公开(公告)号：US08784650B2

公开(公告)日：2014-07-22

申请号：US13120366

申请日：2009-07-01

申请人： Minli Cui ,  Jianwei Huang ,  Xu Hao ,  Liren Cao ,  Yongwang Li

发明人： Minli Cui ,  Jianwei Huang ,  Xu Hao ,  Liren Cao ,  Yongwang Li

IPC分类号： C10G1/00 ,  C10G2/00 ,  C10L1/32 ,  C10G65/00 ,  C10G1/06 ,  C10G65/12 ,  C10J3/46

CPC分类号： C10G1/002 ,  C10G1/065 ,  C10G2/30 ,  C10G2/32 ,  C10G65/00 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/304 ,  C10G2300/305 ,  C10G2300/307 ,  C10G2300/308 ,  C10G2300/701 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/28 ,  C10J3/466 ,  C10J2300/0903 ,  C10J2300/0906 ,  C10J2300/093 ,  C10J2300/0959 ,  C10J2300/0973 ,  C10J2300/0989 ,  C10J2300/1659 ,  C10J2300/1678 ,  C10L1/322 ,  Y02E50/32 ,  Y02P30/20 ,  Y02T50/678

摘要： A method for multistage transforming carbonaceous solid fuel to oil, includes mixing solid fuel (17) with heavy oil (40) to obtain fuel-oil slurry; heating and dehydrating of the slurry; liquefying of the slurry by hydrogenation under a low-medium pressure to obtain light oil (25) and heavy oil-residue slurry; hydrorefining the light oil (25) to obtain refined oil; gasifying the heavy oil-residue slurry in a gasifier (11) to obtain syngas (47); producing F-T synthesis oil (52) with the syngas (47); hydrorefining and hydrocracking the F-T synthesis oil (52) to obtain refined oil; mixing the refined oil from the F-T synthesis oil with the refined oil from liquefying by hydrogenation for producing high quality oil with low sulfur and low ammonia, and other chemical product. The method can be applied to various kinds of coals and biomass, especially applied to lignite and biomass. A suspended bed reactor for liquefying of carbonaceous solid fuel by hydrogenation is also disclosed.

摘要翻译： 将含碳固体燃料多级转化为油的方法包括将固体燃料（17）与重油（40）混合以获得燃料油浆料; 加热和脱水浆料; 在低中压下通过氢化液化浆料以获得轻油（25）和重油残渣浆料; 加氢精炼轻油（25）以获得精制油; 在气化器（11）中气化重质残油浆料以获得合成气（47）; 用合成气（47）生产F-T合成油（52）; 加氢精制和加氢裂化F-T合成油（52），得到精制油; 将来自F-T合成油的精制油与精炼油混合，通过氢化液化，生产低硫和低氨等高品质油等化学产品。 该方法可应用于各种煤和生物质，特别适用于褐煤和生物质。 还公开了一种用于通过氢化液化碳质固体燃料的悬浮床反应器。

公开(公告)号：US20100216896A1

公开(公告)日：2010-08-26

申请号：US12527355

申请日：2007-10-12

申请人： Jinsheng Wang ,  Xu Hao ,  Dongxun Liu ,  Liang Bai ,  Liren Cao ,  Yongwang Li

发明人： Jinsheng Wang ,  Xu Hao ,  Dongxun Liu ,  Liang Bai ,  Liren Cao ,  Yongwang Li

IPC分类号： C07C1/04 ,  B01J19/00

CPC分类号： B01J8/44 ,  B01J8/006 ,  B01J8/1818 ,  B01J8/1836 ,  B01J8/22 ,  B01J2208/00194 ,  C10G2/342

摘要： A Fischer-Tropsch synthesis three-phase suspension bed reactor (“suspension bed” also called “slurry bed”) and its supplemental systems, may include: 1) structure and dimension design of F-T synthesis reactor, 2) a gas distributor located at the bottom of the reactor, 3) structure and arrangement of a heat exchanger members inside the reactor, 4) a liquid-solid filtration separation device inside reactor, 5) a flow guidance device inside reactor, 6) a condensate flux and separation member located in the gas phase space at the top of reactor, 7) a pressure stabilizer, a cleaning system for the separation device; an online cleaning system for the gas distributor; an ancillary system for slurry deposition and a pre-condensate and mist separation system located at the outlet of upper reactor. This reactor is suitable for industrial scale application of Fischer-Tropsch synthesis.

摘要翻译： 费 - 托合成三相悬浮床反应器（“悬浮床”也称为“浆料床”）及其补充系统可包括：1）FT合成反应器的结构和尺寸设计，2）位于 反应器底部，3）反应器内部的热交换器部件的结构和布置; 4）反应器内部的液固过滤分离装置; 5）反应器内的流动引导装置，6）位于 反应器顶部的气相空间，7）压力稳定器，分离装置的清洗系统; 用于气体分配器的在线清洁系统; 用于浆料沉积的辅助系统和位于上反应器出口处的预冷凝和雾化分离系统。 该反应器适用于费 - 托合成的工业规模应用。

公开(公告)号：US08506895B2

公开(公告)日：2013-08-13

申请号：US12527355

申请日：2007-10-12

申请人： Jinsheng Wang ,  Xu Hao ,  Dongxun Liu ,  Liang Bai ,  Liren Cao ,  Yongwang Li

发明人： Jinsheng Wang ,  Xu Hao ,  Dongxun Liu ,  Liang Bai ,  Liren Cao ,  Yongwang Li

IPC分类号： C07C27/06 ,  B01J8/08

CPC分类号： B01J8/44 ,  B01J8/006 ,  B01J8/1818 ,  B01J8/1836 ,  B01J8/22 ,  B01J2208/00194 ,  C10G2/342

摘要： A Fischer-Tropsch synthesis three-phase suspension bed reactor (“suspension bed” also called “slurry bed”) and its supplemental systems, may include: 1) structure and dimension design of F-T synthesis reactor, 2) a gas distributor located at the bottom of the reactor, 3) structure and arrangement of a heat exchanger members inside the reactor, 4) a liquid-solid filtration separation device inside reactor, 5) a flow guidance device inside reactor, 6) a condensate flux and separation member located in the gas phase space at the top of reactor, 7) a pressure stabilizer, a cleaning system for the separation device; an online cleaning system for the gas distributor; an ancillary system for slurry deposition and a pre-condensate and mist separation system located at the outlet of upper reactor. This reactor is suitable for industrial scale application of Fischer-Tropsch synthesis.

摘要翻译： 费 - 托合成三相悬浮床反应器（“悬浮床”也称为“浆料床”）及其补充系统可包括：1）FT合成反应器的结构和尺寸设计，2）位于 反应器底部，3）反应器内部的热交换器部件的结构和布置; 4）反应器内部的液固过滤分离装置; 5）反应器内的流动引导装置，6）位于 反应器顶部的气相空间，7）压力稳定器，分离装置的清洗系统; 用于气体分配器的在线清洁系统; 用于浆料沉积的辅助系统和位于上反应器出口处的预冷凝和雾化分离系统。 该反应器适用于费 - 托合成的工业规模应用。

公开(公告)号：US20110174683A1

公开(公告)日：2011-07-21

申请号：US13120366

申请日：2009-07-01

申请人： Minli Cui ,  Jianwei Huang ,  Xu Hao ,  Liren Cao ,  Yongwang Li

发明人： Minli Cui ,  Jianwei Huang ,  Xu Hao ,  Liren Cao ,  Yongwang Li

IPC分类号： C10G69/02 ,  B01J8/00

CPC分类号： C10G1/002 ,  C10G1/065 ,  C10G2/30 ,  C10G2/32 ,  C10G65/00 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/304 ,  C10G2300/305 ,  C10G2300/307 ,  C10G2300/308 ,  C10G2300/701 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/28 ,  C10J3/466 ,  C10J2300/0903 ,  C10J2300/0906 ,  C10J2300/093 ,  C10J2300/0959 ,  C10J2300/0973 ,  C10J2300/0989 ,  C10J2300/1659 ,  C10J2300/1678 ,  C10L1/322 ,  Y02E50/32 ,  Y02P30/20 ,  Y02T50/678

摘要： A method for multistage transforming carbonaceous solid fuel to oil, includes mixing solid fuel (17) with heavy oil (40) to obtain fuel-oil slurry; heating and dehydrating of the slurry; liquefying of the slurry by hydrogenation under a low-medium pressure to obtain light oil (25) and heavy oil-residue slurry; hydrorefining the light oil (25) to obtain refined oil; gasifying the heavy oil-residue slurry in a gasifier (11) to obtain syngas (47); producing F-T synthesis oil (52) with the syngas (47); hydrorefining and hydrocracking the F-T synthesis oil (52) to obtain refined oil; mixing the refined oil from the F-T synthesis oil with the refined oil from liquefying by hydrogenation for producing high quality oil with low sulfur and low ammonia, and other chemical product. The method can be applied to various kinds of coals and biomass, especially applied to lignite and biomass. A suspended bed reactor for liquefying of carbonaceous solid fuel by hydrogenation is also disclosed.

摘要翻译： 将含碳固体燃料多级转化为油的方法包括将固体燃料（17）与重油（40）混合以获得燃料油浆料; 加热和脱水浆料; 在低中压下通过氢化液化浆料以获得轻油（25）和重油残渣浆料; 加氢精炼轻油（25）以获得精制油; 在气化器（11）中气化重质残油浆料以获得合成气（47）; 用合成气（47）生产F-T合成油（52）; 加氢精制和加氢裂化F-T合成油（52），得到精制油; 将来自F-T合成油的精制油与精炼油混合，通过氢化液化，生产低硫和低氨等高品质油等化学产品。 该方法可应用于各种煤和生物质，特别适用于褐煤和生物质。 还公开了一种用于通过氢化液化碳质固体燃料的悬浮床反应器。