mizushiro
IPC分类号: C08G65/48 , C08L23/02 , C08L71/12 , C08L53/02 , C08F283/08
CPC分类号: C08L23/02 , C08G65/485 , C08L71/12 , Y10S525/905
摘要: Disclosed is a shaped resin article comprising (1) a continuous phase of a polyphenylene ether and (2) a dispersed phase dispersed in the continuous phase (1). The dispersed phase comprises (a) a particulate dispersed polyolefin phase which is comprised of a polyolefin and has a minor diameter of not greater than 0.5 .mu.m, the outer surface of the dispersed polyolefin phase (a) having, cohered thereto, particles of at least one copolymer selected from the group consisting of a copolymer of a vinyl aromatic compound and a conjugated diene compound and a hydrogenation product thereof, and (b) a particulate dispersed copolymer phase having a minor diameter of not greater than 0.3 .mu.m, which is comprised of at least one copolymer selected from the above-mentioned group and is dispersed in the continuous phase (1) and not cohered to the dispersed polyolefin phase (a). The shaped resin article has not only remarkably improved weld-line toughness and delamination resistance but also excellent resistance to heat, impact and chemicals.
摘要翻译: 公开了一种成型树脂制品,其包括(1)聚苯醚的连续相和(2)分散在连续相(1)中的分散相。 分散相包含(a)由聚烯烃组成并且具有不大于0.5(m)m的小直径的颗粒分散的聚烯烃相,其中分散的聚烯烃相(a)的外表面与其结合, 的至少一种选自乙烯基芳族化合物和共轭二烯化合物的共聚物及其氢化产物的共聚物,和(b)小直径不大于0.3(my)的颗粒分散共聚物相, m,其由至少一种选自上述基团的共聚物组成,并分散在连续相(1)中,不与分散的聚烯烃相(a)结合。 成型树脂制品不仅显着提高了焊接线韧性和耐分层性,而且具有优异的耐热性,耐冲击性和耐化学性。
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公开(公告)号:US4732928A
公开(公告)日:1988-03-22
申请号:US909233
申请日:1986-09-19
申请人: Ken Mizushiro , Hideo Morita
发明人: Ken Mizushiro , Hideo Morita
CPC分类号: H01B3/44 , C08L53/02 , C08L71/123 , H01B3/427
摘要: A thermoplastic elastomer composition having superior compression set performance and moldability, comprising the following components (a) to (d):(a) a styrenic block copolymer having in the same molecule at least two of polymeric block A mainly comprised of vinyl aromatic compounds and at least one of polymeric block B mainly comprised of conjugated diene compounds, and containing vinyl aromatic compounds in an amount of not less than 15% by weight and not more than 60% by weight;(b) a styrenic block copolymer having in the same molecule at least one of each of polymeric block A mainly comprised of vinyl aromatic compounds and polymeric block B mainly comprised of conjugated diene compounds, and containing vinyl aromatic compounds in an amount of not less than 60% by weight and not more than 95% by weight;(c) a polyphenylene ether resin having the reduced viscosity ranging from 0.15 to 0.70 in 0.5 g/dl of a chloroform solution at 30.degree. C.; and(d) a non-aromatic rubber softening oil, and the contents of said components (a), (b), (c) and (d) in the composition satisfying the following formulae (1), (2) and (3) in weight ratio:2.0.gtoreq.b/a.gtoreq.0 (1)1.4.gtoreq.c/(a+b).gtoreq.0.1 (2)3.0.gtoreq.d/(a+b).gtoreq.0.1 (3);and a method for producing the thermoplastic elastomer composition comprising melt kneading the components (a) to (d) described above. The composition is useful in the field of automobile parts, electric wire coatings, footwear, toys, sundry goods, etc.
摘要翻译: 一种具有优异的压缩变形性能和成型性的热塑性弹性体组合物,其包含以下组分(a)至(d):(a)在相同分子中具有至少两个主要由乙烯基芳族化合物组成的聚合嵌段A的苯乙烯嵌段共聚物和 主要由共轭二烯化合物构成的聚合嵌段B中的至少一种,含有不小于15重量%且不超过60重量%的乙烯基芳族化合物; (b)在相同分子中具有主要由乙烯基芳族化合物构成的聚合物嵌段A和主要由共轭二烯化合物构成的聚合嵌段B中的至少一种的苯乙烯嵌段共聚物,并且含有不小于 60重量%且不大于95重量%; (c)在30℃下在0.5g / dl氯仿溶液中具有0.15-0.70的比浓粘度的聚苯醚树脂; 和(d)非芳族橡胶软化油,以及满足下式(1),(2)和(3)的组合物中所述组分(a),(b),(c)和(d) )重量比:2.0> / = b / a> / = 0(1)1.4> / = c /(a + b)> / = 0.1(2)3.0> / = d /(a + b) = 0.1(3); 以及包含熔融捏合上述成分(a)〜(d)的热塑性弹性体组合物的制造方法。 该组合物可用于汽车零件,电线涂料,鞋类,玩具,杂货等领域。
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公开(公告)号:US4772657A
公开(公告)日:1988-09-20
申请号:US886601
申请日:1986-07-18
CPC分类号: C08L53/025 , C08L71/123 , C08L65/00 , Y10S525/905
摘要: A composition having a composition containing substantially no other engineering thermoplastic resin and a compression set (JIS K 6301; 100.degree. C..times.22 hours; and compressibility, 25%) of 65% or less as rubber which comprises:(a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two polymer blocks A composed mainly of a vinyl-substituted aromatic hydrocarbon and at least one polymer block B composed mainly of a conjugated diene,(b) 11 to 233 parts by weight of a homopolymeric and/or copolymeric polyphenylene ether resin comprising a binding unit represented by the general formula, ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, represent substituents selected from the group consisting of hydrogen, halogen, hydrocarbon groups and substituted hydrocarbon groups, and having a reduced viscosity in a range of from 0.15 to 0.70 as measured at 30.degree. C. in a 0.5 g/dl chloroform solution,(c) 10 to 500 parts by weight of a non-aromatic softening agent for rubber, and(d) 5 to 150 parts by weight of a polyolefin resin and/or a polystyrene resin.
摘要翻译: 具有基本上不含其他工程热塑性树脂和压缩永久变形的组合物(JIS K 6301; 100℃×22小时;压缩性,25%)为65%以下的组合物,其为橡胶,其包含:(a)100份 通过氢化包含至少两个主要由乙烯基取代的芳族烃组成的聚合物嵌段A和至少一个主要由共轭二烯组成的聚合物嵌段B的嵌段共聚物获得的氢化嵌段共聚物的重量,(b)11〜233份 包含由通式表示的结合单元的均聚聚合和/或共聚聚苯醚树脂的重量,其中R 1,R 2,R 3和R 4可以相同或不同,表示选自氢, ,卤素,烃基和取代烃基,并且在30℃下在0.5g / dl氯仿溶液中具有在0.15-0.70范围内的比浓粘度,(c)10至500p (d)5〜150重量份的聚烯烃树脂和/或聚苯乙烯树脂。
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