公开(公告)号：US4460701A

公开(公告)日：1984-07-17

申请号：US482059

申请日：1983-04-05

申请人： Minoru Terano ,  Kouhei Kimura ,  Atsushi Murai ,  Masuo Inoue ,  Katsuyoshi Miyoshi

发明人： Minoru Terano ,  Kouhei Kimura ,  Atsushi Murai ,  Masuo Inoue ,  Katsuyoshi Miyoshi

IPC分类号： C08F4/00 ,  C08F4/10 ,  C08F4/16 ,  C08F4/60 ,  C08F4/64 ,  C08F4/65 ,  C08F10/00 ,  C08F4/02

CPC分类号： C08F10/00

摘要： A process for the preparation of the former catalyst component of a catalyst for the polymerization of olefins composed of a titanium-based catalyst component and an organo aluminium compound is disclosed, which process comprises suspending (a) a fatty acid salt of magnesium and (b) dialkoxymagnesium into (c) a liquid halogenated hydrocarbon to form a first suspension, and adding said first suspension to (d) a titanium halide of the general formula: TiX.sub.4, wherein X represents a halogen atom, to be contacted for reaction to form a first reaction mixture, (e) an electron donor compound being present in at least one of the first suspension, the titanium halide and the first reaction mixture; or suspending the dialkoxymagnesium into the liquid halogenated hydrocarbon to form a second suspension, and adding said second suspension to a mixture of the titanium halide and the fatty acid salt of magnesium to be contacted for reaction to form a second reaction mixture, the electron donor compound being present in at least one of the second suspension, the mixture of the titanium halide and the fatty acid salt of magnesium, and the second reaction mixture.In the polymerization of olefins by use of the former catalyst component, both the amount of catalyst residues in the produced polymer and halogen content therein are greatly reduced with high polymerization activity per unit weight of the former catalyst component and with high yield of stereoregular polymer.

摘要翻译： 公开了制备由钛基催化剂组分和有机铝化合物组成的烯烃聚合催化剂的前催化剂组分的方法，该方法包括将（a）镁的脂肪酸盐和（b ）二烷氧基镁转化为（c）液体卤代烃以形成第一悬浮液，并将所述第一悬浮液加入到（d）通式TiX 4的卤化钛，其中X表示卤素原子，以进行反应以形成 第一反应混合物，（e）电子给体化合物存在于第一悬浮液，卤化钛和第一反应混合物中的至少一种中; 或将二烷氧基镁悬浮到液体卤代烃中以形成第二悬浮液，并将所述第二悬浮液加入到待接触的卤化钛和镁的脂肪酸盐的混合物中以形成第二反应混合物，电子给体化合物 存在于第二悬浮液，卤化钛和镁的脂肪酸盐的混合物中的至少一种和第二反应混合物中。 在通过使用前述催化剂组分的烯烃聚合中，所制备的聚合物中的催化剂残余物的量和其中的卤素含量都大大降低，而单一重量的前一种催化剂组分具有高的聚合活性，并且立体有规聚合物的产率高。

公开(公告)号：US4439537A

公开(公告)日：1984-03-27

申请号：US390858

申请日：1982-06-22

申请人： Atsushi Murai ,  Minoru Terano ,  Yoshikazu Hitosugi ,  Kouhei Kimura ,  Masuo Inoue ,  Katsuyoshi Miyoshi

发明人： Atsushi Murai ,  Minoru Terano ,  Yoshikazu Hitosugi ,  Kouhei Kimura ,  Masuo Inoue ,  Katsuyoshi Miyoshi

IPC分类号： C08F4/10 ,  C08F4/16 ,  C08F4/64 ,  C08F4/646 ,  C08F4/65 ,  C08F10/00 ,  G09B15/02

CPC分类号： C08F10/00

摘要： A process for the preparation of the former catalyst component of a catalyst for the polymerization of olefins composed of a titanium-based catalyst component and an organo aluminium compound is disclosed.The former catalyst component can readily be produced by contacting (a) a fatty acid salt of magnesium, (b) an electron donor compound and (c) a titanium halide.In the polymerization of olefins by use of the former catalyst component, both the amount of catalyst residues in the produced polymer and halogen content therein are greatly reduced with high polymerization activity per unit weight of the former catalyst component and with high yield of stereoregular polymer.

摘要翻译： 公开了制备由钛基催化剂组分和有机铝化合物组成的烯烃聚合催化剂的前催化剂组分的方法。 前一种催化剂组分可以容易地通过使（a）镁的脂肪酸盐，（b）电子给体化合物和（c）卤化钛）接触来制备。 在通过使用前述催化剂组分的烯烃聚合中，所制备的聚合物中的催化剂残余物的量和其中的卤素含量都大大降低，而单一重量的前一种催化剂组分具有高的聚合活性，并且立体有规聚合物的产率高。

公开(公告)号：US4562173A

公开(公告)日：1985-12-31

申请号：US675557

申请日：1984-11-28

申请人： Minoru Terano ,  Kouhei Kimura ,  Atsushi Murai ,  Masuo Inoue ,  Katsuyoshi Miyoshi

发明人： Minoru Terano ,  Kouhei Kimura ,  Atsushi Murai ,  Masuo Inoue ,  Katsuyoshi Miyoshi

IPC分类号： C08F4/00 ,  C08F4/10 ,  C08F4/16 ,  C08F4/58 ,  C08F4/60 ,  C08F4/64 ,  C08F4/646 ,  C08F4/65 ,  C08F4/658 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A catalyst for the polymerization of olefins comprising:(A) a catalyst component obtained by a process comprising contacting (a) a fatty acid salt of magnesium, (b) a carbonate of magnesium or a substance containing said carbonate, (c) diester of an aromatic dicarboxylic acid, and (d) a titanium halide of the general formula: TiX.sub.4, wherein X represents a halogen atom;(B) a silicon compound represented by the general formula: SiR.sub.m (OR').sub.4-m, wherein R is hydrogen, alkyl group or aryl group, R' is alkyl group or aryl group, and m is represented as O.ltoreq.m.ltoreq.4; and(C) an organoaluminium compound.Polymerization of olefins by use of the catalyst provides such advantages as high polymerization activity per unit weight of the catalyst component, prolonged polymerization activity, high yield of stereoregular polymer, and a produced polymer free of such an estereal odor as in the prior art, and having high bulk density as well as uniform particle size and shape.

摘要翻译： 一种用于烯烃聚合的催化剂，包括：（A）通过以下方法获得的催化剂组分，该方法包括：（a）镁的脂肪酸盐，（b）镁的碳酸盐或含有所述碳酸酯的物质，（c） 芳族二羧酸和（d）通式TiX 4的卤化钛，其中X表示卤素原子; （B）由通式SiRm（OR'）4-m表示的硅化合物，其中R是氢，烷基或芳基，R'是烷基或芳基，m表示为O m

公开(公告)号：US4332697A

公开(公告)日：1982-06-01

申请号：US216766

申请日：1980-12-15

申请人： Kouhei Kimura ,  Hiroyasu Ohba ,  Atsushi Murai

发明人： Kouhei Kimura ,  Hiroyasu Ohba ,  Atsushi Murai

IPC分类号： C08F4/02 ,  C08F4/46 ,  C08F4/50 ,  C08F4/64 ,  C08F4/652 ,  C08F10/00

CPC分类号： C08F4/022 ,  C08F10/00

摘要： Disclosed is a process for the preparation of the former catalyst component of a catalyst for the polymerization of .alpha.-olefins composed of a titanium-based catalyst component and an organo aluminium compound. According to the above process, a magnesium halide is copulverized with aluminium isopropoxide to form a first copulverization product, to which an electron donor compound is added for copulverization to form a second copulverization product, and the second copulverization product is brought into contact with a titanium halide followed by washing with an inert organic solvent.In the polymerization of .alpha.-olefins by use of the former catalyst component as above, both polymerization activity per unit weight of the catalyst component and yield of stereoregular polymers are remarkably increased.

摘要翻译： 公开了一种制备用于聚合由钛基催化剂组分和有机铝化合物组成的α-烯烃的催化剂的前催化剂组分的方法。 根据上述方法，将卤化镁与异丙醇铝共烧以形成第一共混物，向其中加入电子给体化合物以共混以形成第二共沉积产物，并将第二共沉积产物与钛 卤化物，然后用惰性有机溶剂洗涤。 在通过使用如上所述的前述催化剂组分的α-烯烃的聚合中，催化剂组分的每单位重量的聚合活性和立体规则聚合物的产率都显着增加。