公开(公告)号：US06436269B1

公开(公告)日：2002-08-20

申请号：US09691985

申请日：2000-10-19

申请人： Vincent C. Opaskar ,  Lee Desmond Capper

发明人： Vincent C. Opaskar ,  Lee Desmond Capper

IPC分类号： C25D360

CPC分类号： C25D3/60

摘要： The present invention relates to an aqueous plating bath for electrodeposition of tin-zinc alloys comprising at least one bath-soluble stannous salt, at least one bath soluble zinc salt, and a quaternary ammonium polymer selected from a ureylene quaternary ammonium polymer, an iminoureylene quaternary ammonium polymer or a thioureylene quaternary ammonium polymer. The plating baths also may contain one or more of the following additives: hydroxy polycarboxylic acids or salts thereof such as citric acid; ammonium salts; conducting salts; aromatic carbonyl-containing compounds; polymers of aliphatic amines such as a poly(alkyleneimine); and hydroxyalkyl substituted diamines as metal complexing agents. The plating baths of this invention deposit a bright and level deposit, and they can be adapted to provide plated alloys having high tin concentration over a wide current density range.

摘要翻译： 本发明涉及一种用于电沉积锡 - 锌合金的含水电镀液，其包含至少一种可溶溶的亚锡盐，至少一种溶液可溶性锌盐和季铵聚合物，所述季铵聚合物选自脲芳季铵聚合物，亚氨基亚乙基季铵 铵聚合物或硫脲类季铵聚合物。 电镀浴还可以含有一种或多种以下添加剂：羟基多元羧酸或其盐如柠檬酸; 铵盐; 导电盐 含芳族羰基的化合物; 脂族胺的聚合物如聚（亚烷基亚胺）; 和羟烷基取代的二胺作为金属络合剂。 本发明的电镀液沉积了明亮的水平沉积物，并且它们可适用于在宽电流密度范围内提供具有高锡浓度的电镀合金。

公开(公告)号：US07442286B2

公开(公告)日：2008-10-28

申请号：US10789175

申请日：2004-02-26

申请人： Lee Desmond Capper ,  Vincent C. Opaskar ,  Paul Christopher Wynn ,  Craig V. Bishop

发明人： Lee Desmond Capper ,  Vincent C. Opaskar ,  Paul Christopher Wynn ,  Craig V. Bishop

IPC分类号： C25D3/56

CPC分类号： C25D3/565

摘要： An electroplating bath, a system, a process for, and the article obtained from, depositing a zinc-nickel ternary or higher alloy, a) zinc ions; b) nickel ions; and c) one or more ionic species selected from ions of Te+4, Bi+3 and Sb+3, and in some embodiments, further including one or more additional ionic species selected from ions of Bi+3, Sb+3, Ag+1, Cd+2, Co+2, Cr+3, Cu+2, Fe+2, In+3, Mn+2, Mo+6, P+3, Sn+2 and W+6. In some embodiments, the system includes a divider forming a cathodic chamber and an anodic chamber, with the electroplating bath in the cathodic chamber only. In various embodiments, the zinc-nickel ternary and higher alloys may provide improved properties to the conductive substrates upon which the alloys are deposited.

摘要翻译： 电镀浴，系统，工艺和从沉积锌 - 镍三元或更高合金得到的制品，a）锌离子; b）镍离子; 和c）选自Te +4，Bi + 3和Sb + 3的离子中的一种或多种离子物质，并且在一些实施方案中， 还包括一种或多种另外的选自Bi +3 +，Sb + 3 +，+，+，+ 2 +，+ + + +， - + - ， - - - - - 在 ^{+3 中，Mn +2，Mo +6，P +3，Sn +2 和W + 6。 在一些实施例中，系统包括形成阴极室和阳极室的分隔器，电镀浴仅在阴极室中。 在各种实施方案中，锌 - 镍三元和更高的合金可以为沉积合金的导电基底提供改进的性能。}