Polymers bridged by a transition metal
    1.
    发明申请
    Polymers bridged by a transition metal 审中-公开
    由过渡金属桥接的聚合物

    公开(公告)号:US20060052579A1

    公开(公告)日:2006-03-09

    申请号:US10532723

    申请日:2003-10-24

    IPC分类号: C08G73/06 C08F6/00 C08L57/12

    CPC分类号: C08G65/338 C08G65/33317

    摘要: In the polymer of transition-metal-bridged units of the formula (I) where A is an m-valent organic radical, T independently of one another are O or NH, Q independently of one another are CHR1—CH2 where R1 is H or optionally substituted C1-6-alkyl, R independently of one another are H, 2-pyridyl, 2-imidazolinyl, 2-imidazolyl, 2-thiazolinyl, 2-thiazolyl, 2-pyridazyl, 2-pyrimidyl, carboxyl, carboxylic ester radical, carboxamide radical, carboxylate, phosphonate, where at least one of the radicals R is different from H, M is Fe2+, Fe3+, Co2+, Co3+, Zn2+, Ru2+, Os2+, Ni2+, Z is SO42−, CH3OO−, BF4−, SF6−, Cl−, I−, PF6−, perchlorate, n is 1 to 10 000, m is 2 to 100, p is a number which corresponds to the charge balance within the polymer, the average molecular weight of the polymer is at least 15 000.

    摘要翻译: 在式(I)的过渡金属桥接单元的聚合物中,