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    POLYMERIZATION FLUID, METHOD FOR PRODUCING THE POLYMERIZATION FLUID, TRANSPARENT FILM AND TRANSPARENT ELECTRODE MADE FROM THE POLYMERIZATION FLUID
    2.
    发明申请
    POLYMERIZATION FLUID, METHOD FOR PRODUCING THE POLYMERIZATION FLUID, TRANSPARENT FILM AND TRANSPARENT ELECTRODE MADE FROM THE POLYMERIZATION FLUID 有权
    聚合流体，聚合流体生产方法，透明膜和透明电极从聚合流体

    公开(公告)号：US20130037411A1

    公开(公告)日：2013-02-14

    申请号：US13582282

    申请日：2011-03-01

    申请人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

    发明人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

    IPC分类号： C25D9/02 ,  B32B27/00 ,  C25D7/00

    CPC分类号： H01G9/028 ,  C08G61/126 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/44 ,  H01B1/127 ,  H01G11/56 ,  H05B33/28 ,  Y02E60/13

    摘要： Disclosed is a polymerization fluid for electropolymerization which exhibits a reduced environmental burden and excellent economic efficiency and which can yield a conductive polymer film that has high conductivity and that is dense and highly transparent. The polymerization fluid includes at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes which is dispersed as oil drops in surfactant-free water, and the polymerization fluid is transparent. The polymerization fluid can be produced by a method which includes: an addition step of adding the monomer to surfactant-free water to prepare a phase separation fluid where water and the monomer are phase-separated; a first dispersion step of irradiating the phase separation fluid with ultrasonic waves to make the monomer dispersed in the form of oil drops and thus prepare an opaque dispersion, and a second dispersion step of irradiating the opaque dispersion with ultrasonic waves having a frequency higher than that of the ultrasonic waves used in the first dispersion step to reduce the mean size of the oil drops of the monomer and thus prepare a transparent dispersion.

    摘要翻译： 公开了用于电聚合的聚合流体，其具有降低的环境负担和优异的经济效率，并且可以产生具有高导电性并且致密和高度透明的导电聚合物膜。 聚合流体包括至少一种选自3,4-二取代噻吩的单体，其以油滴分散在不含表面活性剂的水中，聚合流体是透明的。 聚合流体可以通过以下方法制备：将单体添加到无表面活性剂的水中以制备其中水和单体相分离的相分离流体的添加步骤; 第一分散步骤，用超声波照射相分离液，使单体以油滴的形式分散，从而制备不透明的分散体;第二分散步骤，用频率高于其的频率的超声波照射不透明分散体。 的第一分散步骤中使用的超声波，以减少单体的油滴的平均尺寸，从而制备透明分散体。

    Polymerization fluid, method for producing the polymerization fluid, transparent film and transparent electrode made from the polymerization fluid
    3.
    发明授权
    Polymerization fluid, method for producing the polymerization fluid, transparent film and transparent electrode made from the polymerization fluid 有权
    聚合流体，聚合流体的制造方法，由聚合流体制成的透明膜和透明电极

    公开(公告)号：US08927683B2

    公开(公告)日：2015-01-06

    申请号：US13582282

    申请日：2011-03-01

    申请人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

    发明人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

    IPC分类号： C08G75/00 ,  H01G9/028 ,  C08G61/12 ,  H01B1/12 ,  H05B33/28 ,  H01G11/56

    CPC分类号： H01G9/028 ,  C08G61/126 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/44 ,  H01B1/127 ,  H01G11/56 ,  H05B33/28 ,  Y02E60/13

    摘要： Disclosed is a polymerization fluid for electropolymerization which exhibits a reduced environmental burden and excellent economic efficiency and which can yield a conductive polymer film that has high conductivity and that is dense and highly transparent. The polymerization fluid includes at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes which is dispersed as oil drops in surfactant-free water, and the polymerization fluid is transparent. The polymerization fluid can be produced by a method which includes: an addition step of adding the monomer to surfactant-free water to prepare a phase separation fluid where water and the monomer are phase-separated; a first dispersion step of irradiating the phase separation fluid with ultrasonic waves to make the monomer dispersed in the form of oil drops and thus prepare an opaque dispersion, and a second dispersion step of irradiating the opaque dispersion with ultrasonic waves having a frequency higher than that of the ultrasonic waves used in the first dispersion step to reduce the mean size of the oil drops of the monomer and thus prepare a transparent dispersion.

    摘要翻译： 公开了用于电聚合的聚合流体，其具有降低的环境负担和优异的经济效率，并且可以产生具有高导电性并且致密和高度透明的导电聚合物膜。 聚合流体包括至少一种选自3,4-二取代噻吩的单体，其以油滴分散在不含表面活性剂的水中，聚合流体是透明的。 聚合流体可以通过以下方法制备：将单体添加到无表面活性剂的水中以制备其中水和单体相分离的相分离流体的添加步骤; 第一分散步骤，用超声波照射相分离液，使单体以油滴的形式分散，从而制备不透明的分散体;第二分散步骤，用频率高于其的频率的超声波照射不透明分散体。 的第一分散步骤中使用的超声波，以减少单体的油滴的平均尺寸，从而制备透明分散体。