公开(公告)号：US4218372A

公开(公告)日：1980-08-19

申请号：US853531

申请日：1977-11-21

Applicant: Klaus Koerte

Inventor： Klaus Koerte

IPC: C09B29/00 ,  C09B29/06 ,  C09B31/04 ,  C09B29/36

CPC classification number: C09B29/0077 ,  C09B29/0037 ,  C09B29/0059 ,  C09B29/0092 ,  C09B29/06 ,  C09B31/04

Abstract: Compounds of the formula, ##STR1## in which D is a diazo component radical of the benzene, pyrazole, thiophene, thiazole, isothiazole or thiadiazole series,K is 1,4-phenylene, substituted 1,4-phenylene or 1,4-naphthylene,R.sub.1, in the case where K is 1,4-naphthylene, is hydrogen or (C.sub.1-4)-alkyl or, in the case where K is 1,4-phenylene or substituted 1,4-phenylene, R.sub.1 is hydrogen, (C.sub.1-4)alkyl, (C.sub.1-4)alkyl monosubstituted by chlorine, bromine, vinylsulphonyl, hydroxy, cyano, (C.sub.1-2)alkoxy, phenyl, acetyl, phenoxy, formyloxy, alkyl(C.sub.1-3)carbonyloxy, benzoyloxy, alkoxy(C.sub.1-2)carbonyl, alkoxy(C.sub.1-2)carbonyloxy, (C.sub.1-2)alkylaminocarbonyl, di(C.sub.1-2)alkylaminocarbonyl or --CO--O--C(U.sub.1 U.sub.2)--C.tbd.C--U.sub.3 ; (C.sub.3-4)alkyl substituted by hydroxy and one further substituent selected from the group consisting of chlorine, (C.sub.1-4) alkoxy, hydroxy, phenoxy and benzyloxy; (C.sub.2-4)alkenyl; chloro(C.sub.3-4)alkenyl or bromo(C.sub.3-4)alkenyl,R.sub.2 is straight chain or branched chain (C.sub.1-4)alkylene or --CH.sub.2 CH.sub.2 --O--CH.sub.2 CH.sub.2 --,either, each of U.sub.1 and U.sub.2, independently, is hydrogen or (C.sub.1-4)alkyl, andU.sub.3 is hydrogen or ##STR2## or U.sub.1 and U.sub.2 together with the carbon atom to which they are bound form a cyclohexyl ring, andU.sub.3 is hydrogen,wherein U.sub.4 is hydrogen, (C.sub.1-4)alkyl or alkyl(C.sub.1-4)carbonyl,which compounds are useful as disperse dyes for dyeing and printing textile substrates comprising synthetic or semi-synthetic high molecular weight, hydrophobic organic materials such as linear, aromatic polyesters, cellulose 21/2 acetate, cellulose triacetate and synthetic polyamides. The obtained dyeings possess notable fastness to light, thermofixation, sublimation, pressing and wet treatments.

Abstract translation: 其中D是苯，吡唑，噻吩，噻唑，异噻唑或噻二唑系的重氮组分基团的式（IMAGE）化合物，K是1,4-亚苯基，取代的1,4-亚苯基或1,4-亚苯基， 亚萘基，在K为1,4-亚萘基的情况下，R 1为氢或（C 1-4） - 烷基，或在K为1,4-亚苯基或取代的1,4-亚苯基的情况下，R 1为氢 ，（C 1-4）烷基，被氯，溴，乙烯基磺酰基，羟基，氰基，（C1-2）烷氧基，苯基，乙酰基，苯氧基，甲酰氧基，烷基（C1-3）羰基氧基，苯甲酰氧基 ，烷氧基（C1-2）羰基，烷氧基（C1-2）羰氧基，（C1-2）烷基氨基羰基，二（C1-2）烷基氨基羰基或-CO-OC（U1U2）-C3OND C-U3; 被羟基和一个选自氯，（C 1-4）烷氧基，羟基，苯氧基和苄氧基的另外的取代基取代的（C3-4）烷基; （C2-4）烯基; 氯（C3-4）烯基或溴（C3-4）烯基，R2是直链或支链（C1-4）亚烷基或-CH2CH2-O-CH2CH2-，U1和U2各自独立地是氢 或（C 1-4）烷基，并且U 3是氢或者Y 1和U 2与它们所连接的碳原子一起形成环己基环，U 3是氢，其中U 4是氢，（C 1-4） 烷基或烷基（C 1-4）羰基，该化合物可用作分散染料，用于染色和印刷包含合成或半合成高分子量疏水性有机材料如线性芳族聚酯，纤维素21/2乙酸酯，纤维素 三醋酸酯和合成聚酰胺。 获得的染色具有显着的耐光牢度，耐热固化性，升华性，压制性和湿润性。

公开(公告)号：US4609727A

公开(公告)日：1986-09-02

申请号：US450289

申请日：1982-12-16

Applicant: Klaus Koerte

Inventor： Klaus Koerte

IPC: C09B29/08 ,  C09B43/42 ,  D06P1/18 ,  C09B29/01 ,  C09B29/34

CPC classification number: C09B43/42 ,  C09B29/0813 ,  D06P1/18

Abstract: Compounds of the formula ##STR1## wherein R.sub.1 is nitro or cyano;R.sub.2 is cyano or halo;R.sub.3 is C.sub.1-4 alkyl;R.sub.4 is methyl or ethyl;R.sub.5 is C.sub.1-8 alkyl; andR.sub.6 is --CH.sub.2 CHOHCH.sub.2 O(CH.sub.2 CH.sub.2 O).sub.a R.sub.7, --CH.sub.2 CHOHC.sub.6 H.sub.5, --CH(C.sub.6 H.sub.5)CH.sub.2 OH; --(CH.sub.2).sub.n O--CO--NHR.sub.3, --CH.sub.2 CH(R.sub.4)--O--CO--NHR.sub.3 ; --(CH.sub.2).sub.n --O--CO--R.sub.3, --CH.sub.2 CH(R.sub.4)--O--CO--R.sub.3 or C.sub.2-4 hydroxyalkyl, with the provisos that R.sub.6 may be any of the last three groups only when R.sub.1 and R.sub.2 are both cyano and that R.sub.6 may be C.sub.2-4 hydroxyalkyl also when R.sub.5 is C.sub.1-2 alkyl,whereinR.sub.7 is phenyl; phenyl substituted by 1 or 2 substituents independently selected from hydroxy, chloro, bromo, methyl and C.sub.1-4 alkoxy; benzyl; benzyl substituted by 1 or 2 substituents independently selected from hydroxy, chloro, bromo, methyl and C.sub.1-4 alkoxy; allyl; haloalkyl; propyn-2-yl or halopropyn-2-yl, with the proviso that R.sub.7 may be allyl, haloallyl, propyn-2-yl or halopropyn-2-yl only when a is 0;a is 0 or 1; andn is 2 or 3,processes for their preparation and their use for dyeing and printing textiles comprising synthetic or semi-synthetic, hydrophobic, high molecular weight materials, e.g., linear aromatic polyester, cellulose 21/2 acetate, cellulose triacetate and synthetic polyamides, by, for example, the rapid dyeing procedure.

Abstract translation: 其中R1是硝基或氰基的式“IMAGE”的化合物; R2是氰基或卤素; R3是C1-4烷基; R4是甲基或乙基; R5是C1-8烷基; 和R6是-CH2CHOHCH2O（CH2CH2O）aR7，-CH2CHOHC6H5，-CH（C6H5）CH2OH; - （CH 2）n O-CO-NHR 3，-CH 2 CH（R 4）-O-CO-NHR 3; - （CH 2）n O-CO-R 3，-CH 2 CH（R 4）-O-CO-R 3或C 2-4 -4-羟基烷基，条件是R 6可以是仅当R 1和R 2都是氰基时，R 6可以是最后三个基团中的任何一个， 当R 5是C 1-2烷基时，也可以是C 2-4的羟基烷基，其中R 7是苯基; 被1或2个独立地选自羟基，氯，溴，甲基和C 1-4烷氧基的取代基取代的苯基; 苄基; 被1或2个独立地选自羟基，氯，溴，甲基和C 1-4烷氧基的取代基取代的苄基; 烯丙基 卤代烷基 丙炔-2-基或卤代丙炔-2-基，条件是仅当a为0时，R 7可为烯丙基，卤代烯丙基，丙炔-2-基或卤代丙炔-2-基; a是0或1; n为2或3，其制备方法及其用于染色和印花纺织品的方法包括合成或半合成，疏水，高分子量材料，例如线性芳族聚酯，21/2乙酸纤维素，三醋酸纤维素和合成聚酰胺 通过例如快速染色方法。

公开(公告)号：US4307015A

公开(公告)日：1981-12-22

申请号：US70762

申请日：1979-08-30

Applicant: Klaus Koerte

Inventor： Klaus Koerte

IPC: C09B29/01 ,  C09B29/08 ,  C09B29/095 ,  C09B29/26 ,  D06P3/36

CPC classification number: C09B29/0813 ,  C09B29/0003 ,  C09B29/095

Abstract: Compounds of the formula ##STR1## wherein D is a diazo component radical,K is the radical of a coupling component of the 1,4-phenylene or 1,4-naphthylene series,R.sub.1 is hydrogen; alkyl; or alkenyl; and when K is a coupling component radical of the 1,4-phenylene series, R.sub.1 is also alkenyl monosubstituted by halogen; or alkyl which is substituted by a halogen, hydroxy, alkoxy, acyloxy, phenyl, phenoxy, cyano, alkenyloxy, alkynyloxy or alkoxyalkynyloxy group and is optionally further substituted by a hydroxy group,R.sub.2 is hydrogen, acyl, alkyl or alkyl monosubstituted by halogen, alkoxy, phenyl, phenoxy, benzyloxy, hydroxy or acyloxy and ##STR2## with the proviso that when R.sub.4 is ##STR3## K is a coupling component radical of the 1,4-naphthylene series, R.sub.5 is hydrogen, or ##STR4## each of R.sub.3 and R.sub.3 ' is independently hydrogen or alkyl, or R.sub.3 and R.sub.3 ' together with the carbon atom to which they are bound form a cyclohexane ring, with the proviso that when R.sub.3 and R.sub.3 ' form a cyclohexane R.sub.5 is hydrogen,one ofR.sub.6 and R.sub.6 ' is hydrogen and the other is hydrogen or halogen,R.sub.7 is hydrogen or alkyl,each ofR.sub.8 and R.sub.8 ' independently, is hydrogen or alkyl andR.sub.9 is hydrogen, acyl, alkyl or alkyl monosubstituted by alkoxy, alkoxyalkoxy or acyloxy,wherein all alkyl and alkoxy moieties contain 1 to 6 carbon atoms, and all alkenyl and alkynyl moieties contain 2-6 carbon atoms, which compounds are useful as disperse dyes for dyeing or printing substrates comprising synthetic or semi-synthetic, hydrophobic, high molecular weight organic textile materials.

Abstract translation: 其中D是重氮组分基团的式“IMAGE”的化合物，K是1,4-亚苯基或1,4-亚萘基系列的偶联组分的基团，R 1是氢; 烷基; 或烯基; 当K是1,4-亚苯基系的偶联成分基团时，R 1也是被卤素单取代的烯基; 或被卤素，羟基，烷氧基，酰氧基，苯基，苯氧基，氰基，烯氧基，炔氧基或烷氧基炔基氧基取代的烷基，并且任选被羟基进一步取代，R 2是氢，酰基，被卤素单取代的烷基或烷基， 烷氧基，苯基，苯氧基，苄氧基，羟基或酰氧基和，条件是当R4是1,4-亚萘基系列的偶联组分基团时，R 5是氢或每个 R 3和R 3'独立地是氢或烷基，或者R 3和R 3'与它们所连接的碳原子一起形成环己烷环，条件是当R 3和R 3'形成环己烷时，R 5是氢，R 6和 R 6'是氢，另一个是氢或卤素，R 7是氢或烷基，R 8和R 8'各自独立地是氢或烷基，R 9是氢，酰基，被烷氧基，烷氧基烷氧基或酰氧基单取代的烷基或烷基，其中全部 烷基和烷氧基部分含有1至6个碳原子，和a 烯基和炔基部分含有2-6个碳原子，该化合物可用作用于染色或印刷包含合成或半合成，疏水，高分子量有机纺织材料的基材的分散染料。

公开(公告)号：US5401834A

公开(公告)日：1995-03-28

申请号：US81927

申请日：1993-06-22

Applicant: Klaus Koerte

Inventor： Klaus Koerte

IPC: C09B45/16 ,  C09B45/14 ,  C09B45/20 ,  C09B67/22 ,  D06P1/10 ,  C09B45/06 ,  C23C22/26

CPC classification number: C09B45/14

Abstract: Complexes of the formula ##STR1## which are in free acid or salt form, and mixtures thereof, wherein each ofR.sub.1 and R.sub.3 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy, amino, sulfo or carboxy,each ofR.sub.2 and R.sub.4 is independently hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by hydroxy, amino, sulfo or carboxy; --COR.sub.5 ; --COOR.sub.6 or --CONHR.sub.7,M is chromium or cobalt, andM.sub.K.sup..sym. is hydrogen or a non-chromophoric cation, useful for dyeing or printing, materials such as natural and synthetic polyamides and particularly artificially produced oxide layers on aluminum and aluminum alloys.

Abstract translation: 具有游离酸或盐形式的式[IMAGE]的络合物及其混合物，其中R 1和R 3各自独立地是氢，C 1-4烷基或被羟基，氨基，磺基或羧基单取代的C 1-4烷基，每个 R2和R4独立地是氢; C 1-4烷基; 被羟基，氨基，磺基或羧基单取代的C 1-4烷基; -COR5; -COOR6或-CONHR7，M为铬或钴，MK（+）为氢或非发色阳离子，可用于染色或印刷，材料如天然和合成聚酰胺，特别是人造生产的铝和铝合金氧化物层 。

公开(公告)号：US4439362A

公开(公告)日：1984-03-27

申请号：US813485

申请日：1977-07-07

Applicant: Klaus Koerte

Inventor： Klaus Koerte

IPC: C09B29/08 ,  C09B29/06 ,  C09B31/04 ,  C09B43/00 ,  C09B29/36 ,  C09B31/14 ,  D06P3/26 ,  D06P3/54

CPC classification number: C09B43/00 ,  C09B29/06 ,  C09B31/04

Abstract: Compounds of the formula ##STR1## in which D is a diazo component radical,K is unsubstituted or substituted 1,4-phenylene or 1,4-naphthylene,R.sub.1 is, in the case where K is unsubstituted or substituted 1,4-phenylene, hydrogen, (C.sub.1-4)alkyl, C.sub.2-4 alkenyl, ##STR2## or (C.sub.2-4)alkyl or (C.sub.2-4)alkenyl monosubstituted by chlorine, bromine, hydroxy, cyano, (C.sub.1-4)alkoxy, phenoxy, phenyl, formyloxy, alkyl(C.sub.1-4)carbonyloxy, benzoyloxy, alkoxy(C.sub.1-4)carbonyl, alkoxy(C.sub.1-4 alkoxy)carbonyloxy, mono(C.sub.1,4 -alkyl)aminocarbonyloxy or dialkyl(C.sub.1-4)aminocarbonyloxy, or in the case where K is unsubstituted or substituted 1,4-naphthylene, R.sub.1 is hydrogen, C.sub.1-4 alkyl or (C.sub.2-4)alkenyl,R.sub.2 is (C.sub.1-4)alkylene or C.sub.2-4 alkylene-O-C.sub.2-4 alkylene, and where R.sub.1 is ##STR3## the R.sub.2 's are identical, are useful as disperse dyes for dyeing and printing synthetic and semi-synthetic, hydrophobic, high molecular weight organic materials such as linear aromatic polyesters, cellulose 21/2 acetate, cellulose triacetate and synthetic polyamides. The obtained dyeings possess notable fastness to light, sublimation, pressing and wet treatments.

Abstract translation: 其中D是重氮组分基团的式“IMAGE”的化合物，K是未取代的或取代的1,4-亚苯基或1,4-亚萘基，在K是未取代的或取代的1,4-亚苯基的情况下，R 1是 ，（C 1-4）烷基，C 2-4烯基，（C 2-4）烷基或被氯，溴，羟基，氰基，（C 1-4）烷氧基，苯氧基， 苯基，甲酰氧基，（C 1-4）羰基氧基，苯甲酰氧基，烷氧基（C 1-4）羰基，烷氧基（C 1-4烷氧基）羰基氧基，单（C 1-4烷基）氨基羰基氧基或二烷基（C 1-4）氨基羰基氧基， 其中K为未取代或取代的1,4-亚萘基，R1为氢，C1-4烷基或（C2-4）烯基，R2为（C1-4）亚烷基或C2-4亚烷基-O-C2-4亚烷基，其中 R1是，R2是相同的，可用作染色和印刷合成和半合成，疏水，高分子量有机材料如线性芳族聚酯，纤维素21/2乙酸酯，三乙酸纤维素和合成聚酰胺的分散染料 s。 获得的染色具有显着的耐光牢度，升华，压制和湿润处理。