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1.发明申请LADDER POLYMERS WITH INTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF 有权具有内在微结构的梯形聚合物及其生产方法公开(公告)号：US20140243441A1
公开(公告)日：2014-08-28
申请号：US14206065
申请日：2014-03-12
CPC分类号： C08J9/00 , B01D53/02 , B01D53/228 , B01D71/76 , B01D2253/202 , B01D2256/12 , B01D2256/22 , B01D2257/102 , B01J20/26 , B01J20/262 , B01J20/28033 , B01J20/2808 , C07D339/08 , C08G65/40 , C08G65/4006 , C08G75/23 , C08L2205/05
摘要： A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.
摘要翻译： 式（I）的聚合物：其中：n为10至5000的整数; m为10〜5000的整数; Ar1和Ar3相同或不同，是衍生自四羟基芳族单体的残基，四羟基芳族单体是其中R相同或不同，为H或C1-C8烷基，C2-C8链烯基或C3 -C8环烷基 并且Ar 2和Ar 4相同或不同，并且是衍生自四卤代芳族单体的残基，其中X是F，Cl或Br的四卤代芳族单体，R 1和R 2相同或不同，其中 y为1〜8的整数， 条件是当Ar 1与Ar 3相同且Ar 2与Ar 4相同时，R 1和R 2不能同时为-CN可用作气体分离，气相分离，吸附剂或催化剂的材料。
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2.发明授权Ladder polymers with instrinsic microporosity and process for production thereof 有权具有固有微孔性的梯形聚合物及其生产方法公开(公告)号：US08686104B2
公开(公告)日：2014-04-01
申请号：US13063816
申请日：2009-10-16
CPC分类号： C08J9/00 , B01D53/02 , B01D53/228 , B01D71/76 , B01D2253/202 , B01D2256/12 , B01D2256/22 , B01D2257/102 , B01J20/26 , B01J20/262 , B01J20/28033 , B01J20/2808 , C07D339/08 , C08G65/40 , C08G65/4006 , C08G75/23 , C08L2205/05
摘要： A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.
摘要翻译： 式（I）的聚合物：其中：n为10至5000的整数; m为10〜5000的整数; Ar1和Ar3相同或不同，是衍生自四羟基芳族单体的残基，四羟基芳族单体是其中R相同或不同，为H或C1-C8烷基，C2-C8链烯基或C3 -C8环烷基 并且Ar 2和Ar 4相同或不同，并且是衍生自四卤代芳族单体的残基，其中X是F，Cl或Br的四卤代芳族单体，R 1和R 2相同或不同，其中 y为1〜8的整数; 条件是当Ar 1与Ar 3相同且Ar 2与Ar 4相同时，R 1和R 2不能同时为-CN可用作气体分离，气相分离，吸附剂或催化剂的材料。
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3.发明授权Ladder polymers with intrinsic microporosity and process for production thereof 有权具有固有微孔性的梯形聚合物及其生产方法公开(公告)号：US09371429B2
公开(公告)日：2016-06-21
申请号：US14206065
申请日：2014-03-12
IPC分类号： C08G59/06 , C08G59/14 , C08G65/40 , C08J9/00 , B01D53/02 , B01D53/22 , B01D71/76 , B01J20/26 , B01J20/28 , C07D339/08 , C08G75/23 , C08G59/00 , C08G65/00
CPC分类号： C08J9/00 , B01D53/02 , B01D53/228 , B01D71/76 , B01D2253/202 , B01D2256/12 , B01D2256/22 , B01D2257/102 , B01J20/26 , B01J20/262 , B01J20/28033 , B01J20/2808 , C07D339/08 , C08G65/40 , C08G65/4006 , C08G75/23 , C08L2205/05
摘要： A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.
摘要翻译： 式（I）的聚合物：其中：n为10至5000的整数; m为10〜5000的整数; Ar1和Ar3相同或不同，是衍生自四羟基芳族单体的残基，四羟基芳族单体是其中R相同或不同，为H或C1-C8烷基，C2-C8链烯基或C3 -C8环烷基 并且Ar 2和Ar 4相同或不同，并且是衍生自四卤代芳族单体的残基，其中X是F，Cl或Br的四卤代芳族单体，R 1和R 2相同或不同，其中 y为1〜8的整数; 条件是当Ar 1与Ar 3相同且Ar 2与Ar 4相同时，R 1和R 2不能同时为-CN可用作气体分离，气相分离，吸附剂或催化剂的材料。
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4.发明申请LADDER POLYMERS WITH INSTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF 有权具有内在微结构的梯形聚合物及其生产方法公开(公告)号：US20110190409A1
公开(公告)日：2011-08-04
申请号：US13063816
申请日：2009-10-16
IPC分类号： C08G65/40 , C08G75/23 , C08J9/00 , C07D339/08
CPC分类号： C08J9/00 , B01D53/02 , B01D53/228 , B01D71/76 , B01D2253/202 , B01D2256/12 , B01D2256/22 , B01D2257/102 , B01J20/26 , B01J20/262 , B01J20/28033 , B01J20/2808 , C07D339/08 , C08G65/40 , C08G65/4006 , C08G75/23 , C08L2205/05
摘要： A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.
摘要翻译： 式（I）的聚合物：其中：n为10至5000的整数; m为10〜5000的整数; Ar1和Ar3相同或不同，是衍生自四羟基芳族单体的残基，四羟基芳族单体是其中R相同或不同，为H或C 1 -C 8烷基，C 2 -C 8烯基或C 3 -C8环烷基 并且Ar 2和Ar 4相同或不同，并且是衍生自四卤代芳族单体的残基，其中X是F，Cl或Br的四卤代芳族单体，R 1和R 2相同或不同，其中 y为1〜8的整数; 条件是当Ar 1与Ar 3相同且Ar 2与Ar 4相同时，R 1和R 2不能同时为-CN可用作气体分离，气相分离，吸附剂或催化剂的材料。
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公开(公告)号：US08623928B2
公开(公告)日：2014-01-07
申请号：US13509630
申请日：2010-10-28
申请人： Naiying Du , Michael D. Guiver
发明人： Naiying Du , Michael D. Guiver
IPC分类号： B01J41/14 , C07D257/00
CPC分类号： C08G65/48 , C08G65/4006
摘要： The invention provides a tetrazole-containing polymer of intrinsic microporosity comprising (10) or more subunits, wherein one or more of the subunits comprise one or more tetrazolyl moieties. In one embodiment, a polymer of intrinsic microporosity (PIM-1) was modified using a “click chemistry” [2+3] cycloaddition reaction with sodium azide and zinc chloride to yield new PIMs containing tetrazole units. Polymers of the present invention are useful as high-performance materials for membrane-based gas separation, materials for ion exchange resins, materials for chelating resins, materials for superabsorbents, materials for ion conductive matrixes, materials for catalyst supports or materials for nanoparticle stabilizers.
摘要翻译： 本发明提供了含有（10）或更多个亚基的本征微孔的含四唑的聚合物，其中一个或多个亚基包含一个或多个四唑基部分。 在一个实施方案中，使用与叠氮化钠和氯化锌进行“点击化学”[2 + 3]环加成反应来改变本征微孔性聚合物（PIM-1），以产生含有四唑单元的新型PIM。 本发明的聚合物可用作用于膜基气体分离的高性能材料，用于离子交换树脂的材料，用于螯合树脂的材料，用于超吸收剂的材料，用于离子传导性基质的材料，用于催化剂载体的材料或用于纳米颗粒稳定剂的材料。
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6.发明申请Carboxylated Polymers of Intrinsic Microporosity (PIMs) with Tunable Gas Transport Properties 有权具有可调气体运输特性的固有微孔（PIM）的羧基化聚合物公开(公告)号：US20120041084A1
公开(公告)日：2012-02-16
申请号：US13266304
申请日：2010-03-10
CPC分类号： C08G65/48 , C08J5/18 , C08J2371/02 , C08L71/02
摘要： A film of a carboxylated polymer of formula (I): wherein the sum of x, y and z is an integer from 10 to 10,000 and degree of hydrolysis is 0.05 or greater provides gas separation materials in which the degree of hydrolysis may be used to tune the selectivity of the gases to an optimal required range. Such films may be prepared by casting a film of a polymer of formula (II): wherein n is an integer from 10 to 10,000, and hydrolyzing all or a portion of the —CN groups to form —COOH groups.
摘要翻译： 式（I）的羧化聚合物的膜：其中x，y和z的总和为10至10,000的整数，水解度为0.05或更大提供可以使用水解度的气体分离材料 将气体的选择性调整到最佳所需范围。 这样的膜可以通过浇铸式（II）的聚合物的膜来制备：其中n是10至10,000的整数，并且将全部或部分-CN基团水解形成-COOH基团。
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7.发明授权Carboxylated polymers of intrinsic microporosity (PIMs) with tunable gas transport properties 有权具有可调气体传输性能的固有微孔（PIM）的羧基化聚合物公开(公告)号：US08809488B2
公开(公告)日：2014-08-19
申请号：US13266304
申请日：2010-03-10
CPC分类号： C08G65/48 , C08J5/18 , C08J2371/02 , C08L71/02
摘要： A film of a carboxylated polymer of formula (I): wherein the sum of x, y and z is an integer from 10 to 10,000 and degree of hydrolysis is 0.05 or greater provides gas separation materials in which the degree of hydrolysis may be used to tune the selectivity of the gases to an optimal required range. Such films may be prepared by casting a film of a polymer of formula (II): wherein n is an integer from 10 to 10,000, and hydrolyzing all or a portion of the —CN groups to form —COOH groups.
摘要翻译： 式（I）的羧化聚合物的膜：其中x，y和z的总和为10至10,000的整数，水解度为0.05或更大提供可以使用水解度的气体分离材料 将气体的选择性调整到最佳所需范围。 这样的膜可以通过浇铸式（II）的聚合物的膜来制备：其中n是10至10,000的整数，并且将全部或部分-CN基团水解形成-COOH基团。
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公开(公告)号：US20120264589A1
公开(公告)日：2012-10-18
申请号：US13509630
申请日：2010-10-28
申请人： Naiying Du , Michael D. Guiver
发明人： Naiying Du , Michael D. Guiver
CPC分类号： C08G65/48 , C08G65/4006
摘要： The invention provides a tetrazole-containing polymer of intrinsic microporosity comprising (10) or more subunits, wherein one or more of the subunits comprise one or more tetrazolyl moieties. In one embodiment, a polymer of intrinsic microporosity (PIM-1) was modified using a “click chemistry” [2+3] cycloaddition reaction with sodium azide and zinc chloride to yield new PIMs containing tetrazole units. Polymers of the present invention are useful as high-performance materials for membrane-based gas separation, materials for ion exchange resins, materials for chelating resins, materials for superabsorbents, materials for ion conductive matrixes, materials for catalyst supports or materials for nanoparticle stabilizers.
摘要翻译： 本发明提供了含有（10）或更多个亚基的本征微孔的含四唑的聚合物，其中一个或多个亚基包含一个或多个四唑基部分。 在一个实施方案中，使用与叠氮化钠和氯化锌的点击化学[2 + 3]环加成反应来修饰本征微孔性聚合物（PIM-1），以产生含有四唑单元的新PIM。 本发明的聚合物可用作用于膜基气体分离的高性能材料，用于离子交换树脂的材料，用于螯合树脂的材料，用于超吸收剂的材料，用于离子传导性基质的材料，用于催化剂载体的材料或用于纳米颗粒稳定剂的材料。
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