公开(公告)号：US08183183B2

公开(公告)日：2012-05-22

申请号：US12821851

申请日：2010-06-23

申请人： Leiming Li ,  Lijun Lin ,  Curtis L. Boney ,  Michael D. Parris ,  Kevin W. England

发明人： Leiming Li ,  Lijun Lin ,  Curtis L. Boney ,  Michael D. Parris ,  Kevin W. England

IPC分类号： C09K8/68 ,  E21B43/26

CPC分类号： C09K8/685 ,  C09K8/70 ,  C09K8/90 ,  Y10S507/903 ,  Y10S507/904

摘要： A method for treating a subterranean formation is made of steps of providing a composition comprising a carrier fluid, a polymer viscosifying agent, carbon dioxide and a formate salt or formic acid; injecting into a wellbore, the composition; contacting the composition with the subterranean formation, wherein the temperature is above 100 degrees Celsius at this contact; and allowing the composition to treat the subterranean formation.

摘要翻译： 处理地层的方法由提供包含载体流体，聚合物增粘剂，二氧化碳和甲酸盐或甲酸的组合物的步骤制成; 注入井筒，组合物; 使组合物与地层接触，其中该接触温度高于100摄氏度; 并允许组合物处理地层。

公开(公告)号：US08067342B2

公开(公告)日：2011-11-29

申请号：US12122121

申请日：2008-05-16

申请人： Lijun Lin ,  Leiming Li ,  Carlos Abad

发明人： Lijun Lin ,  Leiming Li ,  Carlos Abad

IPC分类号： C09K8/68

CPC分类号： C09K8/602 ,  C09K8/68 ,  C09K8/72 ,  C09K2208/26 ,  C09K2208/30

摘要： Internal breakers are given that break fluids viscosified with non-polymeric viscosifiers such as viscoelastic surfactants, inside formation pores. The breakers are polyols, for example natural and synthetic sugars, monoalcohols, and mixtures of the two. The sugars may be ketones and aldehydes. The sugars are also breaker aides for oxidizing agents used as breakers. Methods of using the breakers and breaker aides in oilfield treatment fluids are given.

摘要翻译： 给出了内部断路器，使用非聚合增粘剂（如粘弹性表面活性剂，内部形成孔隙）粘稠的流体破裂。 断路器是多元醇，例如天然和合成的糖，一元醇和两者的混合物。 糖可以是酮和醛。 这些糖也是用作破碎剂的氧化剂的破碎剂助剂。 给出了在油田处理液中使用断路器和断路器助剂的方法。

公开(公告)号：US20110237470A1

公开(公告)日：2011-09-29

申请号：US12748503

申请日：2010-03-29

申请人： Leiming Li ,  Lijun Lin ,  Oscar Bustos ,  Randy Tercero ,  Mathew M. Samuel

发明人： Leiming Li ,  Lijun Lin ,  Oscar Bustos ,  Randy Tercero ,  Mathew M. Samuel

IPC分类号： C09K8/64 ,  C09K8/68 ,  C09K8/588 ,  C09K8/584

CPC分类号： C09K8/584 ,  C09K8/64 ,  C09K8/703

摘要： A method of decreasing the viscosity of a gelled organic-based fluid is disclosed. The method comprises combining an organic solvent, a gelling agent, and a metal crosslinker; forming the gelled organic-based fluid; and adding a chelating agent forming a complex with the metal to decrease the viscosity of the gelled organic-based fluid. The chelating agent may be chosen within nitrilotriacetic acid (NTA), citric acid; ascorbic acid, hydroxyethylethylenediaminetriacetic acid (HEDTA) or its salts, ethylenediaminetetraacetic acid (EDTA) or its salts, diethylenetriaminepentaacetic acid (DTPA) or its salts, phosphinopolyacrylate, thioglycolates, or a combination thereof.

摘要翻译： 公开了降低凝胶状有机基流体粘度的方法。 该方法包括组合有机溶剂，胶凝剂和金属交联剂; 形成胶凝的有机基流体; 并加入与金属形成络合物的螯合剂以降低胶凝的有机基流体的粘度。 螯合剂可以选择在次氮基三乙酸（NTA），柠檬酸， 抗坏血酸，羟乙基乙二胺三乙酸（HEDTA）或其盐，乙二胺四乙酸（EDTA）或其盐，二亚乙基三胺五乙酸（DTPA）或其盐，膦酸多异丙酯，巯基乙酸酯或其组合。

公开(公告)号：US07923414B2

公开(公告)日：2011-04-12

申请号：US12534901

申请日：2009-08-04

申请人： Lijun Lin ,  Leiming Li ,  Mathew M. Samuel ,  Syed Ali

发明人： Lijun Lin ,  Leiming Li ,  Mathew M. Samuel ,  Syed Ali

IPC分类号： C09K8/22 ,  E21B43/00

CPC分类号： C09K8/035 ,  Y10S507/904

摘要： Embodiments of this invention relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and a polymer, and exposing the fluid to a temperature of about 20° C. to about 200° C., wherein a viscosity is observed that is at least about 5 percent different than if no salt were present. Embodiments of this invention also relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and diutan and/or guar and/or guar derivatives and/or a combination thereof, and exposing the fluid to a temperature of about 20° C. to about 163° C., wherein a viscosity is observed that is at least about 5 percent lower than if no salt were present. Embodiments of this invention also relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and xanthan, and exposing the fluid to a temperature of about 20° C. to about 200° C., wherein a viscosity is observed that is at least about 5 percent higher than if no salt were present.

摘要翻译： 本发明的实施方案涉及用于定制用于油田服务行业的流体的流变学的组合物和方法，包括形成包含四（羟烷基）鏻盐和聚合物的流体，并将流体暴露于 约20℃至约200℃，其中观察到与不存在盐相比至少约5％的粘度。 本发明的实施方案还涉及用于定制用于油田服务行业的流体的流变学的组合物和方法，包括形成包含四（羟烷基）鏻盐和二氘和/或瓜尔胶和/或瓜尔胶衍生物的流体 和/或其组合，并将流体暴露于约20℃至约163℃的温度，其中观察到比不存在盐低至少约5％的粘度。 本发明的实施方案还涉及用于定制用于油田服务行业的流体的流变学的组合物和方法，包括形成包含四（羟基烷基）鏻盐和黄原胶的流体，并将流体暴露于 约20℃至约200℃，其中观察到比不存在盐高至少约5％的粘度。

公开(公告)号：US20110034352A1

公开(公告)日：2011-02-10

申请号：US12534901

申请日：2009-08-04

申请人： Lijun Lin ,  Leiming Li ,  Mathew M. Samuel ,  Syed Ali

发明人： Lijun Lin ,  Leiming Li ,  Mathew M. Samuel ,  Syed Ali

IPC分类号： C09K8/60

CPC分类号： C09K8/035 ,  Y10S507/904

摘要： Embodiments of this invention relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and a polymer, and exposing the fluid to a temperature of about 20° C. to about 200° C., wherein a viscosity is observed that is at least about 5 percent different than if no salt were present. Embodiments of this invention also relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and diutan and/or guar and/or guar derivatives and/or a combination thereof, and exposing the fluid to a temperature of about 20° C. to about 163° C., wherein a viscosity is observed that is at least about 5 percent lower than if no salt were present. Embodiments of this invention also relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and xanthan, and exposing the fluid to a temperature of about 20° C. to about 200° C., wherein a viscosity is observed that is at least about 5 percent higher than if no salt were present.

摘要翻译： 本发明的实施方案涉及用于定制用于油田服务行业的流体的流变学的组合物和方法，包括形成包含四（羟烷基）鏻盐和聚合物的流体，并将流体暴露于 约20℃至约200℃，其中观察到与不存在盐相比至少约5％的粘度。 本发明的实施方案还涉及用于定制用于油田服务行业的流体的流变学的组合物和方法，包括形成包含四（羟烷基）鏻盐和二氘和/或瓜尔胶和/或瓜尔胶衍生物的流体 和/或其组合，并将流体暴露于约20℃至约163℃的温度，其中观察到比不存在盐低至少约5％的粘度。 本发明的实施方案还涉及用于定制用于油田服务行业的流体的流变学的组合物和方法，包括形成包含四（羟基烷基）鏻盐和黄原胶的流体，并将流体暴露于 约20℃至约200℃，其中观察到比不存在盐高至少约5％的粘度。

公开(公告)号：US20110028357A1

公开(公告)日：2011-02-03

申请号：US12511182

申请日：2009-07-29

申请人： Carlos Abad ,  Hemant K. Ladva ,  Lijun Lin ,  Yiyan Chen

发明人： Carlos Abad ,  Hemant K. Ladva ,  Lijun Lin ,  Yiyan Chen

IPC分类号： F15C1/00 ,  C09K8/60

CPC分类号： E21B43/24 ,  C09K8/03 ,  E21B21/06 ,  Y10S507/904 ,  Y10T137/85978

摘要： A method includes performing a chemical process to create a chemical product and an amount of heat, and transferring the heat to a first fluid. The method further includes hydrating a polymer in the first fluid, and adding the chemical product from the chemical process to the first fluid to create a treatment fluid. The method further includes diluting the treatment fluid with respect to at least one constituent of the treatment fluid. The method includes treating a formation of interest in a wellbore with the treatment fluid. The method includes changing a formulation of the treatment fluid during the treating. The method also includes extending the treating beyond a design amount, or ending the treatment before the design amount and preserving some reagents of the chemical process.

摘要翻译： 一种方法包括执行化学过程以产生化学产品和一定量的热量，并将热量传递给第一流体。 该方法还包括将第一流体中的聚合物水合，并将化学产物从化学过程加入到第一流体中以产生处理流体。 该方法还包括相对于处理流体的至少一种成分稀释处理流体。 该方法包括用处理流体处理在井眼中的感兴趣的形成。 该方法包括在处理期间改变处理液的配方。 该方法还包括将处理延伸超过设计量，或在设计量之前结束处理并保留化学过程的一些试剂。

公开(公告)号：US07833949B2

公开(公告)日：2010-11-16

申请号：US12180062

申请日：2008-07-25

申请人： Leiming Li ,  Curtis L. Boney ,  Cody Hanzik ,  Lijun Lin ,  Syed Ali ,  Oscar Bustos

发明人： Leiming Li ,  Curtis L. Boney ,  Cody Hanzik ,  Lijun Lin ,  Syed Ali ,  Oscar Bustos

IPC分类号： C09K8/52 ,  C09K8/588 ,  C09K8/68 ,  E21B43/26

CPC分类号： C09K8/528 ,  C09K8/68 ,  C09K8/685 ,  C09K8/703 ,  C09K8/90 ,  C09K8/94 ,  C09K2208/08

摘要： A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from an aqueous medium, a diutan heteropolysaccharide having a tetrasaccharide repeating unit in the polymer backbone and a peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore may be carried out by introducing the treatment fluid into the formation through the wellbore. Breaking aids or catalysts may also be used with the treatment fluid.

摘要翻译： 用于处理由井筒穿透的地层的处理流体由水性介质，在聚合物主链中具有四糖重复单元的二an杂多糖和过氧化物破坏剂形成。 可以通过将井眼中的处理流体引入到地层中来进行井眼渗透的地层的处理方法。 破碎助剂或催化剂也可与处理液一起使用。

公开(公告)号：US07781380B2

公开(公告)日：2010-08-24

申请号：US11339015

申请日：2006-01-25

申请人： Lijun Lin ,  Alejandro Pena ,  Golchehreh Salamat

发明人： Lijun Lin ,  Alejandro Pena ,  Golchehreh Salamat

IPC分类号： C09K8/68 ,  E21B43/04

CPC分类号： C09K8/68 ,  C09K8/52 ,  C09K8/602 ,  C09K8/703 ,  C09K8/74 ,  C09K8/845 ,  C09K8/86 ,  C09K8/887 ,  C09K8/90 ,  C09K8/905 ,  C09K8/94 ,  C09K2208/26

摘要： Disclosed are methods of treating subterranean formations with rapidly hydratable treatment fluids based upon heteropolysaccharides. In particular, the invention relates to treatment methods with fluids containing a heteropolysaccharide, aqueous medium, and an electrolyte, wherein the fluids may further include a gas component, a surfactant and/or an organoamino compound. The fluids exhibit good rheological properties at elevated temperatures, and unusually rapid hydration rates which allows utilizing such fluids without the need of hydration tanks.

摘要翻译： 公开的是使用基于杂多糖的快速可水合处理流体处理地下地层的方法。 特别地，本发明涉及含有杂多糖，水性介质和电解质的流体的处理方法，其中流体可以进一步包括气体组分，表面活性剂和/或有机氨基化合物。 这些流体在升高的温度下表现出良好的流变性能，并且异常快速的水化速率允许利用这种流体而不需要水化罐。

公开(公告)号：US20100175881A1

公开(公告)日：2010-07-15

申请号：US12354500

申请日：2009-01-15

申请人： Philip F. Sullivan ,  Gary John Tustin ,  Yiyan Chen ,  Lijun Lin

发明人： Philip F. Sullivan ,  Gary John Tustin ,  Yiyan Chen ,  Lijun Lin

IPC分类号： E21B43/00 ,  E21B36/00

CPC分类号： C09K8/52 ,  C09K8/536 ,  C09K2208/28 ,  Y10S507/904

摘要： Methods and apparatus for forming a fluid for use within in a subterranean formation including combining a partitioning agent and viscosifying polymer into a fluid, introducing the fluid into the subterranean formation, and recovering at least a portion of the fluid at a uppermost surface of the subterranean formation. Methods and apparatus of forming a fluid for use within in a subterranean formation including combining a partitioning agent and viscosifying polymer into a fluid, introducing the fluid into the subterranean formation at a temperature of about 45° C. or higher, and recovering at least a portion of the fluid at a uppermost surface of the subterranean formation at a temperature of about 45° C. or lower.

摘要翻译： 用于形成在地层内使用的流体的方法和装置，包括将分配剂和增粘聚合物组合成流体，将流体引入地下地层，以及在地下最上表面处回收至少一部分流体 形成。 形成在地层内使用的流体的方法和装置，包括将分配剂和增粘聚合物混合到流体中，在大约45℃或更高的温度下将流体引入地层，并回收至少一种 部分流体在地下层的最上表面处于约45℃或更低的温度。

公开(公告)号：US07677311B2

公开(公告)日：2010-03-16

申请号：US11532553

申请日：2006-09-18

申请人： Carlos Abad ,  Jesse C. Lee ,  Philip F. Sullivan ,  Erik Nelson ,  Yiyan Chen ,  Belgin Baser ,  Lijun Lin

发明人： Carlos Abad ,  Jesse C. Lee ,  Philip F. Sullivan ,  Erik Nelson ,  Yiyan Chen ,  Belgin Baser ,  Lijun Lin

IPC分类号： E21B43/267 ,  E21B43/27 ,  C09K8/68 ,  C09K8/76

CPC分类号： C09K8/68 ,  C09K8/508 ,  C09K8/5751 ,  C09K8/76 ,  C09K2208/18 ,  C09K2208/26 ,  C09K2208/30 ,  Y10S507/922 ,  Y10S507/923

摘要： A composition and method for improving the fluid efficiency of many oilfield treatments is given. The composition is a solid additive, in a viscosified fluid, in a size range small enough that it enters formation pores; it optionally bridges there to form an internal filter cake, and then decomposes to provide a breaker for the viscosifying system for the fluid. Examples of suitable additives include waxes, polyesters, polycarbonates, polyacetals, polymelamines, polyvinyl chlorides, and polyvinyl acetates. Degradation of the additive may be accelerated or delayed.

摘要翻译： 给出了一种用于提高许多油田处理流体效率的组合物和方法。 该组合物是一种固体添加剂，在粘稠流体中，其尺寸范围足够小，使其进入地层孔; 它可选地在那里桥接以形成内部滤饼，然后分解以提供用于流体的增粘系统的断路器。 合适的添加剂的实例包括蜡，聚酯，聚碳酸酯，聚缩醛，聚蜜胺，聚氯乙烯和聚乙酸乙烯酯。 添加剂的降解可能会加速或延迟。