Hydrogen storage materials and method of making same
    1.
    发明授权
    Hydrogen storage materials and method of making same 失效
    储氢材料及其制备方法

    公开(公告)号:US4431561A

    公开(公告)日:1984-02-14

    申请号:US372665

    申请日:1982-04-28

    Abstract: A material for reversibly storing hydrogen is formed from a lightweight matrix which is chemically and structurally modified to improve its hydrogen storage properties. The utilization of a material which can be any of a number of different disordered structures makes possible the modification of local order chemical environments of the material to increase hydrogen storage capacity and/or improve absorption and desorption properties. Lightweight modifier elements structurally modify the local chemical environments of the matrix to provide a material having an increased density of storage sites to increase hydrogen storage capacity. Transition and rare earth modifier elements structurally modify the local chemical environments to provide a material with an increased density of catalytically active sites for dissociating hydrogen molecules to increase the rate at which hydrogen absorption and desorption can be accomplished. The transition and rare earth modifier elements also structurally modify local order chemical environments to provide sites which store hydrogen atoms at lower bond energies to significantly reduce hydrogen desorption temperatures.

    Abstract translation: 用于可逆地储存氢的材料由化学和结构改性以改善其储氢性质的轻质基体形成。 可以使用可以是多种不同无序结构中的任何一种的材料使得可以改变材料的局部顺序化学环境以增加储氢能力和/或改善吸收和解吸性能。 轻质改性剂元素结构上改变基质的局部化学环境,以提供具有增加的储存位置密度以增加储氢容量的材料。 过渡和稀土改性剂元件结构上改变局部化学环境,以提供具有增加的用于解离氢分子的催化活性位点的密度的材料,以提高可以实现氢吸收和解吸的速率。 过渡和稀土改性剂元素还在结构上改变局部顺序化学环境以提供在较低键能下存储氢原子的位点,以显着降低氢解吸温度。

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