REACTOR FOR HOMOGENEOUS REGENERATION OF SPENT IONIC LIQUID

    公开(公告)号:US20170216828A1

    公开(公告)日:2017-08-03

    申请号:US15010236

    申请日:2016-01-29

    IPC分类号: B01J31/40 B01J38/10 B01J31/02

    摘要: We provide a segmented reactor for regenerating a spent acidic ionic liquid via hydrogenation and hydrocracking, comprising: no solid hydrogenation catalyst; a gas inlet for feeding a gas feed comprising a hydrogen; a liquid inlet for feeding a spent acidic ionic liquid; partitions along an axis of the reactor that create segments, wherein each segment functions as a bubble column reactor; and an outlet from which a regenerated acidic ionic liquid flow out of the segmented reactor. We also provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a solid hydrogenation catalyst in the segmented reactor.

    Method for synthesizing polyoxymethylene dimethyl ethers catalyzed by an ionic liquid
    8.
    发明授权
    Method for synthesizing polyoxymethylene dimethyl ethers catalyzed by an ionic liquid 有权
    由离子液体催化的聚甲醛二甲醚的合成方法

    公开(公告)号:US08816131B2

    公开(公告)日:2014-08-26

    申请号:US13154359

    申请日:2011-06-06

    IPC分类号: C07C41/58 C07C41/50 C07C41/56

    摘要: It is related to a method for preparing polyoxymethylene dimethyl ethers by a continuous acetalation reaction of trioxymethylene and methanol or methylal catalyzed by an ionic liquid. The processing apparatus used in the method includes a reaction zone, a separation zone, a catalyst regeneration zone and a product dehydration zone. A manner of circulating tubular reaction is used, resulting in a high external heat exchange efficiency, a simple structure of design and a low investment. A film evaporator is used, realizing a rapid separation and recycling of the light component, with a high separation efficiency. The separation of the catalyst solution from the crude product is simple, thereby realizing the regeneration and recycling of the catalyst.

    摘要翻译: 它涉及一种通过三氯甲烷和甲醇或甲缩醛通过离子液体催化的连续缩醛反应制备聚甲醛二甲醚的方法。 该方法中使用的处理装置包括反应区,分离区,催化剂再生区和产物脱水区。 使用循环管状反应的方式,导致外部热交换效率高,设计结构简单,投资少。 使用薄膜蒸发器,实现轻组分的快速分离和再循环,分离效率高。 催化剂溶液与粗产物的分离是简单的,从而实现催化剂的再生和再循环。

    Alkylation Process Using Phosphonium-Based Ionic Liquids
    10.
    发明申请
    Alkylation Process Using Phosphonium-Based Ionic Liquids 有权
    使用鏻基离子液体的烷基化方法

    公开(公告)号:US20130345482A1

    公开(公告)日:2013-12-26

    申请号:US13796646

    申请日:2013-03-12

    申请人: UOP LLC

    IPC分类号: C07C2/56

    摘要: A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary phosphonium based ionic liquid, and the reaction is performed at or near ambient temperatures.

    摘要翻译: 提出了制备烷基化物的方法。 该方法包括在烷基化反应器中将异链烷烃流与烯烃物流混合。 烷基化反应器包括用于进行反应的催化剂。 催化剂是基于季鏻的离子液体的离子液体,反应在环境温度或接近环境温度下进行。