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    Synthesis of poly(arylene)s copolymers containing pendant sulfonic acid groups bonded to naphthalene as proton exchange membrane materials
    2.
    发明授权
    Synthesis of poly(arylene)s copolymers containing pendant sulfonic acid groups bonded to naphthalene as proton exchange membrane materials 失效
    含有与萘结合的侧链磺酸基团作为质子交换膜材料的聚（亚芳基）共聚物的合成

    公开(公告)号：US07579427B2

    公开(公告)日：2009-08-25

    申请号：US11168379

    申请日：2005-06-29

    申请人： Yan Gao ,  Michael D. Guiver ,  Gilles P. Robertson

    发明人： Yan Gao ,  Michael D. Guiver ,  Gilles P. Robertson

    IPC分类号： C08G14/04 ,  C08G61/02

    CPC分类号： C08G65/4012 ,  C08G65/4056 ,  C08G65/48

    摘要： A new series of wholly aromatic poly(arylene ether ether ketone ketone)s containing pendant sulfonic acid groups (SPAEEKK) were conveniently prepared by potassium carbonate mediated nucleophilic polycondensation reactions of inexpensive commercially available monomers: 1,3-bis(4-fluorobenzoyl)benzene (BFBB), sodium 6,7-dihydroxy-2-naphthalenesulfonate (DHNS), and 4,4′-biphenol or hydroquinone in N-methyl-2-pyrrolidone (NMP) at 170° C. FT-IR and NMR were used to characterize the structures and the sulfonate or sulfonic acid contents (SC) of the polymers. Flexible membrane films were obtained by casting N,N-dimethylacetamide (DMAc) solutions of copolymers. Membrane films in acid form were then obtained by treating the sodium form membrane films in 2 N sulfuric acid at room temperature. Glass transition temperatures (Tgs) and decomposition temperatures (Tds) of SPAEEKKs in both sodium and acid forms were determined. Water uptake and swelling ratio values increased with SCs and temperatures. The proton conductivities of acid form membrane films increased with SC value and temperature and reached 5.6×10−2S/cm at 100° C. for SPAEEKK-100.

    摘要翻译： 通过碳酸钾介导的亲脂性缩聚反应方便地制备了一系列含有侧基磺酸基团（SPAEEKK）的全芳香族聚（亚芳基醚醚酮酮），它们是廉价的市售单体：1,3-双（4-氟苯甲酰基）苯 （BFBB），6,7-二羟基-2-萘磺酸钠（DHNS）和4,4'-联苯酚或氢醌在N-甲基-2-吡咯烷酮（NMP）中的溶液中，使用FT-IR和NMR 以表征聚合物的结构和磺酸盐或磺酸含量（SC）。 通过浇铸N，N-二甲基乙酰胺（DMAc）共聚物溶液获得柔性膜膜。 然后通过在室温下在2N硫酸中处理钠形式的膜膜，得到酸形式的膜膜。 测定了钠和酸形式的SPAEEKK的玻璃化转变温度（Tgs）和分解温度（Tds）。 吸水率和溶胀率值随SCs和温度升高。 酸性膜膜的质子电导率随着SC值和温度的升高而升高，在100℃时达到5.6x10-2S / cm，对于SPAEEKK-100。

    LADDER POLYMERS WITH INSTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF
    4.
    发明申请
    LADDER POLYMERS WITH INSTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF 有权
    具有内在微结构的梯形聚合物及其生产方法

    公开(公告)号：US20110190409A1

    公开(公告)日：2011-08-04

    申请号：US13063816

    申请日：2009-10-16

    申请人： Naiying Du ,  Michael D. Guiver ,  Gilles P. Robertson

    发明人： Naiying Du ,  Michael D. Guiver ,  Gilles P. Robertson

    IPC分类号： C08G65/40 ,  C08G75/23 ,  C08J9/00 ,  C07D339/08

    CPC分类号： C08J9/00 ,  B01D53/02 ,  B01D53/228 ,  B01D71/76 ,  B01D2253/202 ,  B01D2256/12 ,  B01D2256/22 ,  B01D2257/102 ,  B01J20/26 ,  B01J20/262 ,  B01J20/28033 ,  B01J20/2808 ,  C07D339/08 ,  C08G65/40 ,  C08G65/4006 ,  C08G75/23 ,  C08L2205/05

    摘要： A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.

    摘要翻译： 式（I）的聚合物：其中：n为10至5000的整数; m为10〜5000的整数; Ar1和Ar3相同或不同，是衍生自四羟基芳族单体的残基，四羟基芳族单体是其中R相同或不同，为H或C 1 -C 8烷基，C 2 -C 8烯基或C 3 -C8环烷基 并且Ar 2和Ar 4相同或不同，并且是衍生自四卤代芳族单体的残基，其中X是F，Cl或Br的四卤代芳族单体，R 1和R 2相同或不同，其中 y为1〜8的整数; 条件是当Ar 1与Ar 3相同且Ar 2与Ar 4相同时，R 1和R 2不能同时为-CN可用作气体分离，气相分离，吸附剂或催化剂的材料。

    Proton exchange membrane materials based on sulfonated poly (phthalazinones)
    5.
    发明授权
    Proton exchange membrane materials based on sulfonated poly (phthalazinones) 有权
    基于磺化聚（2,3-二氮杂萘酮）的质子交换膜材料

    公开(公告)号：US07678863B2

    公开(公告)日：2010-03-16

    申请号：US10529020

    申请日：2003-09-25

    申请人： Yan Gao ,  Michael D. Gulver ,  Gilles P. Robertson ,  Xigao Jian

    发明人： Yan Gao ,  Michael D. Gulver ,  Gilles P. Robertson ,  Xigao Jian

    IPC分类号： C08G73/06 ,  C08J5/20 ,  C08J5/22 ,  B01J39/18 ,  H01M8/10

    CPC分类号： C08J5/2256 ,  C08G65/4037 ,  C08G65/48 ,  C08G73/0694 ,  C08J2379/04 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M2300/0082

    摘要： A novel class of proton exchange membrane materials, sulfonated poly(phthalazinones), were prepared by modification of poly(phthalazinone). Sulfonation reactions were conducted at room temperature using mixtures of 95-98% concentrated sulfuric acid and 27-33% fuming sulfuric acid with different acid ratios in order to get SPPEK with degree of sulfonation (DS) in the range of 0.6 to 1.0. The presence of sulfonic acid groups was confirmed by FT-IR analysis, and the DS and structures were characterized by NMR. The introduction of sulfonic groups into the polymer chains led to an increase in the glass transition temperature and a decrease in the decomposition temperature. Membrane films were cast from solution in N,N-dimethylformamide or N,N-dimethylacetamide. Water uptakes and swelling ratios of the membrane films increased with DS and sulfonated polymers with DS>1.2 were water soluble at 80° C. Proton conductivity increased with DS and temperature up to 95° C., reaching 10−2 S/Cm.

    摘要翻译： 通过改性聚（酞嗪酮）制备了一类新颖的质子交换膜材料，磺化聚（2,3-二氮杂萘酮）。 使用95-98％浓硫酸和27-33％发烟硫酸的混合物在室温下进行磺化反应，以使得具有0.6-1.0的磺化度（DS）的SPPEK。 通过FT-IR分析证实磺酸基团的存在，并通过NMR表征DS和结构。 在聚合物链中引入磺基导致玻璃化转变温度的升高和分解温度的降低。 从N，N-二甲基甲酰胺或N，N-二甲基乙酰胺中的溶液中浇铸膜膜。 DS的吸水率和溶胀比随DS增加，DS> 1.2的磺化聚合物在80℃水溶性，质子传导率随DS升高，达到95℃，达到10-2 S / Cm。

    LADDER POLYMERS WITH INTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF
    7.
    发明申请
    LADDER POLYMERS WITH INTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF 有权
    具有内在微结构的梯形聚合物及其生产方法

    公开(公告)号：US20140243441A1

    公开(公告)日：2014-08-28

    申请号：US14206065

    申请日：2014-03-12

    申请人： Naiying DU ,  Michael D. GUIVER ,  Gilles P. ROBERTSON

    发明人： Naiying DU ,  Michael D. GUIVER ,  Gilles P. ROBERTSON

    IPC分类号： C08G65/40 ,  C08J9/00 ,  B01D53/22

    CPC分类号： C08J9/00 ,  B01D53/02 ,  B01D53/228 ,  B01D71/76 ,  B01D2253/202 ,  B01D2256/12 ,  B01D2256/22 ,  B01D2257/102 ,  B01J20/26 ,  B01J20/262 ,  B01J20/28033 ,  B01J20/2808 ,  C07D339/08 ,  C08G65/40 ,  C08G65/4006 ,  C08G75/23 ,  C08L2205/05

    摘要： A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.

    摘要翻译： 式（I）的聚合物：其中：n为10至5000的整数; m为10〜5000的整数; Ar1和Ar3相同或不同，是衍生自四羟基芳族单体的残基，四羟基芳族单体是其中R相同或不同，为H或C1-C8烷基，C2-C8链烯基或C3 -C8环烷基 并且Ar 2和Ar 4相同或不同，并且是衍生自四卤代芳族单体的残基，其中X是F，Cl或Br的四卤代芳族单体，R 1和R 2相同或不同，其中 y为1〜8的整数， 条件是当Ar 1与Ar 3相同且Ar 2与Ar 4相同时，R 1和R 2不能同时为-CN可用作气体分离，气相分离，吸附剂或催化剂的材料。

    Process for producing azide-substituted aromatic polymers and the products thereof
    9.
    发明授权
    Process for producing azide-substituted aromatic polymers and the products thereof 失效
    叠氮取代芳族聚合物的制备方法及其制备方法

    公开(公告)号：US5475065A

    公开(公告)日：1995-12-12

    申请号：US292959

    申请日：1994-08-22

    申请人： Michael D. Guiver ,  Gilles P. Robertson

    发明人： Michael D. Guiver ,  Gilles P. Robertson

    IPC分类号： C08G75/23 ,  C08L81/06

    CPC分类号： C08G75/23

    摘要： The invention disclosed relates to a process for producing azide-substituted aromatic polymers such as polysulfones, and to certain novel azide-substituted polysulfones so produced. The process involves attaching azide groups onto the aromatic rings of the polymers by first activating the attachment site by direct lithiation or bromination, followed by lithiation. The lithiated intermediates are converted substantially qantitatively to azides by reacting with a suitable azide, preferably tosyl azide, under substantially anhydrous conditions. Novel azide-substituted polysulfones containing from one to about three azide groups per repeat polymer unit were obtained, the degree of azide substitution being determined by the degree of lithiation. The azides may also be converted to other functional derivatives such as primary amines and cross-linked membranes.

    摘要翻译： 所公开的本发明涉及一种制备叠氮化物取代的芳族聚合物如聚砜的方法，以及如此制备的某些新型叠氮取代的聚砜。 该方法包括通过首先通过直接锂化或溴化来活化附着位点，然后进行锂化，将叠氮基团连接到聚合物的芳环上。 在基本无水的条件下，锂化中间体通过与合适的叠氮化物（优选甲苯磺酰基叠氮化物）反应而基本上经过空位转化为叠氮化物。 得到每重复聚合物单元含有1至约3个叠氮基的新型叠氮取代聚砜，叠氮化度取决于锂化度。 叠氮化物也可以转化为其他官能衍生物，例如伯胺和交联膜。

    Carboxylated Polymers of Intrinsic Microporosity (PIMs) with Tunable Gas Transport Properties
    10.
    发明申请
    Carboxylated Polymers of Intrinsic Microporosity (PIMs) with Tunable Gas Transport Properties 有权
    具有可调气体运输特性的固有微孔（PIM）的羧基化聚合物

    公开(公告)号：US20120041084A1

    公开(公告)日：2012-02-16

    申请号：US13266304

    申请日：2010-03-10

    申请人： Naiying Du ,  Michael D. Guiver ,  Gilles P. Robertson ,  Jingshe Song

    发明人： Naiying Du ,  Michael D. Guiver ,  Gilles P. Robertson ,  Jingshe Song

    IPC分类号： C08J5/22 ,  B29C39/14 ,  C08G63/44

    CPC分类号： C08G65/48 ,  C08J5/18 ,  C08J2371/02 ,  C08L71/02

    摘要： A film of a carboxylated polymer of formula (I): wherein the sum of x, y and z is an integer from 10 to 10,000 and degree of hydrolysis is 0.05 or greater provides gas separation materials in which the degree of hydrolysis may be used to tune the selectivity of the gases to an optimal required range. Such films may be prepared by casting a film of a polymer of formula (II): wherein n is an integer from 10 to 10,000, and hydrolyzing all or a portion of the —CN groups to form —COOH groups.

    摘要翻译： 式（I）的羧化聚合物的膜：其中x，y和z的总和为10至10,000的整数，水解度为0.05或更大提供可以使用水解度的气体分离材料 将气体的选择性调整到最佳所需范围。 这样的膜可以通过浇铸式（II）的聚合物的膜来制备：其中n是10至10,000的整数，并且将全部或部分-CN基团水解形成-COOH基团。