公开(公告)号：US5432286A

公开(公告)日：1995-07-11

申请号：US133502

申请日：1993-10-07

Applicant: Ivan Cabrera ,  Uwe Falk ,  Werner Hickel ,  Donald Lupo ,  Ude Scheunemann ,  Peter Boldt ,  Martin Blenkle

Inventor： Ivan Cabrera ,  Uwe Falk ,  Werner Hickel ,  Donald Lupo ,  Ude Scheunemann ,  Peter Boldt ,  Martin Blenkle

IPC: B05D1/20 ,  C07D495/04 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  G02F1/365 ,  G02F1/37 ,  C07D493/04

CPC classification number: C07D495/04 ,  B05D1/202 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  G02F1/3614 ,  G02F1/3618

Abstract: Substituted thieno[3,2-b]thiophenes, processes for their preparation and their useCompounds of the formula I ##STR1## in which R is a C.sub.1 - to C.sub.22 -alkyl radical,A.sup.1 and A.sup.2 are hydrogen or methyl orA.sup.1 is hydrogen and A.sup.2 is the nitro group, andB is the cyano group, the nitro group or an electron-attracting organic group having a double bond which is in conjugation with the thieno[3,2-b]thiophene ring system,have a high dipole moment and a high polarizability and are suitable for purposes of nonlinear optics. If R in the formula I is a C.sub.12 - to C.sub.22 -alkyl radical, monomolecular layers can be applied to a substrate by the Langmuir-Blodgett method. The resulting layer elements are suitable, inter alia, as waveguides.

Abstract translation: 取代的噻吩并[3,2-b]噻吩，其制备方法及用途其中R为C 1至C 22 - 烷基的式I的化合物，A 1和A 2为氢或甲基或A 1为 氢和A2是硝基，B是氰基，硝基或具有与噻吩并[3,2-b]噻吩环体系共轭的双键的吸电子有机基团具有高的 偶极矩和高极化性，适用于非线性光学。 如果式I中的R是C 12 -C 22烷基，则可以通过Langmuir-Blodgett法将单分子层施加到基底上。 所得到的层元件尤其适用于波导。

公开(公告)号：US5684165A

公开(公告)日：1997-11-04

申请号：US423006

申请日：1995-04-14

Applicant: Ivan Cabrera ,  Uwe Falk ,  Werner Hickel ,  Donald Lupo ,  Ude Scheunemann ,  Peter Boldt ,  Martin Blenkle

Inventor： Ivan Cabrera ,  Uwe Falk ,  Werner Hickel ,  Donald Lupo ,  Ude Scheunemann ,  Peter Boldt ,  Martin Blenkle

IPC: B05D1/20 ,  C07D495/04 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  G02F1/365 ,  G02F1/37 ,  G02B6/02

CPC classification number: C07D495/04 ,  B05D1/202 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  G02F1/3614 ,  G02F1/3618

Abstract: Compounds of the formula I ##STR1## in which R is a C.sub.1 - to C.sub.22 -alkyl radical, A.sup.1 and A.sup.2 are hydrogen or methyl or, A.sup.1 is hydrogen and A.sup.2 is the nitro group, and B is the cyano group, the nitro group or an electron-attracting organic group having a double bond which is in conjugation with the thieno�3,2-b!thiophene ring system, have a high dipole moment and a high polarizability and are suitable for purposes of nonlinear optics. If R in the formula I is a C.sub.12 - to C.sub.22 -alkyl radical, monomolecular layers can be applied to a substrate by the Langmuir-Blodgett method. The resulting layer elements are suitable, inter alia, as waveguides.

Abstract translation: 其中R是C 1〜C 22 - 烷基的式I的化合物，A 1和A 2为氢或甲基，或者A 1为氢，A 2为硝基，B为氰基，硝基 基团或具有与噻吩并[3,2-b]噻吩环体系共轭的双键的吸电子有机基团具有高偶极矩和高极化性，并且适用于非线性光学的目的。 如果式I中的R是C 12 -C 22烷基，则可以通过Langmuir-Blodgett法将单分子层施加到基底上。 所得到的层元件尤其适用于波导。