公开(公告)号：US20240326024A1

公开(公告)日：2024-10-03

申请号：US18442900

申请日：2024-02-15

Applicant: Hindustan Petroleum Corporation Limited

Inventor： Kotni SANTHOSH ,  Valavarasu Gnanasekaran ,  Ganapati V. Shanbhag ,  Rajappan Vetrivel ,  Anand B. Halgeri ,  Sujith S. ,  Chaitra N. Mallannavar ,  K. M. Rajashekhar Vaibhava

IPC: B01J23/83 ,  B01J37/00 ,  B01J37/03 ,  B01J37/06 ,  B01J37/08

CPC classification number: B01J23/83 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08

Abstract: The present disclosure relates to a catalyst for carbon dioxide hydrogenation to methanol having 80-95% w/w of a metal and their oxides; 5-20% w/w of a structural promoter; and 5-10% w/w of a binder of the total weight of the catalyst. Further, the present disclosure also relates to a method for preparation of a catalyst for carbon dioxide hydrogenation to methanol having a) co-precipitating of 80-95% w/w of a metal precursors of the total weight of the catalyst under with a 1.0-1.8M precipitating agent followed by adding 5-20% w/w of a structural promoter of the total weight of the catalyst to obtain an active metal precipitate, b) washing and drying the active metal precipitate under conditions to obtain a dried active metal precipitate followed by calcination under conditions to form a mixed metal oxide, c) adding 5-10% w/w of a binder of the total weight of the catalyst to the 90-95% w/w mixed metal oxides along with 0.5-1.5M peptizing agent, followed by drying and calcination under conditions to obtain a catalyst for CO2 hydrogenation to methanol. The present catalyst yielded higher methanol with higher selectivity.

公开(公告)号：US12060319B2

公开(公告)日：2024-08-13

申请号：US17580588

申请日：2022-01-20

Applicant: China Petroleum & Chemical Corporation ,  Dalian Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

Inventor： Kai Qiao ,  Feng Zhou ,  Jie Su ,  Huixia Ma ,  Qingtong Zhai ,  Shumei Zhang

IPC: C07C45/00 ,  B01J21/04 ,  B01J23/83 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  B01J37/34

CPC classification number: C07C45/002 ,  B01J21/04 ,  B01J23/83 ,  B01J37/0018 ,  B01J37/009 ,  B01J37/0207 ,  B01J37/031 ,  B01J37/04 ,  B01J37/082 ,  B01J37/343

Abstract: The present invention relates to a preparation process for a Cu-based catalyst and use of the Cu-based catalyst as the dehydrogenation catalyst in producing a hydroxyketone compound such as acetoin. Said Cu-based catalyst shows a high the acetoin selectivity as the dehydrogenation catalyst for producing acetoin.

公开(公告)号：US20240216895A1

公开(公告)日：2024-07-04

申请号：US18606313

申请日：2024-03-15

Applicant: Air Company Holdings, Inc.

Inventor： Stafford W. Sheehan ,  Chi Chen ,  Mahlet Garedew-Ballard ,  Neva Luthria ,  Mihir R. Shah ,  Qiyuan Wu

IPC: B01J23/80 ,  B01J21/04 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  C10G2/00

CPC classification number: B01J23/80 ,  B01J21/04 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J37/0036 ,  B01J37/0213 ,  B01J37/031 ,  B01J37/08 ,  C10G2/50 ,  C10G2300/4081 ,  C10G2300/70

Abstract: The present disclosure provides catalysts, reactor systems, and methods for the conversion of carbon dioxide and hydrogen gas into paraffins, olefins, and other hydrocarbon products. Methods for utilization of mixtures of carbon dioxide, carbon monoxide, and hydrogen gas in a manner distinct from legacy Fischer-Tropsch reactors to produce hydrocarbons is also included.

公开(公告)号：US20240189804A1

公开(公告)日：2024-06-13

申请号：US18172132

申请日：2023-02-21

Applicant: Dalian Maritime University

Inventor： Xiaofeng WANG ,  Mengyue QIN ,  Qingbo LI

IPC: B01J29/85 ,  B01J37/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08

CPC classification number: B01J29/85 ,  B01J37/0018 ,  B01J37/031 ,  B01J37/04 ,  B01J37/088

Abstract: The present disclosure belongs to the technical field of denitration catalysts, and provides a Cu-SAPO-34 catalyst and a preparation method and use thereof. In the preparation method provided by the present disclosure, during crystallization growth, an aluminum precursor, a phosphorus precursor, a silicon precursor, and a copper complex form a Cu-SAPO-34 molecular sieve catalyst under the guiding action of a template morpholine, and the template in the Cu-SAPO-34 molecular sieve catalyst is removed by roasting to obtain the Cu-SAPO-34 catalyst. In the preparation method, a molar ratio of phosphorus and aluminum in the Cu-SAPO-34 catalyst is controlled at (0.1-5):1, thereby increasing a particle size and a specific surface area of the Cu-SAPO-34 catalyst, which is conducive to adsorption of a reaction gas to improve a denitration efficiency. Meanwhile, aggregation of Cu2+ after hydrothermal aging of the Cu-SAPO-34 catalyst is suppressed, thereby improving a hydrothermal stability of the Cu-SAPO-34 catalyst.

公开(公告)号：US11999671B2

公开(公告)日：2024-06-04

申请号：US17286903

申请日：2019-12-10

Applicant: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES

Inventor： Feng Jiao ,  Gen Li ,  Xiulian Pan ,  Xinhe Bao

IPC: C07C1/04 ,  B01J8/02 ,  B01J8/24 ,  B01J19/14 ,  B01J21/04 ,  B01J21/06 ,  B01J23/00 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/18 ,  B01J23/26 ,  B01J23/34 ,  B01J23/745 ,  B01J23/75 ,  B01J29/85 ,  B01J35/00 ,  B01J35/61 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  B01J37/18

CPC classification number: C07C1/044 ,  B01J8/02 ,  B01J8/24 ,  B01J19/14 ,  B01J21/04 ,  B01J21/066 ,  B01J23/002 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/18 ,  B01J23/26 ,  B01J23/34 ,  B01J23/745 ,  B01J23/75 ,  B01J29/85 ,  B01J35/19 ,  B01J35/613 ,  B01J35/615 ,  B01J37/0036 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/082 ,  B01J37/10 ,  B01J37/18 ,  C07C1/0435 ,  B01J2229/18 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/18 ,  C07C2523/26 ,  C07C2523/34 ,  C07C2523/745 ,  C07C2523/75

Abstract: A composite catalyst containing heteroatom-doped zeolite for preparing light olefin using direct conversion of syngas is formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide, and the component II is a heteroatom-doped zeolite. The zeolite topology is CHA or AEI, and the skeleton atoms include Al—P—O or Si—Al—P—O; the heteroatoms is at least one of divalent metal Mg, Ca, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sr, Zr, Mo, Cd, Ba and Ce, trivalent metal Ti and Ga, and tetravalent metal Ge. A weight ratio of the active ingredient in the component I to the component II is 0.1-20. The reaction process has high light olefin selectivity; the sum selectivity of the light olefin including ethylene, propylene and butylene can reach 50-90%, while the selectivity of a methane side product is less than 7%.

公开(公告)号：US11958043B2

公开(公告)日：2024-04-16

申请号：US16612660

申请日：2018-05-11

Applicant: William Marsh Rice University

Inventor： Nancy Jean Halas ,  Peter Nordlander ,  Hossein Robatjazi ,  Dayne Francis Swearer ,  Chao Zhang ,  Hangqi Zhao ,  Linan Zhou

IPC: B01J35/00 ,  B01J19/12 ,  B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/00 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/78 ,  B01J23/89 ,  B01J27/04 ,  B01J27/14 ,  B01J27/20 ,  B01J27/22 ,  B01J27/24 ,  B01J31/06 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/34 ,  C01B3/04 ,  C01B3/40 ,  C01B4/00 ,  C01B5/00 ,  C01B21/02 ,  C01B32/40 ,  B01J31/16

CPC classification number: B01J35/004 ,  B01J19/123 ,  B01J19/127 ,  B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/002 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/78 ,  B01J23/8926 ,  B01J23/8946 ,  B01J27/04 ,  B01J27/14 ,  B01J27/20 ,  B01J27/22 ,  B01J27/24 ,  B01J31/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/006 ,  B01J35/008 ,  B01J35/026 ,  B01J35/1066 ,  B01J37/0203 ,  B01J37/0225 ,  B01J37/03 ,  B01J37/031 ,  B01J37/035 ,  B01J37/08 ,  B01J37/344 ,  C01B3/047 ,  C01B3/40 ,  C01B4/00 ,  C01B5/00 ,  C01B21/02 ,  C01B32/40 ,  B01J31/1691 ,  B01J2219/00635 ,  B01J2523/00 ,  B01J2540/66 ,  C01B2203/0238 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  B01J2523/00 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/821

Abstract: A method of making a multicomponent photocatalyst, includes inducing precipitation from a pre-cursor solution comprising a pre-cursor of a plasmonic material and a pre-cursor of a reactive component to form co-precipitated particles; collecting the co-precipitated particles; and annealing the co-precipitated particles to form the multicomponent photocatalyst comprising a reactive component optically, thermally, or electronically coupled to a plasmonic material.

公开(公告)号：US11883798B2

公开(公告)日：2024-01-30

申请号：US17250538

申请日：2019-09-17

Applicant: SABIC Global Technologies B.V.

Inventor： Srikant Gopal ,  Turki Al-Smari

IPC: B01J23/652 ,  B01J37/04 ,  B01J37/08 ,  B01J6/00 ,  B01J37/03 ,  C07C51/16

CPC classification number: B01J23/6525 ,  B01J6/001 ,  B01J37/031 ,  B01J37/04 ,  B01J37/08 ,  C07C51/16

Abstract: Methods of producing a catalyst for oxidation of C2 hydrocarbons and methods of using the catalyst are disclosed. Molybdenum, vanadium, and niobium metal or metal containing compounds are used to form a slurry in water. After agitating the slurry for at least 15 minutes, palladium or a palladium containing compound is added to the slurry. After further agitation, a precipitate is collected, dried and calcined to obtain an active catalyst, with palladium primarily distributed on a surface of the catalyst. The active catalyst is capable of catalyzing the conversion of C2 hydrocarbons into acetic acid.

公开(公告)号：US20230399235A1

公开(公告)日：2023-12-14

申请号：US18022942

申请日：2021-08-02

Applicant: Mitsui Mining & Smelting Co., Ltd.

Inventor： Syuhei HARA ,  Taihei KUMA

IPC: C01G23/00 ,  B01J23/04 ,  B01J37/04 ,  B01J37/03 ,  B01J37/06 ,  C07C211/63

CPC classification number: C01G23/005 ,  B01J23/04 ,  C01G23/006 ,  C07C211/63 ,  B01J37/031 ,  B01J37/06 ,  B01J37/04

Abstract: A novel titanate aqueous solution is provided that is capable of easily preparing titanate compounds composed of alkali metals or alkaline earth metals, wherein the titanate aqueous solution contains titanate ions and quaternary ammonium cations in water, and the titanate aqueous solution is characterized in that 30 g of the titanate aqueous solution (25° C.) adjusted to a concentration containing 9% by mass of titanium in terms of TiO2 is added with 30 mL of a sodium hydroxide aqueous solution (25° C.) having a concentration of 2.2% by mass while stirring to form a precipitate composed of Na2Ti3O7 hydrate, or has a transmittance at a wavelength of 360 nm being 50% or less.

公开(公告)号：US20230398520A1

公开(公告)日：2023-12-14

申请号：US18200001

申请日：2023-05-22

Applicant: CLARIANT INTERNATIONAL LTD

Inventor： Yunyun Zhou ,  Jason Spencer ,  Brooke Ames ,  Yeping Cai

IPC: B01J23/80 ,  B01J23/06 ,  B01J23/00 ,  B01J35/00 ,  B01J37/03 ,  B01J37/08 ,  C01B3/32 ,  H01M8/0612

CPC classification number: B01J23/80 ,  B01J23/06 ,  B01J23/005 ,  B01J35/0066 ,  B01J35/006 ,  B01J37/031 ,  B01J37/088 ,  C01B3/326 ,  H01M8/0618 ,  C01B2203/0233 ,  C01B2203/1223 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/066

Abstract: The present disclosure relates generally to a methanol reforming catalyst composition comprising a ZnO phase, present in the composition in an amount of 20-75 wt. %; a zinc-aluminum spinel phase, present in the composition in an amount of 20-60 wt. %; and a Cu dopant phase, present in the composition in an amount of 0.1-20 wt. %. In various embodiments, the methanol reforming catalyst can achieve stable high methanol conversion rates and high hydrogen production rates at high temperatures (>300° C.).

公开(公告)号：US20230390750A1

公开(公告)日：2023-12-07

申请号：US18249649

申请日：2021-10-19

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC

Inventor： Jing DONG ,  Su LIU ,  Yangdong WANG

IPC: B01J35/00 ,  B01J35/02 ,  B01J37/04 ,  B01J37/03 ,  B01J37/02 ,  B01J37/06 ,  B01J37/00 ,  B01J37/08 ,  B01J29/03 ,  B01J29/78 ,  B01J21/10 ,  B01J21/08 ,  B01J21/12 ,  B01J23/30 ,  B01J23/02 ,  C07C6/04

CPC classification number: B01J35/0006 ,  B01J35/023 ,  B01J35/026 ,  B01J37/04 ,  B01J37/031 ,  B01J37/0236 ,  B01J37/06 ,  B01J37/0018 ,  B01J37/088 ,  B01J29/0341 ,  B01J29/78 ,  B01J21/10 ,  B01J21/08 ,  B01J21/12 ,  B01J23/30 ,  B01J23/02 ,  C07C6/04 ,  C07C2523/30

Abstract: An integrated catalyst can be used in an olefin disproportionation reaction. The integrated catalyst contains a plurality of different integrated active phases. The relative positions among different active phases remain substantially unchanged during the olefin disproportionation reaction. The effective distance between respective bisecting planes of two adjacent different active phases is 0.5-5 mm, preferably 1-3 mm.