摘要:
Disclosed is a composite transition metal precursor for a cathode active material containing Ni and at least one transition metal, wherein a molar amount of Ni is 60% or more based on a total amount of transition metal and a ratio (I101/I001) of an intensity of a (101) plane to an intensity of a (001) plane ranges from 0.7 to 1.1 in XRD analysis.
摘要:
Disclosed, as a particle for cathode active materials, is a novel one-body particle for cathode active materials, including a core of lithium transition metal oxide containing Ni and a surface-layer portion formed on at least a part of the core, wherein the surface-layer portion contains both Co and a structure-stabilizing element, the core is present as a non-aggregated primary particle, and the structure-stabilizing element has a bond dissociation energy (BDE) with oxygen (O) greater than a bond dissociation energy (BDE) of Co and oxygen (O).
摘要:
Disclosed is a coating material for coating a surface of a kiln for preparing an active material, the coating material being represented by the following Formula 1: NiaXz (1) wherein an equation of a+z=1 is satisfied, with the proviso that 0.2≤a
摘要:
Disclosed are novel precursor particles for preparing a cathode active material including transition metal precursor particles containing one or more transition metals, and one or more of an alkali metal and an alkaline earth metal, wherein the alkali metal and the alkaline earth metal are contained in one or more of inner and outer parts of the transition metal precursor particles, and a novel precursor powder including the novel precursor particles.
摘要:
The present invention relates to a cathode active material, and a lithium secondary battery comprising the same, the present invention provides a cathode active material, represented by the following Chemical Formula 1, wherein I003/I104 ratio is 1.6 or more, and R-factor value represented by the following Formula 1 is 0.40 to 0.44, and c-axis lattice constant (c) and a-axis lattice constant (a) satisfy 3(a)+5.555≤(c)≤3(a)+5.580: R-factor=(I102+I006)/(I101) Formula 1 wherein I003, I006, I101, I102, and I104 are the intensity of diffraction peaks on the (003), (006), (101), (102), and (104) planes by X-ray diffraction analysis using CuKα-rays, Liα[(NixCoy)1-βAβ]Oz Chemical Formula 1 in the Chemical Formula 1, 0.95≤α≤1.1, 0.75≤x≤0.95, 0.03≤y≤0.25, 0
摘要:
The present invention relates to a metal oxide powder, a method of preparing the same, and a lithium secondary battery using the same, which comprises: a metal oxide powder is represented by Formula (1), Lix(M1-m-zAmDz)Ot Formula (1) in the above Formula (1), 0.85≤x≤1.2, 0≤m≤0.01, 0 3.5.
摘要:
In an embodiment of the present invention, a positive active material for a lithium secondary battery is represented by Formula 1, and includes a core including a compound having a core portion and a surface portion, and the compound has a lower L3/L2 intensity ratio of Ni in the surface portion than an L3/L2 intensity ratio of Ni in the core portion. Li[LizA(1-z-a)Da]EbO2-b [Formula 1] (In the above formula (1), A is NiαCoβMnγ, D is at least one element selected from the group consisting of Na, K, Mg, Ca, Sr, Ni, Co, Ti, Al, B, Si, Sn, Mn, Cr, Fe, V, Zr, Nb, and Mo, E is at least one element selected from the group consisting of P, F, and S, −0.05≤z≤0.1, 0≤a≤0.05, 0≤b≤0.05, 0.3≤α≤0.9, 0.05≤β≤0.4, and 0.05≤γ≤0.4.)(The L3/L2 intensity ratio of Ni is the oxidation number of Ni measured by electronic energy loss spectroscopy (EELS).).
摘要:
Disclosed are a method for preparing a positive electrode active material for a lithium secondary battery and a positive electrode active material for a lithium secondary battery, the method including: preparing a mixture of a precursor represented by Chemical Formula 1 below, a lithium composite oxide represented by Chemical Formula 2 below and capable of intercalating/deintercalating lithium ions, and a lithium feed material; and firing the prepared mixture: A(OH)2-a [Chemical Formula 1] Li[LizA(1-z-a)Da]EbO2-b [Chemical Formula 2]
摘要:
There are provided a cathode active material for a lithium secondary battery, a method of preparing the same, and a lithium secondary battery containing the same. The cathode active material for a lithium secondary battery includes: a compound reversibly intercalating and deintercalating lithium; and a coating layer positioned on at least a portion of a surface of the compound, wherein the coating layer is a composite coating layer containing Li3PO4 and LiF, and further containing a lithium metal compound, a metal oxide, a metal fluoride compound, and/or a combination thereof.
摘要翻译:提供了一种用于锂二次电池的正极活性材料,其制备方法和含有它的锂二次电池。 锂二次电池用正极活性物质包括:可逆地嵌入和脱嵌锂的化合物; 以及位于所述化合物的表面的至少一部分上的涂层,其中所述涂层是含有Li 3 PO 4和LiF的复合涂层,并且还含有锂金属化合物,金属氧化物,金属氟化物和/ 或其组合。
摘要:
Disclosed is a transition metal-containing precursor for preparing a cathode active material for a lithium secondary battery, wherein the transition metal-containing precursor includes a first precursor and a second precursor having an average particle diameter (D50) smaller than that of the first precursor, and has a ratio of a BET of the first precursor to a BET of the second precursor (BET of first precursor/BET of second precursor) of 0.3 to 3.5.