公开(公告)号：US20140168855A1

公开(公告)日：2014-06-19

申请号：US14237091

申请日：2012-08-03

申请人： Herve Galiano ,  Meriem Anouti ,  Daniel Lemordant ,  Laure Timperman

发明人： Herve Galiano ,  Meriem Anouti ,  Daniel Lemordant ,  Laure Timperman

IPC分类号： H01G11/58

CPC分类号： H01G11/58 ,  B01J31/0288 ,  C07F9/5407 ,  H01G9/035 ,  H01G9/038 ,  H01G2009/0007 ,  H01G2009/0025 ,  H01M2300/0045 ,  Y02E60/13

摘要： The present invention relates to ionic liquids comprising, as cation, a specific phosphonium cation, as anion, a formiate anion, which can be used, alone or as a mixture, to constitute electrolytes for energy storage devices.

摘要翻译： 本发明涉及离子液体，其包含作为阳离子的特定鏻阳离子作为阴离子，甲酸根阴离子，其可以单独使用或作为混合物用于构成用于储能装置的电解质。

公开(公告)号：US09136066B2

公开(公告)日：2015-09-15

申请号：US14119570

申请日：2012-04-17

申请人： Meriem Anouti ,  Daniel Lemordant ,  Grzegorz Lota ,  Celine Moueza-Decaux ,  Encarnacion Raymundo-Pinero ,  Francois Beguin ,  Philippe Azais

发明人： Meriem Anouti ,  Daniel Lemordant ,  Grzegorz Lota ,  Celine Moueza-Decaux ,  Encarnacion Raymundo-Pinero ,  Francois Beguin ,  Philippe Azais

IPC分类号： H01L21/76 ,  H01G11/84 ,  H01G11/62

CPC分类号： H01G11/84 ,  H01G11/62 ,  Y02E60/13 ,  Y10T29/417

摘要： A method is provided for developing a hybrid supercapacitor. The method includes the use of a lithium salt of the electrolyte to carry out the intercalation/insertion of the lithium at the negative electrode but by greatly increasing the concentration of lithium ions of the electrolyte order to subsequently accept a depletion. As the depletion in ions has an impact on the conductivity, the amount and the concentration of the electrolyte are chosen in order to make it possible to accept this depletion white retaining a conductivity of the electrolyte compatible with a powerful system for storage of energy. A portion of the Li+ ions present in the electrolyte is used to form the passivation layer and the compound for intercalation/insertion Li˜0.5C6 at the negative electrode.

摘要翻译： 提供了一种用于开发混合超级电容器的方法。 该方法包括使用电解质的锂盐在负极处进行锂的插入/插入，但是通过大大增加电解质的锂离子浓度以便随后接受耗尽。 由于离子的耗尽对导电性有影响，因此选择电解质的量和浓度以使得可以接受这种耗尽白色，保持电解质的电导率与强大的能量储存系统兼容。 存在于电解质中的Li +离子的一部分用于形成钝化层和用于在负极处插入/插入Li-0.5C6的化合物。

公开(公告)号：US20140325807A1

公开(公告)日：2014-11-06

申请号：US14119570

申请日：2012-04-17

申请人： Meriem Anouti ,  Daniel Lemordant ,  Grzegorz Lota ,  Celine Moueza-Decaux ,  Encarnacion Raymundo-Pinero ,  Francois Beguin ,  Philippe Azais

发明人： Meriem Anouti ,  Daniel Lemordant ,  Grzegorz Lota ,  Celine Moueza-Decaux ,  Encarnacion Raymundo-Pinero ,  Francois Beguin ,  Philippe Azais

IPC分类号： H01G11/84

CPC分类号： H01G11/84 ,  H01G11/62 ,  Y02E60/13 ,  Y10T29/417

摘要： The invention relates to a method for developing a hybrid supercapacitor, said method including: at least a step of assembling together a negative electrode, made of at least one non-porous carbon material, and a positive electrode, made of at least one porous carbon material, said electrodes being separated from each other by means of at least one separator impregnated with a liquid electrolyte containing at least one lithium salt dissolved in at least one solvent; and then at least one first charging step, wherein said method is characterized in that: a) the lithium-ion concentration in the liquid electrolyte, before the first charging step, is greater than or equal to 1.6 mol/L; b) at least 50 wt % of the lithium salt of the liquid electrolyte contains a salt released from among LiTPSI and the derivatives there of; c) at least 80 vol % of the solvent of the liquid electrolyte contains a solvent selected from among cyclic alkyl carbonates, acyclic alkyl carbonates, lactones, esters, oxalenes, and the mixtures thereof, it being understood then at least 20 vol % of said solvent contains ethylene carbonate; d) the porous carbon material of the positive electrode is selected from among materials, the mean size of the pores of which is greater than 0.7 nm and which has a specific surface area of more than 700 m2/g; e) the non-porous carbon material of the negative electrode is selected from among materials capable of inserting

摘要翻译： 本发明涉及一种用于开发混合超级电容器的方法，所述方法包括：将由至少一种无孔碳材料制成的负极和由至少一种多孔碳制成的正极组装在一起的至少一个步骤 所述电极通过至少一个浸渍有溶解在至少一种溶剂中的至少一种锂盐的液体电解质的隔离物彼此分离; 然后至少一个第一充电步骤，其中所述方法的特征在于：a）在第一充电步骤之前，液体电解质中的锂离子浓度大于或等于1.6mol / L; b）至少50wt％的液体电解质的锂盐含有从LiTPSI及其衍生物中释放的盐; c）至少80体积％的液体电解质的溶剂含有选自环烷基碳酸酯，无环烷基碳酸酯，内酯，酯，草酸及其混合物的溶剂，但应理解的是，所述溶剂的至少20体积％ 溶剂含有碳酸亚乙酯; d）正极的多孔碳材料选自其孔的平均尺寸大于0.7nm并具有大于700m 2 / g的比表面积的材料; e）负极的无孔碳材料选自能够插入的材料