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    Color photographic silver halide material
    1.
    发明授权
    Color photographic silver halide material 失效
    彩色照相卤化银材料

    公开(公告)号：US06562557B2

    公开(公告)日：2003-05-13

    申请号：US09908872

    申请日：2001-07-19

    申请人： Klaus Wagner ,  Heinz Schütz ,  Peter Bell ,  Lothar Endres ,  Detlev Kapitza ,  Thomas Stetzer

    发明人： Klaus Wagner ,  Heinz Schütz ,  Peter Bell ,  Lothar Endres ,  Detlev Kapitza ,  Thomas Stetzer

    IPC分类号： G03C146

    CPC分类号： G03C1/29 ,  G03C1/0051 ,  G03C1/18 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/3041 ,  G03C2001/03511 ,  G03C2001/03535 ,  G03C2007/3034 ,  G03C2200/22 ,  G03C2200/35

    摘要： A color photographic material comprising a transparent support, at least one blue-sensitive, predominantly yellow-coupling silver halide emulsion layer, at least one green-sensitive, predominantly magenta-coupling silver halide emulsion layer (PP-1) and at least one red-sensitive, predominantly cyan-coupling silver halide emulsion layer (BG-1), characterised in that the spectral sensitivity distribution of BG-1 is characterised in that 605≦&lgr;max≦630 nm, 0.1≦&Dgr;lgE640≦0.6 and 1.8≦&Dgr;lgE680, wherein &lgr;max represents the wavelength at which the maximum sensitivity occurs, &Dgr;lgE640 represents the difference of the logarithmic sensitivity at &lgr;max minus the logarithmic sensitivity at 640 nm, and &Dgr;lgE680 represents the difference of the logarithmic sensitivity at &lgr;max minus the logarithmic sensitivity at 680 nm, and the sensitivities are determined after exposure and processing of the material at a cyan color density which is formed by coupling with developer oxidation product and which is 0.5 above the minimum density, is distinguished by its high sensitivity to light, its good color reproduction both when taking photographs in standard light and in other types of illumination such as artificial light from fluorescent lamps, its good reproduction of colors such as that of delphinium, and its high stability on storage under humid climatic conditions.

    摘要翻译： 一种彩色照相材料，包括透明载体，至少一种蓝色敏感，主要为黄色偶合的卤化银乳剂层，至少一种感绿，主要是品红色偶合的卤化银乳剂层（PP-1）和至少一种红 敏感的，主要是青色偶联的卤化银乳剂层（BG-1），其特征在于BG-1的光谱灵敏度分布的特征在于其中lambdmax表示最大灵敏度发生的波长，DELTAlgE640表示对数 在lambdmax处的灵敏度减去640nm处的对数灵敏度，DELTAlgE680表示在lambdmax处的对数灵敏度减去680nm处的对数灵敏度之间的差异，并且在形成的青色浓度下的材料曝光和加工后确定敏感度 通过与显影剂氧化产物偶联，其最小密度为0.5以上 由于其对光的高灵敏度，其在标准光和其他类型的照明（例如来自荧光灯的人造光）中拍摄照片时的良好的色彩再现，其诸如雀斑的颜色的良好再现以及其在存储上的高稳定性 在潮湿的气候条件下。

    Color photographic silver halide material
    2.
    发明授权
    Color photographic silver halide material 失效
    彩色照相卤化银材料

    公开(公告)号：US06017689A

    公开(公告)日：2000-01-25

    申请号：US156506

    申请日：1998-09-17

    申请人： Peter Bell ,  Ralf Buscher ,  Lothar Endres ,  Lothar Rosenhahn ,  Rainer Scheerer ,  Lydia Simon ,  Thomas Stetzer

    发明人： Peter Bell ,  Ralf Buscher ,  Lothar Endres ,  Lothar Rosenhahn ,  Rainer Scheerer ,  Lydia Simon ,  Thomas Stetzer

    IPC分类号： G03C7/30 ,  G03C1/46

    CPC分类号： G03C7/3029 ,  G03C2007/3015 ,  G03C2200/12

    摘要： A color photographic silver halide material having at least two blue-sensitive, yellow coupler containing silver halide emulsion layers, at least two green-sensitive, magenta coupler containing silver halide emulsion layers and at least two red-sensitive, cyan coupler containing silver halide emulsion layers together with conventional interlayers and protective layers, wherein photosensitive layers of identical color sensitivity differ with regard to the photographic sensitivity thereof and the more highly sensitive layers are arranged further away from the support than the less sensitive layers of identical color sensitivity, which material contains, in a layer which is arranged further from the support than the most highly sensitive, blue-sensitive layer, both at least one yellow coupler and at least one magenta or cyan coupler, is distinguished by improved grain and sensitivity combined with very good color reproduction.

    摘要翻译： 具有至少两个含有卤化银乳剂层的蓝色敏感的黄色成色剂的彩色照相卤化银材料，至少两种含有卤化银乳剂层的绿色敏感的品红色成色剂和至少两种含有卤化银乳剂的红色敏感的青色成色剂 层与传统的中间层和保护层一起，其中相同颜色敏感度的感光层相对于其感光灵敏度而不同，并且与具有相同色彩敏感度的较不敏感层相比，较高灵敏度层被布置得远离支撑体，该材料含有 ，在比最高灵敏度蓝色敏感层更远的布置的层中，至少一个黄色耦合器和至少一个品红色或青色耦合器，通过改善的纹理和灵敏度以及非常好的色彩再现而被区分开来 。

    Color photographic film
    3.
    发明授权
    Color photographic film 失效
    彩色摄影胶片

    公开(公告)号：US6093524A

    公开(公告)日：2000-07-25

    申请号：US153180

    申请日：1998-09-16

    申请人： Rainer Scheerer ,  Lothar Endres ,  Hans-Ulrich Borst ,  Lydia Simon ,  Thomas Stetzer ,  Peter Bell ,  Lothar Rosenhahn ,  Ralf Buscher

    发明人： Rainer Scheerer ,  Lothar Endres ,  Hans-Ulrich Borst ,  Lydia Simon ,  Thomas Stetzer ,  Peter Bell ,  Lothar Rosenhahn ,  Ralf Buscher

    IPC分类号： G03C7/30 ,  G03C1/46

    CPC分类号： G03C7/3022 ,  G03C7/3029

    摘要： A color photographic film having a support, 2 or 3 red-sensitive, cyan-coupling silver halide emulsion layers, 2 or 3 green-sensitive, magenta-coupling silver halide emulsion layers, 2 or 3 blue-sensitive, yellow-coupling silver halide emulsion layers, conventional interlayers and protective layers together with a yellow filter layer arranged closer to the support than the blue-sensitive layers, wherein at least one green-sensitive silver halide emulsion layer is arranged further away from the support than all the other photosensitive layers, exhibits improved sharpness without color distortion if at least 50% of the projected surface area of the silver halide emulsion of the green-sensitive silver halide emulsion layer, of which there is at least one, consists of tabular silver halide grains having an aspect ratio of at least 3.

    摘要翻译： 具有支持体，2或3个红色敏感的青色偶联的卤化银乳剂层，2或3个绿色敏感的品红色偶联的卤化银乳剂层，2或3个蓝色敏感的黄色偶合卤化银的彩色照相胶片 乳剂层，常规中间层和保护层以及与蓝色敏感层相比布置得更靠近载体的黄色滤光层，其中至少一个感绿卤化银乳剂层比所有其它感光层更远离支撑体布置 如果至少有一个的感光卤化银乳剂层的卤化银乳剂的至少50％的投影表面积由具有纵横比的片状卤化银颗粒组成，则表现出改进的清晰度而没有颜色变形 至少3。

    Process for the production of silver halide emulsions
    6.
    发明授权
    Process for the production of silver halide emulsions 失效
    制备卤化银乳剂的方法

    公开(公告)号：US5604087A

    公开(公告)日：1997-02-18

    申请号：US561172

    申请日：1995-11-21

    申请人： Otto Lapp ,  Lothar Endres ,  Klaus Wagner

    发明人： Otto Lapp ,  Lothar Endres ,  Klaus Wagner

    IPC分类号： C01G5/02 ,  G03C1/015 ,  G03C1/035

    CPC分类号： C01G5/02 ,  G03C1/015 ,  G03C1/035

    摘要： A silver halide having at least two halides of differing atomic numbers may successfully be produced with a more uniform halide distribution within certain zones or throughout the entire volume of the individual grain and from grain to grain, if a portion or the entire quantity of the halide of the higher atomic number is dissolved in an aqueous silver salt solution and the resulting solution is introduced at any stage into the emulsion preparation process.

    摘要翻译： 具有不同原子序数的至少两种卤化物的卤化银可以成功地在单个晶粒的某些区域内或整个体积内从颗粒到晶粒的更均匀的卤化物分布产生，如果卤化物的一部分或全部量 的较高原子序数溶解在银盐水溶液中，并将所得溶液在任何阶段引入乳液制备方法中。

    Color photographic silver halide material
    8.
    发明授权
    Color photographic silver halide material 失效
    彩色照相卤化银材料

    公开(公告)号：US5599657A

    公开(公告)日：1997-02-04

    申请号：US547249

    申请日：1995-10-24

    申请人： Detlef Brennecke ,  Johannes Willsau ,  Ralf B uscher ,  Hans-Ulrich Borst ,  Peter Bell ,  Lothar Endres

    发明人： Detlef Brennecke ,  Johannes Willsau ,  Ralf B uscher ,  Hans-Ulrich Borst ,  Peter Bell ,  Lothar Endres

    IPC分类号： G03C7/00 ,  G03C1/76 ,  G03C7/30 ,  G03C1/46

    CPC分类号： G03C7/3029 ,  G03C7/3022

    摘要： A colour photographic silver halide material with a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler, at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one interlayer Z-1 beneath the lowermost red-sensitive silver halide emulsion layer and/or at least one interlayer Z-2 beneath the lowermost green-sensitive silver halide emulsion layer, in which Z-1 and/or Z-2 contains a silver halide emulsion which contains tabular grains with an aspect ratio of>2, an average diameter of a sphere of equal volume of.gtoreq.0.3 .mu.m and a diameter of a circle of equal projected surface area of the tabular grains of at least 0.3 .mu.m, is distinguished by improved red and/or green sensitivity.

    摘要翻译： 具有载体的彩色照相卤化银材料，至少一种含有至少一种青色成色剂的感红卤化银乳剂层，至少一种含有至少一种品红色成色剂的感绿卤化银乳剂层，至少一种蓝色敏感性 含有至少一个黄色成色剂的卤化银乳剂层，在最下面的感红卤化银乳剂层下方的至少一层中间层Z-1和/或最低感绿卤化银乳剂层下面的至少一层中间层Z-2， Z-1和/或Z-2含有卤化银乳剂，其含有长径比> 2的片状颗粒，等体积大于等于0.3μm的球体的平均直径和 至少0.3μm的片状颗粒的相等投影表面积的特征在于改善的红色和/或绿色感光度。

    Process for the preparation of silver halide emulsions
    9.
    发明授权
    Process for the preparation of silver halide emulsions 失效
    制备卤化银乳剂的方法

    公开(公告)号：US5427904A

    公开(公告)日：1995-06-27

    申请号：US125737

    申请日：1993-09-24

    申请人： Hans-Ulrich Borst ,  Lothar Endres ,  Hans hlschlager

    发明人： Hans-Ulrich Borst ,  Lothar Endres ,  Hans hlschlager

    IPC分类号： G03C1/015 ,  G03C1/035 ,  G03C1/06 ,  G03C1/07 ,  G03C1/34 ,  G03C1/005

    CPC分类号： G03C1/06 ,  G03C1/015 ,  G03C1/07

    摘要： Emulsions having an improved sensitivity/grain ratio are obtained when a silver halide emulsion containing up to 20 mol % of AgI is prepared by the precipitation of a silver halide emulsion A containing up to 100 mol % of AgI and the addition of a silver halide emulsion B which contains up to 40 mol % of AgI, has an average grain size of at most 0.25 .mu.m and is always more soluble in aqueous gelatine solution than emulsion A either due to its grain size or due to its iodide content, this being carried out in the presence of at least two compounds selected from imidazole, histidine (.alpha.-amino-.beta.-imidazolyl-(5)-propionic acid) and other monocyclic, 5- or 6-membered heterocyclic compounds which have at least one ring nitrogen atom, are free from SH groups and form sparingly soluble silver salts in weak acid to neutral aqueous solutions, which salts redissolve at pH>9 when ammonia is added, one of the at least two compounds being imidazole or histidine and at least one other compound being a compound other than imidazole or histidine.

    摘要翻译： 当通过沉淀含有高达100mol％的AgI的卤化银乳剂A和加入卤化银乳剂来制备含有高达20mol％的AgI的卤化银乳剂时，具有改善的灵敏度/晶粒比的乳液 B含有高达40mol％的AgI，其平均粒径至多为0.25μm，并且由于其粒径或由于碘化物含量而总是比乳液A更易溶于水性明胶溶液，因此携带 在存在至少两种选自咪唑，组氨酸（α-氨基-β-咪唑基 - （5） - 丙酸）的化合物和其它具有至少一个环氮原子的单环，5或6元杂环化合物 ，不含SH基团，并在弱酸至中性水溶液中形成微溶银盐，当加入氨时，该盐在pH> 9时再溶解，至少两种化合物之一为咪唑或组氨酸，以及至少一种其他化合物 而不是咪唑或组氨酸以外的化合物。