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1.发明授权
公开(公告)号：US5200161A
公开(公告)日：1993-04-06
申请号：US878916
申请日：1992-05-06
申请人： Joachim Fischer , Hubert Wolf , Manfred Diehl
发明人： Joachim Fischer , Hubert Wolf , Manfred Diehl
CPC分类号： B01D53/54 , B01D53/30 , B01D53/346
摘要： A process is disclosed for the separation of hydrogen cyanide from gases and waste gases by a throughflow or circulation scrubbing, in which formaldehyde is added at a controlled rate to the aqueous scrubbing liquid to form glycol nitrile. This addition is controlled by measuring the HCN tension in a measuring stream which has been branched off and which is first treated with hydrogen peroxide so that free H.sub.2 O.sub.2 is still detectable after 1 to 100 seconds and the pH is adjusted to a constant value before measurement of the HCN tension is carried out. The process prevents overdosing with formaldehyde which could not always be prevented in previously known processes in which the addition of formaldehyde was regulated by measuring the cyanide specific redox potential.
摘要翻译： 公开了一种通过通流或循环洗涤从气体和废气中分离氰化氢的方法，其中将甲醛以受控的速率加入到水洗涤液中以形成二醇腈。 该添加通过测量已经分支并且首先用过氧化氢处理的测量流中的HCN张力来控制，使得在1至100秒之后仍然可以检测到游离H 2 O 2，并且在测量之前将pH调节至恒定值 HCN张力进行。 该方法防止了甲醛过量，这在以前已知的通过测量氰化物特定的氧化还原电位来调节甲醛的方法中是不可避免的。
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2.发明授权Aqueous stable suspensions of water insoluble silicates capable of binding calcium ions and their use for the production of washing and cleaning agents 失效能够结合钙离子的水不溶性硅酸盐的水性稳定悬浮液及其用于生产洗涤剂和清洁剂的用途
公开(公告)号：US4671887A
公开(公告)日：1987-06-09
申请号：US804140
申请日：1985-12-03
CPC分类号： C11D3/1286
摘要： There is prepared an aqueous stable suspension of a water insoluble silicate capable of binding calcium ions and it is used for the production of washing and cleaning agents. The suspension contains in addition to water components A and B wherein component A is a silicate capable of binding calcium and having the formula(Cat.sub.2/n O).sub.x -Me.sub.2 O.sub.3 .multidot.(SiO.sub.2).sub.y Iand component B is a dispersing agent comprising a mixture of at least two fatty alcohols polyglycol ether based on isotridecyl alcohol or another aliphatic C.sub.13 alcohol and ethylene oxide having the following properties:(a) Fatty alcohol polyglycol ether having 4.5 to 5.5 EO units______________________________________Turbidity point DIN 53917 56 to 60.degree. C.Solidification point +4 to -25.degree. C.Viscosity at 50.degree. C. 13 to 28 m PasDensity at 50.degree. C. 0.94 to 0.96 g/ml______________________________________(b) Fatty alcohol polyglycol ether having 6 to 8 EO units______________________________________Turbidity point DIN 53917 66 to 74.degree. C.Solidification point +12 to -16.degree. C.Viscosity at 50.degree. C. 18 to 28 m PasDensity at 50.degree. C. 0.96 to 0.98 g/ml______________________________________
摘要翻译： 制备能够结合钙离子的水不溶性硅酸盐的水性稳定悬浮液，并且用于生产洗涤剂和清洁剂。 除了水组分A和B之外，悬浮液还含有其中组分A是能够结合钙并具有式（Cat2 / nO）x-Me2O3x（SiO2）y1的硅酸盐，组分B是包含以下物质的混合物的分散剂： 至少两种基于异十三醇或脂肪族C 13醇和环氧乙烷的脂肪醇聚乙二醇醚具有以下性质：（a）具有4.5至5.5个EO单元的脂肪醇聚乙二醇醚 - 浊度点DIN 53917 56至60℃。固结点 +4至-25℃ - 50℃下的粘度13〜28mPa·50℃下的密度0.94〜0.96g / ml - （b）具有6〜8个EO单元的脂肪醇聚乙二醇醚 - 浊度点 DIN 53917 66〜74℃ - 固结点+12〜-16℃ - 50℃下的粘度18〜28mPa·50℃下的密度0.96〜0.98g / ml〜
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公开(公告)号：US4668420A
公开(公告)日：1987-05-26
申请号：US820353
申请日：1986-01-21
申请人： Manfred Diehl , Roland Bergmann
发明人： Manfred Diehl , Roland Bergmann
摘要： A granulated detergent builder is disclosed comprising:65 to 85 weight percent of a water insoluble silicate capable of binding calcium, in the form of a finely dispersed, bound-water-containing, synthetically produced, water insoluble crystalline compound having the general formula:(Cat.sub.2/n O).sub.x.Me.sub.2 O.sub.3.(SiO.sub.2).sub.y (I), in which Cat is a cation exchangeable with calcium with the valency n, x is a number from 0.7 to 1.5, Me is boron or aluminum, and y a number from 0.8 to 6,4 to 10 weight percent sodium nitrilotriacetate1.5 to 3 weight percent nonionic surfactant0 to 1 weight percent alkali0.5 to 1.5 weight percent carboxymethyl cellulose and/or methylcelluloseand the balance is water.The product can be produced by spray drying an aqueous suspension in which all ingredients are dispersed or dissolved.
摘要翻译： 公开了一种颗粒状洗涤剂助洗剂，其包括：65至85重量％的能够结合钙的水不溶性硅酸盐，其为具有以下通式的微细分散的含结合水的合成产生的水不溶性结晶化合物：（ Cat2 / nO）x.Me2O3。（SiO2）y（I），其中Cat是与钙价态n交换的阳离子，x为0.7至1.5的数，Me为硼或铝，ya为0.8 至6,4至10重量％次氮基三乙酸钠1.5至3重量％非离子表面活性剂0至1重量％的碱0.5至1.5重量％的羧甲基纤维素和/或甲基纤维素，余量为水。 该产品可以通过喷雾干燥其中所有成分分散或溶解的水性悬浮液来制备。
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4.发明授权
公开(公告)号：US5204008A
公开(公告)日：1993-04-20
申请号：US858001
申请日：1992-03-26
申请人： Manfred Diehl , Joachim Fischer , Hubert Wolf
发明人： Manfred Diehl , Joachim Fischer , Hubert Wolf
CPC分类号： C02F1/722 , Y10S210/904
摘要： A process is disclosed for the detoxication of aqueous solutions which contain cyanohydrins, in particular glycol nitrile, and/or nitriles and in addition contain decomposition catalyst for peroxide compounds, in particular manganese compounds, by perhydrolysis of the cyano compounds at temperatures of from 5.degree. to 80.degree. C. and pH values of from 8 to 12 by means of one or more peroxide compounds which are alkali metal percarbonates and perborates of alkali metals and alkaline earth metals and alkaline earth metal peroxides. The peroxide compounds are added as such to the solution to be detoxified or formed in situ in the solution to be detoxified. Sodium percarbonate is preferably used.
摘要翻译： 公开了一种用于对含有氰醇，特别是二醇腈和/或腈的水溶液的解毒的方法，此外还含有过氧化物化合物，特别是锰化合物的分解催化剂，其通过氰化物在5℃的温度下的过水解 通过一种或多种碱金属过碳酸盐和碱金属和碱土金属和碱土金属过氧化物的过硼酸盐的过氧化物化合物，至80℃，pH值为8至12。 将过氧化物化合物原样加入要解毒的溶液中或在待溶解的溶液中原位形成。 优选使用过碳酸钠。
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5.发明授权Aqueous stable suspension of water insoluble silicate capable of binding calcium ions and its use for the production of washing and cleansing agents 失效能够结合钙离子的水不溶性硅酸盐的水性稳定悬浮液及其用于生产洗涤和清洁剂的用途
公开(公告)号：US4486331A
公开(公告)日：1984-12-04
申请号：US475394
申请日：1983-03-15
CPC分类号： C11D3/1286
摘要： There are provided aqueous pumpable stable suspensions of a water insoluble silicate capable of binding calcium ions which contain based on the total weight of the aqueous suspension(A) as the silicate capable of binding calcium 0.5 to 80 weight percent of a finely divided, bound water containing, synthetically produced, water insoluble compound of the general formula(Cat.sub.2/n O).sub.x.Me.sub.2 O.sub.3.(SiO.sub.2).sub.y (I),in which Cat is a cation exchangeable with calcium and which has the valence n, x is a number from 0.7 to 1.5, Me is boron or aluminum and y is a number between 0.8 and 6 and(B) as a dispersingly active component 0.5 to 6 weight percent of a mixture of at least two different alkylphenolethoxylates of the formula ##STR1## where R is an alkyl group of 1 to 15 carbon atoms. The component A especially can be a zeolite A while component B can consist of two alkylphenolethoxylates of formula (II) in which m is 2 to 7 and m is 8 to 15. The suspension can be employed for the production of powdery washing agents and detergents.
摘要翻译： 提供了能够结合钙离子的水不溶性硅酸盐的水性可泵送稳定的悬浮液，其含有基于水性悬浮液（A）的总重量，其为能够结合钙0.5至80重量％的细碎结合水的硅酸盐 含有合成产生的水不溶性的通式（Cat2 / nO）x.Me2O3。（SiO2）y（Ⅰ）的化合物，其中Cat是可与钙交换的阳离子，其中n为正数，x为数 0.7至1.5，Me是硼或铝，y是0.8和6之间的数，和（B）作为分散活性组分0.5至6重量％的至少两种不同的式（II）的烷基苯酚乙氧基化物的混合物， 其中R是1至15个碳原子的烷基。 组分A特别可以是沸石A，而组分B可以由两种式（II）的烷基苯酚乙氧基化物组成，其中m为2至7，m为8至15.该悬浮液可用于生产粉状洗涤剂和洗涤剂 。
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6.发明授权Process for automatically controllable reduction of the nitrite content of nitrite-containing aqueous solutions to values below 1 mg/1 失效将亚硝酸盐水溶液的亚硝酸盐含量自动控制降低至低于1 mg / l的方法
公开(公告)号：US5306431A
公开(公告)日：1994-04-26
申请号：US925749
申请日：1992-08-07
摘要： Reduction of the nitrite content of aqueous solutions by treatment with hydrogen peroxide in the acidic pH range can be controlled by measurement of the redox potential. Contrary to the teaching of the prior art, addition of the hydrogen peroxide in the process according to the invention is terminated not at the highest redox potential, but only after lowering of the potential to a value of 650.+-.10 mV. In this way, nitrite contents below 1 mg/l can be obtained even when the solutions additionally contain fluctuating amounts of various compounds oxidizable by H.sub.2 O.sub.2.
摘要翻译： 通过在酸性pH范围内用过氧化氢处理来降低水溶液的亚硝酸盐含量可以通过测量氧化还原电位来控制。 与现有技术的教导相反，根据本发明的方法中的过氧化氢的添加终止于没有达到最高的氧化还原电位，但是仅在将电位降低到650±10mV的值之后。 这样就可以获得低于1mg / l的亚硝酸盐含量，即使这些溶液另外含有波动量的可被H 2 O 2氧化的各种化合物。
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公开(公告)号：US5207925A
公开(公告)日：1993-05-04
申请号：US857414
申请日：1992-03-26
申请人： Norbert Steiner , Stephen Gos , Frank Ladwig , Manfred Diehl
发明人： Norbert Steiner , Stephen Gos , Frank Ladwig , Manfred Diehl
CPC分类号： C02F1/722 , C02F2101/18 , Y10S210/904
摘要： A process is disclosed for the detoxification of aqueous solutions containing cyanides and/or cyano complexes in the presence of heavy metals which are Mn, Co, Ni, Cu, Cd and Zn, more particularly Cu, by oxidative treatment of the solutions with peroxide compounds at pH values of 8 to 12. Peroxide compounds from the group consisting of alkali metal percarbonates and alkaline earth metal peroxides are used. The peroxide compounds are added to the solutions to be detoxified per se or are formed in situ therein from hydrogen peroxide and other components. Sodium perborate, sodium percarbonate and calcium peroxide are preferred.
摘要翻译： 公开了一种在Mn，Co，Ni，Cu，Cd和Zn，更特别是Cu的重金属存在下，含有氰化物和/或氰基络合物的水溶液的解毒方法，通过用过氧化物化合物氧化处理溶液 在pH值为8至12的情况下使用过氧化物，由碱金属过碳酸盐和碱土金属过氧化物组成。 将过氧化物化合物加入到本身解毒的溶液中或者由过氧化氢和其它组分原位形成。 过硼酸钠，过碳酸钠和过氧化钙是优选的。
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公开(公告)号：US5076957A
公开(公告)日：1991-12-31
申请号：US474658
申请日：1990-02-06
CPC分类号： C11D3/128 , C11D3/3761
摘要： The detergent builder consists of a water-insoluble silicate capable of binding calcium ions as well as of a mixture of two acrylic acid polymerizates which exhibit different viscosity numbers.
摘要翻译： 洗涤剂助洗剂由能够结合钙离子的水不溶性硅酸盐以及显示不同粘度数的两种丙烯酸聚合物的混合物组成。
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公开(公告)号：US4883607A
公开(公告)日：1989-11-28
申请号：US147943
申请日：1988-01-25
申请人： Manfred Diehl
发明人： Manfred Diehl
摘要： Granulated detergent builders, are disclosed consisting essentially of:70 to 80 weight percent of water-insoluble silicate, capable of binding calcium, in the form of a finely divided, bound-water-containing, synthetically produced, water-insoluble, crystalline compound of the general formula(Kat).sub.2/n O).sub.x.Me.sub.2 O.sub.3.(SiO.sub.2).sub.y (I),in which Kat represents an n-valent cation which is exchangeable with calcium, x a number from 0.7 to 1.5, Me boron or aluminum and y a number from 0.8 to 6,2 to 3 weight percent of nonionic surfactant,0 to 1 weight percent of alkali,2.4 to 5 weight percent of carboxymethylcellulose and/or methylcellulose,and the balance water.
摘要翻译： 公开的颗粒状洗涤剂助洗剂基本上由以下组成：70至80重量％的能够结合钙的水不溶性硅酸盐，其为细分的含结合水的合成产生的水不溶性结晶化合物 通式（Kat）2 / nO）x.Me 2 O 3（SiO 2）y（I），其中Kat表示可与钙交换的n价阳离子，xa为0.7至1.5，Me硼或铝和ya 数量为0.8至6,2至3重量％的非离子表面活性剂，0至1重量％的碱，2.4至5重量％的羧甲基纤维素和/或甲基纤维素，以及余量的水。
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公开(公告)号：US4589989A
公开(公告)日：1986-05-20
申请号：US672164
申请日：1984-11-16
申请人： Karl-Hans Muller , Manfred Diehl
发明人： Karl-Hans Muller , Manfred Diehl
IPC分类号： D06M11/00 , C11D1/62 , C11D3/00 , C11D3/12 , D06M11/79 , D06M13/02 , D06M13/322 , D06M13/463 , D06M13/473 , C11D7/02
摘要： A laundry softener concentrate comprises one or more laundry softeners, synthetic silicon dioxide, and optionally one or more solubilizers. The laundry softener concentrate is in the form of a flowable powder.
摘要翻译： 衣物软化剂浓缩物包含一种或多种衣物软化剂，合成二氧化硅和任选的一种或多种增溶剂。 衣物柔软剂浓缩物是可流动粉末的形式。
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