公开(公告)号：US06355671B1

公开(公告)日：2002-03-12

申请号：US09581089

申请日：2000-06-09

申请人： Sotaro Miyano ,  Nobuhiko Iki ,  Toyohisa Fujimoto ,  Fumio Hamada ,  Shingo Kato ,  Yoshiyuki Hiraishi ,  Hitoshi Kumagai ,  Mitsuharu Hasegawa ,  Setsuko Miyanari ,  Yoshihiro Sugawa ,  Masahiro Ishizuka

发明人： Sotaro Miyano ,  Nobuhiko Iki ,  Toyohisa Fujimoto ,  Fumio Hamada ,  Shingo Kato ,  Yoshiyuki Hiraishi ,  Hitoshi Kumagai ,  Mitsuharu Hasegawa ,  Setsuko Miyanari ,  Yoshihiro Sugawa ,  Masahiro Ishizuka

IPC分类号： A61K3138

CPC分类号： B01D15/00 ,  B01J20/22 ,  B01J20/26

摘要： A sulfonic acid compound of a cyclic phenol sulfide represented by formula (1): (wherein X represents a hydrogen atom, a hydrocarbon group, or an acyl group; M represents a hydrogen atom, an alkyl group, a metal, ammonium, (lower-alkyl)ammonium, (lower-alkanol)ammonium, a nitrogen-containing heterocyclic group, or an amino acid residue; Z represents Sm, SO, or SO2; m is an integer of from 1 to 7; and n is an integer of from 4 to 12, with the proviso that the plural X's, M's and Z's are each the same or different, and at least one of the plural M's is neither a hydrogen atom nor an alkyl group), or a salt thereof; a composition for separating and recovering an organic halogen compound or a monocyclic aromatic compound, comprising a cyclic phenol sulfide or a salt thereof, and a carrier; and a pharmaceutical composition a cyclic phenol sulfide or a pharmaceutically acceptable salt, and a carrier.

摘要翻译： 由式（1）表示的环状苯酚硫化物的磺酸化合物:(其中X表示氢原子，烃基或酰基; M表示氢原子，烷基，金属，铵，（低级 - 烷基）铵，（低级链烷醇）铵，含氮杂环基或氨基酸残基; Z表示Sm，SO或SO2; m为1至7的整数; n为 4至12，条件是复数X，M和Z各自相同或不同，并且多个M中的至少一个既不是氢原子也不是烷基）或其盐; 用于分离和回收有机卤素化合物或单环芳族化合物的组合物，其包含环状苯酚硫化物或其盐和载体; 和药物组合物，环状苯酚硫化物或药学上可接受的盐，以及载体。

公开(公告)号：US5824808A

公开(公告)日：1998-10-20

申请号：US614969

申请日：1996-03-11

申请人： Takashi Hori ,  Hitoshi Kumagai ,  Mitsuharu Hasegawa ,  Yoko Sato ,  Hiroshi Munakata ,  Yoshihiro Sugawa

发明人： Takashi Hori ,  Hitoshi Kumagai ,  Mitsuharu Hasegawa ,  Yoko Sato ,  Hiroshi Munakata ,  Yoshihiro Sugawa

IPC分类号： C07D341/00 ,  C07D331/02 ,  C07D327/00 ,  C07D339/00 ,  C08G65/38

CPC分类号： C07D341/00

摘要： A cyclic phenol sulfide represented by the following formula (1) is described: ##STR1## wherein X represents a hydrogen atom, a hydrocarbon group, or an acyl group; Y.sub.1 represents a hydrogen atom, a hydrocarbon group, a halogenated hydrocarbon group, --COR.sup.1, --OR.sup.2, --COOR.sup.3, --CN, --CONH.sub.2, --NO.sub.2, --NR.sup.4 R.sup.5, a halogen atom, --SO.sub.4 R.sup.6, or --SO.sub.3 R.sup.7, in which R.sup.11, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, and R.sup.7 each represents a hydrogen atom or a hydrocarbon group; n is an integer of 3 or more; and m is an integer of 1 to 7, provided that the plural m's of the S.sub.m 's are the same or different; the plural X's are the same or different; and the plural Y.sub.1 's are the same or different. A process for producing the cyclic phenol sulfide is also described.

摘要翻译： 描述由下式（1）表示的环状苯酚硫化物：其中X表示氢原子，烃基或酰基;（1） Y1表示氢原子，烃基，卤代烃基，-COR1，-OR2，-COOR3，-CN，-CONH2，-NO2，-NR4R5，卤素原子，-SO4R6或-SO3R7，其中R11 ，R2，R3，R4，R5，R6和R7各自表示氢原子或烃基; n为3以上的整数， 并且m是1至7的整数，条件是Sm的多个m相同或不同; 复数X是相同或不同的; 并且多个Y1相同或不同。 还描述了制备环状苯酚硫化物的方法。