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公开(公告)号：US20060052579A1
公开(公告)日：2006-03-09
申请号：US10532723
申请日：2003-10-24
CPC分类号： C08G65/338 , C08G65/33317
摘要： In the polymer of transition-metal-bridged units of the formula (I) where A is an m-valent organic radical, T independently of one another are O or NH, Q independently of one another are CHR1—CH2 where R1 is H or optionally substituted C1-6-alkyl, R independently of one another are H, 2-pyridyl, 2-imidazolinyl, 2-imidazolyl, 2-thiazolinyl, 2-thiazolyl, 2-pyridazyl, 2-pyrimidyl, carboxyl, carboxylic ester radical, carboxamide radical, carboxylate, phosphonate, where at least one of the radicals R is different from H, M is Fe2+, Fe3+, Co2+, Co3+, Zn2+, Ru2+, Os2+, Ni2+, Z is SO42−, CH3OO−, BF4−, SF6−, Cl−, I−, PF6−, perchlorate, n is 1 to 10 000, m is 2 to 100, p is a number which corresponds to the charge balance within the polymer, the average molecular weight of the polymer is at least 15 000.
摘要翻译： 在式（I）的过渡金属桥接单元的聚合物中，
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2.发明授权Method of preparing glass and ceramic enamels on glass for adhesive bonding 有权在玻璃上制备用于粘合剂的玻璃和陶瓷搪瓷的方法公开(公告)号：US08435371B2
公开(公告)日：2013-05-07
申请号：US12373763
申请日：2008-05-19
CPC分类号： C03C23/0075 , B60J1/02 , C09J101/02
摘要： In one embodiment, the invention is a method comprising contacting a composition comprising i) alumina particles having a particle size of about 1 to about 40 microns and a Mohs hardness of about 9.0 to about 9.5; ii) one or more alkyl sulphates; iii) one or more thickeners; and iv) water with the surface of glass or a ceramic frit disposed on the surface of glass. The contacting can be performed by applying the composition to the surface of the glass or the ceramic frit using an application apparatus. In one embodiment, the composition further comprises a lubricant. In another embodiment, the composition further comprises one or more ethoxylated alcohols. In another embodiment, the composition further comprises one or more fragrances.
摘要翻译： 在一个实施方案中，本发明是一种方法，包括使包含i）具有约1至约40微米的粒度的氧化铝颗粒和约9.0至约9.5的莫氏硬度的组合物接触; ii）一种或多种烷基硫酸盐; iii）一种或多种增稠剂; 和iv）配置在玻璃表面上的玻璃表面或陶瓷玻璃料的水。 可以通过使用施加装置将组合物施加到玻璃或陶瓷玻璃料的表面来进行接触。 在一个实施方案中，组合物还包含润滑剂。 在另一个实施方案中，组合物还包含一种或多种乙氧基化醇。 在另一个实施方案中，组合物还包含一种或多种香料。
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公开(公告)号：US20110218299A1
公开(公告)日：2011-09-08
申请号：US13112378
申请日：2011-05-20
申请人： Stefan Schmatloch , Dirk Schwöeppe
发明人： Stefan Schmatloch , Dirk Schwöeppe
IPC分类号： C09D175/04 , C08G18/38 , C08K13/02 , C08K5/11
CPC分类号： C08G18/776 , C08G18/10 , C08G18/289 , C08G2190/00 , C09J5/02 , C09J175/04 , Y10T428/31547 , Y10T428/31551 , Y10T428/31554
摘要： A composition for and method for bonding a substrate. In general, applied to a substrate will be a primer composition that includes an adhesion promoter, which is an adduct prepared by the reaction of at least one aromatic polyisocyanate compound, with an active hydrogen containing moiety of an organofunctional silane, and a prepolymer derived from the reaction of at least one aliphatic polyisocyanate and a polyol, and is at least partially reacted with an active hydrogen containing moiety of an organofunctional silane.
摘要翻译： 用于粘合基材的组合物和方法。 通常，应用于底物将是底漆组合物，其包括粘合促进剂，其是通过至少一种芳族多异氰酸酯化合物与有机官能硅烷的含活性氢部分反应制备的加合物，以及衍生自 至少一种脂族多异氰酸酯和多元醇的反应，并且至少部分地与有机官能硅烷的含活性氢部分反应。
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4.发明申请WATER BASED PRIMER COMPOSITION FOR ISOCYANTE AND SILANE FUNCTIONAL ADHESIVES 有权用于异氰酸酯和硅烷官能粘合剂的水基聚合物组合物公开(公告)号：US20120318436A1
公开(公告)日：2012-12-20
申请号：US13577668
申请日：2011-03-04
申请人： Stefan Schmatloch
发明人： Stefan Schmatloch
CPC分类号： C09J183/08 , C03C17/32 , C03C17/322 , C08G18/10 , C08K5/05 , C08K5/544 , C08L83/08 , C09D183/04 , C09D183/08 , C09J175/04
摘要： The present invention is directed to a unique solution for promoting adhesion of substrates to adhesives containing a prepolymer having isocyanate, si lane or both functional groups. The solution comprises a composition comprising: a) from about 0.05 to about 10.0 parts by weight of a hydrosylate of one or more of alkoxysilyl amines; b) from about 0.05 to about 1.0 parts by weight of one of more alkoxylated alcohols, alkoxysilyl terminated alkoxylated alcohols, fatly acids or fatty acid esters; and, c) from about 80 to about 99.9 parts by weight of water: wherein the composition contains 100 parts by weight and the composition exhibits a pH of about 9 to about 12.
摘要翻译： 本发明涉及用于促进基材对含有具有异氰酸酯，硅烷或双官能团的预聚物的粘合剂的粘附的独特解决方案。 该溶液包含一种组合物，其包含：a）约0.05至约10.0重量份的一种或多种烷氧基甲硅烷基胺的氢化甲苯磺酸盐; b）约0.05至约1.0重量份的烷氧基化醇，烷氧基甲硅烷基封端的烷氧基化醇，脂肪酸或脂肪酸酯之一; 和c）约80-约99.9重量份的水：其中组合物含有100重量份，组合物显示约9至约12的pH。
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公开(公告)号：US08298368B2
公开(公告)日：2012-10-30
申请号：US13112378
申请日：2011-05-20
申请人： Stefan Schmatloch , Dirk Schwöeppe
发明人： Stefan Schmatloch , Dirk Schwöeppe
CPC分类号： C08G18/776 , C08G18/10 , C08G18/289 , C08G2190/00 , C09J5/02 , C09J175/04 , Y10T428/31547 , Y10T428/31551 , Y10T428/31554
摘要： A composition for and method for bonding a substrate. In general, applied to a substrate will be a primer composition that includes an adhesion promoter, which is an adduct prepared by the reaction of at least one aromatic polyisocyanate compound, with an active hydrogen containing moiety of an organofunctional silane, and a prepolymer derived from the reaction of at least one aliphatic polyisocyanate and a polyol, and is at least partially reacted with an active hydrogen containing moiety of an organofunctional silane.
摘要翻译： 用于粘合基材的组合物和方法。 通常，应用于底物将是底漆组合物，其包括粘合促进剂，其是通过至少一种芳族多异氰酸酯化合物与有机官能硅烷的含活性氢部分反应制备的加合物，以及衍生自 至少一种脂族多异氰酸酯和多元醇的反应，并且至少部分地与有机官能硅烷的含活性氢部分反应。
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6.发明授权公开(公告)号：US08080609B2
公开(公告)日：2011-12-20
申请号：US12608366
申请日：2009-10-29
申请人： Stefan Schmatloch
发明人： Stefan Schmatloch
IPC分类号： B05D3/02 , B32B27/00 , B32B27/40 , C08G18/00 , C08G18/08 , C08G18/10 , C08G18/28 , C08G77/04 , C08G77/06 , C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00 , C08L83/04 , C09J4/00 , C09J7/02 , C09J101/00 , C09J201/00
CPC分类号： C08G18/755 , C08G18/2027 , C08G18/289 , C08G18/3206 , C08G18/3296 , C08G18/4829 , C08G18/724 , C08G18/7671 , C08G18/776 , C08G18/8025 , C08G18/809 , C08K3/04 , C08L33/08 , C08L2666/20 , C09J175/04 , Y10S524/906 , Y10T428/31551 , C08G18/10
摘要： The invention is a composition comprisinga) one or more prepolymers having on average three or more aliphatic isocyanate groups and further containing alkoxysilane groups; b) one or more aromatic polyisocyanates; c) one or more compounds having at least one heterocyclic ring which hydrolyzes when exposed to moisture to form at least one isocyanate reactive group; d) one or more solvents; and e) one or more amine and/or organometallic polyurethane catalysts; wherein the ratio of aromatic isocyanate groups to aliphatic isocyanate groups in the composition is from about 0.5:1.0 to about 1.5:1.0, preferably about 0.9:1.0 to about 1.5:1.0, and the equivalent ratio of isocyanate groups to isocyanate reactive groups derivable from the one or more compounds having at least one hydrolyzable heterocylic ring is from about 0.8:1.0 to about 5.3:1.0, and most preferably about 1.5:1.0 to about 1.7:1.0.
摘要翻译： 本发明是一种组合物，其包含a）一种或多种具有平均三个或更多个脂族异氰酸酯基并进一步含有烷氧基硅烷基团的预聚物; b）一种或多种芳族多异氰酸酯; c）一种或多种具有至少一个杂环的化合物，其在暴露于水分时水解以形成至少一种异氰酸酯反应性基团; d）一种或多种溶剂; 和e）一种或多种胺和/或有机金属聚氨酯催化剂; 其中组合物中芳族异氰酸酯基团与脂肪族异氰酸酯基团的比率为约0.5:1.0至约1.5:1.0，优选约0.9:1.0至约1.5:1.0，异氰酸酯基团与异氰酸酯反应性基团的当量比可衍生自 一种或多种具有至少一个可水解杂环的化合物为约0.8:1.0至约5.3:1.0，最优选约1.5:1.0至约1.7:1.0。
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公开(公告)号：US07956151B2
公开(公告)日：2011-06-07
申请号：US12618298
申请日：2009-11-13
申请人： Stefan Schmatloch , Dirk Schwöeppe
发明人： Stefan Schmatloch , Dirk Schwöeppe
IPC分类号： C08G77/04 , C09J101/00
CPC分类号： C08G18/776 , C08G18/10 , C08G18/289 , C08G2190/00 , C09J5/02 , C09J175/04 , Y10T428/31547 , Y10T428/31551 , Y10T428/31554
摘要： A composition for and method for bonding a substrate. In general, applied to a substrate will be a primer composition that includes an adhesion promoter, which is an adduct prepared by the reaction of at least one aromatic polyisocyanate compound, with an active hydrogen containing moiety of an organofunctional silane, and a prepolymer derived from the reaction of at least one aliphatic polyisocyanate and a polyol, and is at least partially reacted with an active hydrogen containing moiety of an organofunctional silane.
摘要翻译： 用于粘合基材的组合物和方法。 通常，应用于底物将是底漆组合物，其包括粘合促进剂，其是通过至少一种芳族多异氰酸酯化合物与有机官能硅烷的含活性氢部分反应制备的加合物，以及衍生自 至少一种脂族多异氰酸酯和多元醇的反应，并且至少部分地与有机官能硅烷的含活性氢部分反应。
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8.发明申请公开(公告)号：US20100105829A1
公开(公告)日：2010-04-29
申请号：US12608366
申请日：2009-10-29
申请人： Stefan Schmatloch
发明人： Stefan Schmatloch
CPC分类号： C08G18/755 , C08G18/2027 , C08G18/289 , C08G18/3206 , C08G18/3296 , C08G18/4829 , C08G18/724 , C08G18/7671 , C08G18/776 , C08G18/8025 , C08G18/809 , C08K3/04 , C08L33/08 , C08L2666/20 , C09J175/04 , Y10S524/906 , Y10T428/31551 , C08G18/10
摘要： The invention is a composition comprisinga) one or more prepolymers having on average three or more aliphatic isocyanate groups and further containing alkoxysilane groups; b) one or more aromatic polyisocyanates; c) one or more compounds having at least one heterocyclic ring which hydrolyzes when exposed to moisture to form at least one isocyanate reactive group; d) one or more solvents; and e) one or more amine and/or organometallic polyurethane catalysts; wherein the ratio of aromatic isocyanate groups to aliphatic isocyanate groups in the composition is from about 0.5:1.0 to about 1.5:1.0, preferably about 0.9:1.0 to about 1.5:1.0, and the equivalent ratio of isocyanate groups to isocyanate reactive groups derivable from the one or more compounds having at least one hydrolyzable heterocylic ring is from about 0.8:1.0 to about 5.3:1.0, and most preferably about 1.5:1.0 to about 1.7:1.0.
摘要翻译： 本发明是一种组合物，其包含a）一种或多种具有平均三个或更多个脂族异氰酸酯基并进一步含有烷氧基硅烷基团的预聚物; b）一种或多种芳族多异氰酸酯; c）一种或多种具有至少一个杂环的化合物，其在暴露于水分时水解以形成至少一种异氰酸酯反应性基团; d）一种或多种溶剂; 和e）一种或多种胺和/或有机金属聚氨酯催化剂; 其中组合物中芳族异氰酸酯基团与脂肪族异氰酸酯基团的比率为约0.5:1.0至约1.5:1.0，优选约0.9:1.0至约1.5:1.0，异氰酸酯基团与异氰酸酯反应性基团的当量比可衍生自 一种或多种具有至少一个可水解杂环的化合物为约0.8:1.0至约5.3:1.0，最优选约1.5:1.0至约1.7:1.0。
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公开(公告)号：US20080268259A1
公开(公告)日：2008-10-30
申请号：US12041915
申请日：2008-03-04
申请人： Stefan Schmatloch , Dirk Schwoeppe
发明人： Stefan Schmatloch , Dirk Schwoeppe
CPC分类号： C08G18/776 , C08G18/10 , C08G18/289 , C08G2190/00 , C09J5/02 , C09J175/04 , Y10T428/31547 , Y10T428/31551 , Y10T428/31554
摘要： A composition for and method for bonding a substrate. In general, applied to a substrate will be a primer composition that includes an adhesion promoter, which is an adduct prepared by the reaction of at least one aromatic polyisocyanate compound, with an active hydrogen containing moiety of an organofunctional silane, and a prepolymer derived from the reaction of at least one aliphatic polyisocyanate and a polyol, and is at least partially reacted with an active hydrogen containing moiety of an organofunctional silane.
摘要翻译： 用于粘合基材的组合物和方法。 通常，应用于底物将是底漆组合物，其包括粘合促进剂，其是通过至少一种芳族多异氰酸酯化合物与有机官能硅烷的含活性氢部分反应制备的加合物，以及衍生自 至少一种脂族多异氰酸酯和多元醇的反应，并且至少部分地与有机官能硅烷的含活性氢部分反应。
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10.发明授权Water based primer composition for isocyante and silane functional adhesives 有权用于异氰酸酯和硅烷官能粘合剂的水性底漆组合物公开(公告)号：US08673999B2
公开(公告)日：2014-03-18
申请号：US13577668
申请日：2011-03-04
申请人： Stefan Schmatloch
发明人： Stefan Schmatloch
IPC分类号： C09J175/04 , C09J183/04 , C08L83/08 , C08G18/10 , C03C17/32 , C08K5/544 , C08K5/05 , C09J183/08
CPC分类号： C09J183/08 , C03C17/32 , C03C17/322 , C08G18/10 , C08K5/05 , C08K5/544 , C08L83/08 , C09D183/04 , C09D183/08 , C09J175/04
摘要： The present invention is directed to a unique solution for promoting adhesion of substrates to adhesives containing a prepolymer having isocyanate, silane or both functional groups. The solution comprises a composition comprising: a) from about 0.05 to about 10.0 parts by weight of a hydrolysate of one or more of alkoxysilyl amines; b) from about 0.05 to about 1.0 parts by weight of one of more alkoxylated alcohols, alkoxysilyl terminated alkoxylated alcohols, fatly acids or fatty acid esters; and, c) from about 80 to about 99.9 parts by weight of water: wherein the composition contains 100 parts by weight and the composition exhibits a pH of about 9 to about 12.
摘要翻译： 本发明涉及用于促进基材对含有具有异氰酸酯，硅烷或两种官能团的预聚物的粘合剂的粘附的独特解决方案。 该溶液包含一种组合物，其包含：a）约0.05至约10.0重量份的一种或多种烷氧基甲硅烷基胺的水解产物; b）约0.05至约1.0重量份的烷氧基化醇，烷氧基甲硅烷基封端的烷氧基化醇，脂肪酸或脂肪酸酯之一; 和c）约80-约99.9重量份的水：其中组合物含有100重量份，组合物显示约9至约12的pH。
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