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公开(公告)号：US08222177B2
公开(公告)日：2012-07-17
申请号：US12865053
申请日：2009-01-28
IPC分类号： B01J31/16 , C07C311/15
CPC分类号： C07C311/16 , B01J31/0212 , B01J31/1805 , B01J2231/348 , B01J2531/21 , B01J2531/22 , B01J2531/23 , B01J2531/24 , B01J2531/25 , C07B53/00 , C07B2200/07 , C07C67/347 , C07C201/12 , C07C2602/10 , C07D207/325 , C07D307/54 , C07D333/24 , C07C69/738 , C07C205/56
摘要： Disclosed is a technology for enabling an efficient asymmetric Michael addition reaction which does not require a large amount of a malonic ester, while having a short reaction time. Specifically disclosed is a catalyst which is composed of MX2 (wherein M is Be, Mg, Ca, Sr, Ba or Ra and X is an arbitrary group) and a compound represented by general formula [I]. [In the formula, R7, R8, R9 and R10 each represents a substituted cyclic group or an unsubstituted cyclic group.]
摘要翻译： 公开了一种能够实现不需要大量丙二酸酯的有效的不对称迈克尔加成反应的技术，同时反应时间短。 具体公开的是由MX2（其中M为Be，Mg，Ca，Sr，Ba或Ra，X为任意基团）和通式[I]表示的化合物组成的催化剂。 [式中，R 7，R 8，R 9，R 10分别表示取代的环状基团或未取代的环状基团。
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公开(公告)号：US20110054190A1
公开(公告)日：2011-03-03
申请号：US12865053
申请日：2009-01-28
IPC分类号： C07D207/02 , C07C67/00 , C07F3/00
CPC分类号： C07C311/16 , B01J31/0212 , B01J31/1805 , B01J2231/348 , B01J2531/21 , B01J2531/22 , B01J2531/23 , B01J2531/24 , B01J2531/25 , C07B53/00 , C07B2200/07 , C07C67/347 , C07C201/12 , C07C2602/10 , C07D207/325 , C07D307/54 , C07D333/24 , C07C69/738 , C07C205/56
摘要： Disclosed is a technology for enabling an efficient asymmetric Michael addition reaction which does not require a large amount of a malonic ester, while having a short reaction time. Specifically disclosed is a catalyst which is composed of MX2 (wherein M is Be, Mg, Ca, Sr, Ba or Ra and X is an arbitrary group) and a compound represented by general formula [I]. [In the formula, R7, R8, R9 and R10 each represents a substituted cyclic group or an unsubstituted cyclic group.]
摘要翻译： 公开了一种能够实现不需要大量丙二酸酯的有效的不对称迈克尔加成反应的技术，同时反应时间短。 具体公开的是由MX2（其中M为Be，Mg，Ca，Sr，Ba或Ra，X为任意基团）和通式[I]表示的化合物组成的催化剂。 [式中，R 7，R 8，R 9，R 10分别表示取代的环状基团或未取代的环状基团。
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