公开(公告)号：US07001584B2

公开(公告)日：2006-02-21

申请号：US09878347

申请日：2001-06-12

申请人： Mats Nyström ,  Christina Järnvik

发明人： Mats Nyström ,  Christina Järnvik

IPC分类号： C01B15/023

CPC分类号： C01B15/023

摘要： The invention relates to a process for production of hydrogen peroxide according to the anthraquinone process including alternate hydrogenation and oxidation of one or more quinones selected from anthraquinones and/or tetrahydro anthraquinones in a working solution comprising at least one quinone solvent and at least one hydroquinone solvent, wherein said at least one quinone solvent comprises isodurene in an amount from 15 to 100 wt %. The invention also relates to a composition useful as a working solution at production of hydrogen peroxide.

公开(公告)号：US06524547B1

公开(公告)日：2003-02-25

申请号：US09715103

申请日：2000-11-20

申请人： Mats Nyström ,  Christina Järnvik ,  Hans Thor ,  Seppo Saari

发明人： Mats Nyström ,  Christina Järnvik ,  Hans Thor ,  Seppo Saari

IPC分类号： C01B15023

CPC分类号： C07C50/16 ,  C01B15/023

摘要： The invention concerns a process for production of hydrogen peroxide according to the anthraquinone process comprising the steps of alternate hydrogenation and oxidation of anthraquinones and tetrahydro anthraquinones in a working solution comprising a mixture of alkyl-substituted anthraquinones and alkyl-substituted tetrahydro anthraquinones dissolved in at least one organic solvent, wherein from 10 to 55 mole % of the anthraquinones and the tetrahydro anthraquinones are substituted with one amyl group, and the molar ratio of alkyl-substituted tetrahydro anthraquinones to alkyl-substituted anthraquinones is at least 1:1. The invention also concerns a composition useful as a working solution in said process.

摘要翻译： 本发明涉及一种根据蒽醌方法生产过氧化氢的方法，包括以下步骤：在工作溶液中交替氢化和氧化蒽醌和四氢蒽醌，该工作溶液包含至少溶解在烷基取代的蒽醌和烷基取代的四氢蒽醌的混合物 一种有机溶剂，其中10至55摩尔％的蒽醌和四氢蒽醌被一个戊基取代，并且烷基取代的四氢蒽醌与烷基取代的蒽醌的摩尔比为至少1:1。 本发明还涉及可用作所述方法中的工作溶液的组合物。

公开(公告)号：US06207128B1

公开(公告)日：2001-03-27

申请号：US09070017

申请日：1998-04-30

申请人： Annicka Sellin ,  Mats Nyström

发明人： Annicka Sellin ,  Mats Nyström

IPC分类号： C01B15023

CPC分类号： B01J37/035 ,  B01J23/44 ,  B01J23/626 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/031 ,  C01B15/023

摘要： The invention relates to a method of producing a catalyst comprising a porous support and a catalytically active metal deposited thereon comprising the steps of treating the porous support with a solution of a salt of the catalytically active metal and a reducing agent to achieve electroless deposition of the catalytically active metal on the support. The invention also relates to a catalyst obtainable by the method and a process of producing hydrogen peroxide.

摘要翻译： 本发明涉及一种生产催化剂的方法，其包括多孔载体和沉积在其上的催化活性金属，其包括以下步骤：用催化活性金属和还原剂的盐的溶液处理多孔载体，以实现无电沉积 载体上的催化活性金属。 本发明还涉及通过该方法获得的催化剂和产生过氧化氢的方法。

公开(公告)号：US06299852B1

公开(公告)日：2001-10-09

申请号：US09217586

申请日：1998-12-22

申请人： Mats Nyström ,  Johan Wanngård ,  Wolfgang Herrmann

发明人： Mats Nyström ,  Johan Wanngård ,  Wolfgang Herrmann

IPC分类号： C01B1501

CPC分类号： C01B15/029

摘要： The invention concerns a process of continuously producing hydrogen peroxide by direct reaction between hydrogen and oxygen in a gaseous reaction mixture in contact with a catalyst maintained in a reactor, wherein a gaseous reaction mixture containing hydrogen and oxygen is supplied to the reactor through an inlet and hydrogen peroxide enriched gas is withdrawn from the reactor through an outlet. According to the invention the temperature difference in the gaseous reaction mixture in contact with the catalyst between a position just after the inlet to the reactor and a position at the outlet of the reactor is maintained below about 40° C.

摘要翻译： 本发明涉及通过在保持在反应器中的催化剂接触的气态反应混合物中通过氢和氧之间的直接反应连续生产过氧化氢的方法，其中含有氢和氧的气态反应混合物通过入口和反应器供应到反应器， 富含过氧化氢的气体通过出口从反应器中排出。 根据本发明，在刚好在反应器入口的位置与反应器出口位置之间的与催化剂接触的气态反应混合物中的温度差保持在约40℃以下

公开(公告)号：US06210651B1

公开(公告)日：2001-04-03

申请号：US09217585

申请日：1998-12-22

申请人： Mats Nyström ,  Johan Wanngård ,  Wolfgang Herrmann

发明人： Mats Nyström ,  Johan Wanngård ,  Wolfgang Herrmann

IPC分类号： C01B1501

CPC分类号： C01B15/029

摘要： The invention relates to a process for continuously producing hydrogen peroxide comprising the steps of feeding hydrogen and oxygen containing gas to a reactor provided with a catalyst; contacting the hydrogen and oxygen gas with the catalyst and thereby forming hydrogen peroxide, and; withdrawing hydrogen peroxide containing gas from the reactor; wherein the catalyst comprises a solid catalytically active material at least partially covered with a layer of a stationary phase different from the catalytically active material.

摘要翻译： 本发明涉及一种连续生产过氧化氢的方法，包括以下步骤：向装有催化剂的反应器供给氢气和含氧气体; 使氢气和氧气与催化剂接触，从而形成过氧化氢; 从反应器中抽出含过氧化氢的气体; 其中所述催化剂包含至少部分被不同于所述催化活性材料的固定相的层覆盖的固体催化活性材料。

公开(公告)号：US06787497B2

公开(公告)日：2004-09-07

申请号：US09964358

申请日：2001-09-28

申请人： Anna-Carin Dellve ,  Bozena Tokarz ,  Mats Nyström

发明人： Anna-Carin Dellve ,  Bozena Tokarz ,  Mats Nyström

IPC分类号： B01J2116

CPC分类号： D21H17/68 ,  B01J35/06 ,  C01B15/023

摘要： The invention concerns a catalyst carrier comprising a fibre paper impregnated with a slurry comprising silica sol, micro fibres and a filler, wherein said micro fibres have an equivalent average particle size, measured with sedigraph method, from about 200 nm to about 30000 nm and said filler has an average equivalent particle size, measured with sedigraph method, from about 300 to about 10000 nm. The invention further concerns a method of its preparation, a slurry useful therefore, a catalyst comprising such a catalyst carrier and use of the catalyst.

摘要翻译： 本发明涉及一种催化剂载体，其包含浸渍有包含二氧化硅溶胶，微纤维和填料的浆料的纤维纸，其中所述微纤维具有约200nm至约30000nm的用sedigraph方法测量的当量平均粒径，并且所述 填料具有约300至约10000nm的平均等效粒度，用sedigraph方法测量。 本发明还涉及其制备方法，因此有用的浆料，包含这种催化剂载体的催化剂和催化剂的用途。