公开(公告)号：US06426314B1

公开(公告)日：2002-07-30

申请号：US09872220

申请日：2001-05-31

申请人： David W. Carroll ,  Kenneth V. Salazar ,  Mitchell Trkula ,  Cynthia W. Sandoval

发明人： David W. Carroll ,  Kenneth V. Salazar ,  Mitchell Trkula ,  Cynthia W. Sandoval

IPC分类号： H01J718

CPC分类号： C01B3/00 ,  B01J20/223 ,  B01J20/30 ,  B01J31/2291 ,  B01J31/2295 ,  B01J37/345 ,  B01J2531/46 ,  B01J2531/824 ,  B01J2531/847 ,  Y02E60/327 ,  Y02E60/328

摘要： There has been invented a codeposition process for fabricating hydrogen scavengers. First, a &pgr;-bonded allylic organometallic complex is prepared by reacting an allylic transition metal halide with an organic ligand complexed with an alkali metal; and then, in a second step, a vapor of the &pgr;-bonded allylic organometallic complex is combined with the vapor of an acetylenic compound, irradiated with UV light, and codeposited on a substrate.

摘要翻译： 已经发明了用于制造氢清除剂的共沉积方法。 首先，通过使烯丙基过渡金属卤化物与与碱金属络合的有机配体反应制备π键合的烯丙基有机金属络合物; 然后在第二步中，将pi键合的烯丙基有机金属络合物的蒸气与用紫外线照射的炔属化合物的蒸气组合，并共沉积在基材上。

公开(公告)号：US5783335A

公开(公告)日：1998-07-21

申请号：US864725

申请日：1992-04-07

申请人： Joseph R. Laia, Jr. ,  David W. Carroll ,  Mitchell Trkula ,  Wallace E. Anderson ,  Steven M. Valone

发明人： Joseph R. Laia, Jr. ,  David W. Carroll ,  Mitchell Trkula ,  Wallace E. Anderson ,  Steven M. Valone

IPC分类号： B01J8/18 ,  B01J8/24 ,  B01J8/42 ,  C23C16/27 ,  C23C16/442 ,  C30B25/02

CPC分类号： C23C16/442 ,  B01J8/1836 ,  B01J8/24 ,  B01J8/42 ,  C23C16/27 ,  C30B25/02 ,  C30B29/04

摘要： A process for coating a substrate with diamond or diamond-like material including maintaining a substrate within a bed of particles capable of being fluidized, the particles having substantially uniform dimensions and the substrate characterized as having different dimensions than the bed particles, fluidizing the bed of particles, and depositing a coating of diamond or diamond-like material upon the substrate by chemical vapor deposition of a carbon-containing precursor gas mixture, the precursor gas mixture introduced into the fluidized bed under conditions resulting in excitation mechanisms sufficient to form the diamond coating.

摘要翻译： 一种用金刚石或类金刚石材料涂覆基材的方法，包括将基材保持在能够流化的颗粒床内，所述颗粒具有基本上均匀的尺寸，并且所述基材的特征在于具有与所述床颗粒不同的尺寸， 颗粒，以及通过化学气相沉积含碳前体气体混合物将金刚石或类金刚石材料涂层沉积在基材上，将前体气体混合物引入流化床中，产生足以形成金刚石涂层的激发机制 。

公开(公告)号：US5560897A

公开(公告)日：1996-10-01

申请号：US133726

申请日：1993-10-07

申请人： Steven M. Valone ,  Stevan G. Pattillo ,  Mitchell Trkula ,  Don M. Coates ,  S. Ismat Shah

发明人： Steven M. Valone ,  Stevan G. Pattillo ,  Mitchell Trkula ,  Don M. Coates ,  S. Ismat Shah

IPC分类号： C01B31/06

CPC分类号： C01B31/06

摘要： A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

摘要翻译： 公开了一种通过使烃类材料（例如烃类纤维）在气态进料流中进行等离子体处理足够的时间以形成金刚石（例如金刚石纤维）来制备金刚石，例如金刚石纤维的方法。 该方法通常还包括在用等离子体处理之前，在含氧气氛中，在足以增加所述烃材料内的交联的温度下，但在不足以熔化或分解所述烃材料的温度下加热烃原料，然后在 温度足以促进所述交联烃材料的除气，但是在不足以将所述烃材料转化为碳的温度下。