公开(公告)号：US06989469B2

公开(公告)日：2006-01-24

申请号：US10648072

申请日：2003-08-26

申请人： David Cleve Eubanks ,  Raymond Lawrence June ,  Timothy Michael Nisbet ,  Joseph Broun Powell ,  Marinus Van Zwienen

发明人： David Cleve Eubanks ,  Raymond Lawrence June ,  Timothy Michael Nisbet ,  Joseph Broun Powell ,  Marinus Van Zwienen

IPC分类号： C07C1/00

CPC分类号： C07C1/24 ,  C07C15/46

摘要： The invention pertains to a method of preparing styrene or substituted styrene involving (1) converting a mixture containing alkylbenzene hydroperoxide or substituted alkylbenzene hydroperoxide to a mixture containing phenyl alkanol or substituted phenyl alkanol and (2) dehydrating the phenyl alkanol or substituted phenyl alkanol, characterized by oxidizing an alkene to an alkylene oxide in step (1) in the presence of a heterogenous catalyst and dehydrating the phenyl alkanol or substituted phenyl alkanol in step (2) in the presence of a homogenous dehydration catalyst to obtain styrene or substituted styrene.

摘要翻译： 本发明涉及制备苯乙烯或取代苯乙烯的方法，其涉及（1）将含有烷基苯氢过氧化物或取代的烷基苯氢过氧化物的混合物转化为含有苯基链烷醇或取代的苯基链烷醇的混合物和（2）使苯基链烷醇或取代的苯基链烷醇脱水， 在异种催化剂的存在下，在步骤（1）中将烯烃氧化成烯化氧，并且在步骤（2）中使苯基链烷醇或取代的苯基链烷醇在均相脱水催化剂存在下脱水得到苯乙烯或取代的苯乙烯。

公开(公告)号：US06500310B1

公开(公告)日：2002-12-31

申请号：US09719624

申请日：2000-12-14

申请人： Robert Frank Dee ,  Marinus Van Zwienen

发明人： Robert Frank Dee ,  Marinus Van Zwienen

IPC分类号： B01D314

CPC分类号： C02F1/048 ,  B01D3/146

摘要： A process for treating waste water streams containing at least hydrocarbons and salts to yield a clean water product, a concentrated brine product and a hydrocarbon-rich product, which process includes the steps of: (a) feeding the waste water feed into a first distillation column at a stage in the range of from 0.05 to 0.15 from the top, wherein n represents the total number of theoretical stages of the first distillation column and has a value in the range of from 20 to 40; (b) drawing off a vapor stream at a stage in the range of from 0.55 to 0.75 from the top and feeding this vapor stream into the bottom of a second distillation column having m theoretical stages, with m having a value in the range of from 3 to 10; (c) drawing off the clean water product as the top fraction from the second distillation column and drawing off a bottom stream from the second distillation column, which is fed back into the first distillation column below the draw off of the vapor stream in step (b) at a stage in the range of from 0.60 to 0.85 from the top; (d) drawing off the concentrated brine product as the bottom fraction of the first distillation column; and (e) drawing off the hydrocarbon stream as the top fraction of the first distillation column.

摘要翻译： 一种用于处理含有至少烃和盐的废水流以产生清洁水产品，浓缩的盐水产物和富含烃的产品的方法，该方法包括以下步骤：（a）将废水进料送入第一蒸馏 塔的顶部从0.05至0.15的范围内，其中n表示第一蒸馏塔的理论级总数，其值在20至40的范围内; （b）从顶部抽出0.55至0.75范围内的蒸气流，并将该蒸汽流送入具有理论级的第二蒸馏塔的底部，其中m的值范围为 3至10; （c）从第二蒸馏塔抽出清洁水产品作为顶级馏分，并从第二蒸馏塔中抽出底部物流，该第二蒸馏塔在第一蒸馏塔中被反馈到低于蒸气流的蒸馏流的步骤 b）在从顶部的0.60至0.85范围内的阶段; （d）抽出浓缩的盐水产物作为第一蒸馏塔的塔底部分; 和（e）除去作为第一蒸馏塔顶馏分的烃流。

公开(公告)号：US06939996B2

公开(公告)日：2005-09-06

申请号：US10808858

申请日：2004-03-25

申请人： Timothy Michael Nisbet ,  Marinus Van Zwienen

发明人： Timothy Michael Nisbet ,  Marinus Van Zwienen

IPC分类号： B01J23/70 ,  B01J23/72 ,  B01J23/78 ,  C07C29/145 ,  C07C27/00

CPC分类号： B01J23/78 ,  B01J23/72 ,  C07C29/145 ,  C07C33/22

摘要： The present invention pertains to a process for the hydrogenation of alkylaryl ketones, which process involves contacting a feed containing the alkylaryl ketones and from 0.5% to 30% by weight of phenolic compounds with hydrogen in the presence of a heterogeneous hydrogenation catalyst. The invention further relates to a process for preparing a hydrogenation catalyst with improved activity.

摘要翻译： 本发明涉及一种氢化烷基芳基酮的方法，该方法包括在非均相氢化催化剂存在下使含有烷基芳基酮的进料和0.5％至30％重量的酚类化合物与氢气接触。 本发明还涉及一种制备具有改进活性的氢化催化剂的方法。

公开(公告)号：US06712882B1

公开(公告)日：2004-03-30

申请号：US10111643

申请日：2002-04-26

申请人： Johan Hendrik De Bie ,  Robert Frank Dee ,  Raymond Lawrence June ,  Marinus Van Zwienen

发明人： Johan Hendrik De Bie ,  Robert Frank Dee ,  Raymond Lawrence June ,  Marinus Van Zwienen

IPC分类号： B01D1900

CPC分类号： C02F1/048 ,  B01D5/009

摘要： A process for treating waste water from an industrial process for producing propylene oxide, which process involves the steps of: (a) subjecting the waste water to a multi-effect evaporation treatment resulting in a vaporous top fraction and a liquid bottom fraction containing the non-volatile contaminants; and (b) condensing at least part of the vaporous top fraction into a liquid stream which is subject to a stripping treatment resulting in an overhead stream containing volatile waste organic material and purified water as the liquid bottom stream.

摘要翻译： 一种用于处理来自工业生产环氧丙烷的工艺的废水的方法，该方法包括以下步骤：（a）使废水经受多效蒸发处理，导致蒸气顶部馏分和含有非水溶液的液体底部馏分 挥发性污染物 和（b）将至少部分蒸汽顶部馏分冷凝成液体料流，所述液体料流经过汽提处理，导致含有挥发性有机废物的塔顶馏出物和作为液体底部物流的纯化水。

公开(公告)号：US06437207B1

公开(公告)日：2002-08-20

申请号：US09700302

申请日：2000-11-09

申请人： Hendrik Dirkzwager ,  Marinus Van Zwienen

发明人： Hendrik Dirkzwager ,  Marinus Van Zwienen

IPC分类号： C07C1207

CPC分类号： C07C1/24 ,  B01J21/04 ,  B01J35/0026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/108 ,  C07C2521/04 ,  C07C15/46

摘要： Process for the preparation of styrene comprising the gas phase dehydration of 1-phenyl-ethanol at elevated temperature in the presence of a dehydration catalyst, wherein the dehydration catalyst consists of shaped alumina catalyst particles having a surface area (BET) in the range of from 80 to 140 m2/g and a pore volume (Hg) in the range of from 0.35 to 0.65 ml/g, of which 0.03 to 0.15 ml/g is in pores having a diameter of at least 1000 nm.

摘要翻译： 在脱水催化剂存在下，在高温下，将1-苯基 - 乙醇气相脱水制备苯乙烯的方法，其中脱水催化剂由成形的氧化铝催化剂颗粒组成，其中表面积（BET）为 80至140m 2 / g，孔体积（Hg）在0.35至0.65ml / g的范围内，其中0.03至0.15ml / g在直径至少为1000nm的孔中。

公开(公告)号：US06420620B1

公开(公告)日：2002-07-16

申请号：US09622276

申请日：2000-08-14

申请人： Johan Hendrik De Bie ,  Hendrik Dirkzwager ,  Robertus Raymundus Maria Overtoom ,  Marinus Van Zwienen

发明人： Johan Hendrik De Bie ,  Hendrik Dirkzwager ,  Robertus Raymundus Maria Overtoom ,  Marinus Van Zwienen

IPC分类号： C07C120

CPC分类号： C07C15/44 ,  C07C1/20 ,  C07C1/24 ,  C07C2521/12 ,  C07C2531/025

摘要： A process for the preparation of styrene or substituted styrenes that includes the steps of: subjecting a feed containing 1-phenyl ethanol or substituted 1-phenyl ethanol to a dehydration treatment in the presence of a dehydration catalyst; subjecting the resulting product stream to a separation treatment, thus obtaining a stream containing styrene or substituted styrene and a residual fraction containing heavy ends; and converting at least part of these heavy ends to styrene or substituted styrenes by subjecting a stream containing these heavy ends to a cracking treatment in the presence of an acidic cracking catalyst.

摘要翻译： 一种制备苯乙烯或取代苯乙烯的方法，包括以下步骤：在脱水催化剂存在下，使含有1-苯基乙醇或取代的1-苯基乙醇的进料进行脱水处理; 对所得产物流进行分离处理，从而获得含有苯乙烯或取代苯乙烯的流和含有重馏分的残余馏分; 并通过在酸性裂化催化剂的存在下使含有这些重馏分的物流进行裂化处理，将这些重馏分的至少一部分转化成苯乙烯或取代的苯乙烯。