Method for preparing manganese-based nitride having nearly zero temperature coefficient of resistivity
    1.
    发明授权
    Method for preparing manganese-based nitride having nearly zero temperature coefficient of resistivity 失效
    具有接近零电阻温度系数的锰基氮化物的方法

    公开(公告)号:US06767525B2

    公开(公告)日:2004-07-27

    申请号:US09873240

    申请日:2001-06-05

    IPC分类号: C01B2106

    摘要: The present invention relates to a method for preparing manganese-based nitride having nearly zero temperature coefficient of resistivity and more particularly, to the effective method for preparing manganese-based nitride expressed by the formula (1), wherein the manganese-based nitride, prepared by heating the stoichiometric mixture of Mn2N and Cu in an evacuated quartz tube, provides some advantages in that i) the use of the Mn2N compound as a reactant, the formation of impurities and nitrogen evaporation may be prevented, and ii) through nitrogen is tightly bonded between metals, the manganese-based nitride has extremely low (46 ppm/K) temperature coefficient of resistivity. CuNMn3  (1)

    摘要翻译: 本发明涉及一种制备具有接近零电阻温度系数的锰基氮化物的方法,更具体地说,涉及制备由式(1)表示的锰基氮化物的有效方法,其中制备的锰基氮化物 通过加热真空石英管中的Mn2N和Cu的化学计量混合物,提供了一些优点,即i)使用Mn2N化合物作为反应物,可以防止形成杂质和氮气蒸发,以及ii)通过氮气紧密 在金属之间键合,锰基氮化物具有极低(46ppm / K)的电阻率温度系数。

    Sodium-intervened superconductor and its manufacturing method
    2.
    发明授权
    Sodium-intervened superconductor and its manufacturing method 失效
    钠介导超导体及其制造方法

    公开(公告)号:US6010982A

    公开(公告)日:2000-01-04

    申请号:US222710

    申请日:1998-12-29

    摘要: The present invention relates to a sodium-intervened superconductor and its manufacturing method and more particularly, to the sodium-intervened superconductor expressed by the following Formula 1 and its manufacturing method, wherein the superconductor, prepared from a stoichiometric mixture of Y.sub.2 O.sub.3, NaCuO.sub.2, BaCuO.sub.2, Ln.sub.2 O.sub.3 (Ln: lanthanide ion) and CuO under the atmosphere of oxygen, has some advantages in that a) through the use of NaCuO.sub.2, a ternary oxide, as a reactant, the formation of impurities and sodium evaporation may be prevent, and b) through partial substitution of a divalent barium by a trivalent lanthanide group ion, the superconductor is stable in air with a higher critical current density and critical temperature.Formula 1(Na.sub.1-x Y.sub.x)(Ba.sub.1-y Ln.sub.y).sub.2 Cu.sub.3 O.sub.6+.delta.wherein, Ln is a trivalent lanthanide ion other than Ce and Pr; 0.1

    摘要翻译: 本发明涉及钠介导超导体及其制造方法,更具体地说,涉及由下式1及其制造方法表示的钠介导超导体,其中由Y 2 O 3,NaCuO 2,BaCuO 2的化学计量混合物制备的超导体 ,在氧气氛下的Ln2O3(Ln:镧系元素离子)和CuO具有一些优点:a)通过使用三元氧化物NaCuO 2作为反应物,可以防止杂质的形成和钠蒸发,b )通过三价镧系元素离子部分取代二价钡,超导体在空气中稳定,具有较高的临界电流密度和临界温度。 式(Na1-xYx)(Ba1-yLny)2Cu3O6 +δ其中,Ln是Ce和Pr以外的三价镧系元素离子; 0.1