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51 条记录 (耗时 0.02 秒)

    Polarized films from pairwise-deposited semi-ionomeric syndioregic polymers
    1.
    发明授权
    Polarized films from pairwise-deposited semi-ionomeric syndioregic polymers 失效
    成对沉积的半离聚物共聚聚合物的极化膜

    公开(公告)号：US6114031A

    公开(公告)日：2000-09-05

    申请号：US246197

    申请日：1999-01-11

    申请人： Marion J. Roberts ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Peter Zarras ,  Andrew P. Chafin ,  Richard A. Hollins ,  Geoffrey A. Lindsay

    发明人： Marion J. Roberts ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Peter Zarras ,  Andrew P. Chafin ,  Richard A. Hollins ,  Geoffrey A. Lindsay

    IPC分类号： B05D1/20 ,  G02F1/361

    CPC分类号： B82Y30/00 ,  B05D1/202 ,  B82Y20/00 ,  B82Y40/00 ,  G02F1/3616 ,  G02F1/3618 ,  Y10T428/261

    摘要： This invention is comprised of new nonlinear optic polymers and a new Lanir-Blodgett (LB) film deposition scheme for which these polymers were designed. The invention is unique because it produces an electro-optic film which has never undergone electric-field poling nor high temperature treatment. It eliminates the dilution effect of the long hydrophobic alkyl groups, and creates stronger ionic bonds between the polymer chains. Finally, the invention reduces the time to make a film of a given thickness by at least half by virtue of depositing two polymer layers per stroke. The new polymers are comprised of asymmetric chromophores linked head-to-head by alternating two different kinds of bridging groups. One of the bridging groups contains one or more ionic groups, and the other bridging group contains one or more non-ionic, hydrophilic groups.

    摘要翻译： 本发明由新型非线性光学聚合物和这些聚合物设计的新型Langmuir-Blodgett（LB）薄膜沉积方案组成。 本发明是独特的，因为它产生从未经过电场极化或高温处理的电光膜。 它消除了长疏水烷基的稀释效应，并在聚合物链之间产生更强的离子键。 最后，本发明通过每冲程沉积两个聚合物层，减少了将给定厚度的膜制成至少一半的时间。 新的聚合物由不对称的发色团组成，通过交替两种不同种类的桥连基团与头对头连接。 桥连基团之一含有一个或多个离子基团，另一个桥连基团含有一个或多个非离子的亲水基团。

    Films for non-linear optics
    3.
    发明授权
    Films for non-linear optics 失效
    非线性光学膜

    公开(公告)号：US5510200A

    公开(公告)日：1996-04-23

    申请号：US70341

    申请日：1993-08-30

    申请人： Geoffrey J. Ashwell

    发明人： Geoffrey J. Ashwell

    IPC分类号： B05D1/20 ,  C09K9/02 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  B32B9/04

    CPC分类号： B82Y20/00 ,  B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  G02F1/3618 ,  Y10S428/91 ,  Y10S428/913 ,  Y10T428/31504 ,  Y10T428/31529

    摘要： Multi-layer Langmuir-Blodgett films comprising alternate layers of an optically non-linear amphiphilic compound and a spacer compound wherein the spacer comprises at least two hydrophobic substituents, have high second order non-linear optical coefficients, are stable over a prolonged period and quadratic SHG enhancement based on the number of layers. They are useful in a variety of opto-electronic devices.

    摘要翻译： PCT No.PCT / GB91 / 02096 Sec。 371日期：1993年8月30日 102（e）日期1993年8月30日PCT 1991年11月27日PCT PCT。 出版物WO92 / 09374 日期：1992年6月11日。多层Langmuir-Blodgett膜包含光学非线性两亲性化合物和间隔化合物的交替层，其中间隔物包含至少两个疏水性取代基，具有高二阶非线性光学系数 基于层数稳定长期稳定和二次SHG增强。 它们在各种光电器件中非常有用。

    Process for producing polyacetylene
    5.
    发明授权
    Process for producing polyacetylene 失效
    生产聚乙炔的方法

    公开(公告)号：US5019303A

    公开(公告)日：1991-05-28

    申请号：US347213

    申请日：1989-05-04

    申请人： Norihisa Mino

    发明人： Norihisa Mino

    IPC分类号： B05D1/18 ,  B05D1/20 ,  C08F38/02 ,  G02F1/361 ,  H01B1/12

    CPC分类号： B82Y30/00 ,  B05D1/185 ,  B05D1/202 ,  B82Y20/00 ,  B82Y40/00 ,  C08F38/02 ,  G02F1/3618 ,  H01B1/125

    摘要： The present invention concerns the fields of processes for producing an organic ultrathin film having polyacetylene linkages and the resultant films. In one embodiment the process for producing the film consists of the steps forming an acetylene monomolecular film on a water surface, applying magnetic or electric field to enhance orientation, irradiating the acetylene film with an energy beam to polymerize the acetylene film into a polyacetylene film. Other embodiments for producing the film consists of the steps of forming an acetylene film by chemical absorption, applying magnetic or electric field, and irradiating the film with an energy beam. The polymerized film is useful as an electrical material having high conductivity and as an optical material having non-linear effect.

    Novel nonlinear optical materials and processes employing diacetylenes
    9.
    发明授权
    Novel nonlinear optical materials and processes employing diacetylenes 失效
    新型非线性光学材料和采用二乙炔的方法

    公开(公告)号：US4431263A

    公开(公告)日：1984-02-14

    申请号：US129560

    申请日：1980-03-12

    申请人： Anthony F. Garito

    发明人： Anthony F. Garito

    IPC分类号： B05D1/20 ,  C07C57/18 ,  C07C57/52 ,  C07C205/37 ,  C08F138/00 ,  G02B6/138 ,  G02F1/00 ,  G02F1/35 ,  G02F1/361 ,  G02F1/377 ,  G02F3/00 ,  G03F7/025 ,  G02B5/172

    CPC分类号： B82Y20/00 ,  B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C07C205/37 ,  C07C57/18 ,  C07C57/52 ,  C08F138/00 ,  G02B6/138 ,  G02F1/0018 ,  G02F1/3615 ,  G02F1/3618 ,  G03F7/025 ,  G02F1/3515 ,  G02F1/377 ,  G02F3/00

    摘要： Novel nonlinear optical, piezoelectric, pyroelectric, waveguide, and other materials are presented together with processes for their employment and articles formed thereby. Such materials, processes and articles comprise diacetylenes and polymers formed from diacetylenic species, which polymers are amenable to close geometric, steric, structural, and electronic control. Accordingly, it is now possible to design, formulate and employ new diacetylenic species and polymers formed therefrom to provide nonlinear optic, waveguide, piezoelectric, and pyroelectric materials and devices having surprising efficiencies and degrees of effect. According to a preferred embodiment of the invention, diacetylenes which are crystallizable into crystals having a noncentrosymmetric unit cell may form single crystals or may be elaborated into a thin film upon a substrate by the Langmuir-Blodgett technique. Such films may, optionally, be polymerized either thermally or by irradiation for use in nonlinear optical and other systems. According to other preferred embodiments, diacetylenes are covalently bonded to substrates through the employment of silane species and subsequently polymerized to yield nonlinear optic and other devices having high structural integrity in addition to high efficiencies and effects.

    摘要翻译： 新型非线性光学，压电，热电，波导和其他材料与其使用的工艺和由此形成的制品一起呈现。 这些材料，方法和制品包括二乙炔和由二炔类物质形成的聚合物，该聚合物适于闭合几何，立体，结构和电子控制。 因此，现在可以设计，配制和使用由其形成的新的二炔类物质和聚合物，以提供令人惊奇的效率和效果的非线性光学，波导，压电和热电材料和装置。 根据本发明的优选实施方案，可结晶成具有非中心对称单元电池的晶体的二乙炔可以形成单晶，或者可以通过Langmuir-Blodgett技术在基底上被精制成薄膜。 任选地，这样的膜可以热或通过照射聚合用于非线性光学和其它系统中。 根据其它优选的实施方案，二乙炔通过使用硅烷物质共价键合到基底上，随后聚合以产生除了高效率和效果之外具有高结构完整性的非线性光学元件和其它器件。

    Supramolecular opto-electronic architecture of tautomeric compositions
    10.
    发明授权
    Supramolecular opto-electronic architecture of tautomeric compositions 失效
    互变异构体的超分子光电结构

    公开(公告)号：US6124963A

    公开(公告)日：2000-09-26

    申请号：US274754

    申请日：1999-03-23

    申请人： Robert R. Schumaker

    发明人： Robert R. Schumaker

    IPC分类号： G02B6/12 ,  G02B6/132 ,  G02F1/361 ,  G02B26/08 ,  G02F1/35

    CPC分类号： B82Y20/00 ,  G02B6/12002 ,  G02B6/132 ,  G02F1/3614 ,  G02F1/3618

    摘要： A procedure is disclosed for assembly of novel two-sided monolayer or multilayer device architectures out of self-assembly or self-organizing amphiphilic compounds derived from molecules that undergo a type of valence tautomerization known as asymmetric narcissistic reactions. The two-sided monolayer architectures are constructed by Langmuir-Blodgett (LB) transfer or self-assembly (SA) techniques while the multilayer architectures are formed by Y-type LB depositions, where the two layers or bilayers of the assemblies are alternate depositions of mirror-image forms of the amphiphiles. The resulting three-dimensional supramolecular assemblies described herein are uniquely capable of commutation between two non-centrosymmetric states which have, on a macroscopic scale, an optically antipodal relationship and a third central symmetric state which is, accordingly, optically racemic. The inventive architectures are expected to be useful for constructing a variety of opto-electronic devices for application as chemical sensors or for the transmission, modulation, storage, or processing of information.

    摘要翻译： 公开了用于从衍生自经历称为不对称自恋反应的价态互变异构的分子的自组装或自组织两亲化合物组装新型双面单层或多层器件结构的方法。 双面单层结构由Langmuir-Blodgett（LB）转移或自组装（SA）技术构建，而多层结构由Y型LB沉积形成，其中组件的两层或双层交替沉积 两镜的镜像形式。 本文所述的所得三维超分子组件在两个非中心对称状态之间具有独特的能力，该宏观尺度具有光学对映关系和第三中心对称状态，其相应地是旋光外消旋的。 预期本发明的结构对于构建用作化学传感器或用于信息的传输，调制，存储或处理的各种光电器件是有用的。