公开(公告)号：US20100029836A1

公开(公告)日：2010-02-04

申请号：US12519169

申请日：2007-12-13

申请人： Takayuki Hirose ,  Naosuke Komoto ,  Kensho Okayama ,  Koji Masumoto ,  Naoko Nagaoka

发明人： Takayuki Hirose ,  Naosuke Komoto ,  Kensho Okayama ,  Koji Masumoto ,  Naoko Nagaoka

IPC分类号： C08L33/10

CPC分类号： C08J3/07 ,  C08J2323/02 ,  C08J2333/08 ,  C08J2333/10 ,  C08L23/02 ,  C08L23/025 ,  C08L33/08 ,  C08L33/10 ,  C08L51/06 ,  C08L2314/02 ,  C08L2666/06 ,  C09D133/08 ,  C09D133/10 ,  C09J133/08 ,  C09J133/10

摘要： It is an object of the present invention to provide a polyolefin resin dispersion composition in which the dispersed resin is stable to water or a hydrophilic substance, and which has an adhesive property to nonpolar substrates, in particular poorly adhesive polyolefin-based substrates whose surface has not been treated, is excellent in a coating property, exhibits an excellent adhesive property through drying and press bonding with heat at a temperature in a wide range regardless of whether the temperature is low or high, is excellent in water resistance and gasohol resistance and is less tacky. That is, the present invention provides the dispersed resin composition containing (a) a polyolefin resin, (b) a (meth)acrylic acid homopolymer or copolymer having a side chain comprising an esterified alkyl group, (c) a basic substance and (d) water or a hydrophilic substance, and a process for producing the same.

摘要翻译： 本发明的目的是提供一种聚烯烃树脂分散体组合物，其中分散的树脂对水或亲水物质是稳定的，并且对非极性基材具有粘合性，特别是表面具有粘合性的聚烯烃类基材 未经处理，涂布性优异，无论温度低还是高，在宽范围的温度下通过干燥和加热粘合而具有优异的粘合性，耐水性和耐汽油醇性优异，为 少发粘 也就是说，本发明提供了包含（a）聚烯烃树脂的分散树脂组合物，（b）具有侧链的（甲基）丙烯酸均聚物或共聚物，其包含酯化的烷基，（c）碱性物质和（d ）水或亲水性物质，及其制造方法。

公开(公告)号：US07208552B2

公开(公告)日：2007-04-24

申请号：US10500111

申请日：2002-12-20

申请人： Naosuke Komoto ,  Hidetoshi Yoshioka

发明人： Naosuke Komoto ,  Hidetoshi Yoshioka

IPC分类号： C08F8/20

CPC分类号： C08F8/22 ,  C08F8/50 ,  C08F255/02 ,  C08F255/023 ,  C08L51/06 ,  C08F10/06 ,  C08F220/08

摘要： The invention provides a novel binder resin composition with good adherence onto prime materials of polyolefin, poly (vinyl chloride), polycarbonate, PET, ABS and nylon, and also with excellent solvent solubility.A binder resin composition characterized by being chlorinated propylenic random copolymer with weight average molecular weight of 3000 to 250000, wherein propylenic random copolymer with melting point (Tm) measured by differential scanning calorimeter (DSC) of 115 to 165° C. obtained by copolymerizing propylene with other α-olefin in the coexistence of metallocene type catalyst is chlorinated to chlorine content of 10 to 40% by weight, after thermal degradation or directly without thermal degradation, and/or a binder resin composition characterized by containing carboxyl group-containing chlorinated propylenic random copolymer with weight average molecular weight of 30000 to 220000, wherein propylenic random copolymer with melting point (Tm) measured by differential scanning calorimeter (DSC) of 115 to 165° C. obtained by copolymerizing propylene with other α-olefin in the coexistence of metallocene type catalyst is grafted with α,β-unsaturated carboxylic acid or its anhydride in amounts of 0.1 to 20% by weight, after thermal degradation or directly without thermal degradation, and then chlorinated to chlorine content of 10 to 40% by weight, stabilizer and organic solvent.

摘要翻译： 本发明提供了对聚烯烃，聚（氯乙烯），聚碳酸酯，PET，ABS和尼龙的主要材料具有良好粘附性的新型粘合剂树脂组合物，并且还具有优异的溶剂溶解性。 一种粘合剂树脂组合物，其特征在于重均分子量为3000〜250000的氯化丙烯酸无规共聚物，其中通过差示扫描量热计（DSC）测定的熔点（Tm）为115〜165℃的丙烯无规共聚物，其通过使丙烯 与茂金属型催化剂共存的其它α-烯烃氯化成氯含量为10〜40重量％，热降解后或直接不进行热降解，和/或以含羧基的氯化丙烯酸为特征的粘合剂树脂组合物 重均分子量为30000至220000的无规共聚物，其中通过差示扫描量热计（DSC）测量的熔点（Tm）为115至165℃的丙烯无规共聚物通过共聚丙烯与其它α-烯烃共聚获得 茂金属型催化剂用α，β-不饱和羧酸或其a 二氢化钠的量为0.1〜20重量％，经热降解后直接进行无热降解，氯化至氯含量为10〜40重量％的稳定剂和有机溶剂。

公开(公告)号：US08519046B2

公开(公告)日：2013-08-27

申请号：US12519169

申请日：2007-12-13

申请人： Takayuki Hirose ,  Naosuke Komoto ,  Kensho Okayama ,  Koji Masumoto ,  Naoko Nagaoka

发明人： Takayuki Hirose ,  Naosuke Komoto ,  Kensho Okayama ,  Koji Masumoto ,  Naoko Nagaoka

IPC分类号： C08K5/00 ,  B05D7/00 ,  C08J3/00 ,  C08L33/00 ,  C04B24/26

CPC分类号： C08J3/07 ,  C08J2323/02 ,  C08J2333/08 ,  C08J2333/10 ,  C08L23/02 ,  C08L23/025 ,  C08L33/08 ,  C08L33/10 ,  C08L51/06 ,  C08L2314/02 ,  C08L2666/06 ,  C09D133/08 ,  C09D133/10 ,  C09J133/08 ,  C09J133/10

摘要： It is an object of the present invention to provide a polyolefin resin dispersion composition in which the dispersed resin is stable to water or a hydrophilic substance, and which has an adhesive property to nonpolar substrates, in particular poorly adhesive polyolefin-based substrates whose surface has not been treated, is excellent in a coating property, exhibits an excellent adhesive property through drying and press bonding with heat at a temperature in a wide range regardless of whether the temperature is low or high, is excellent in water resistance and gasohol resistance and is less tacky. That is, the present invention provides the dispersed resin composition containing (a) a polyolefin resin, (b) a (meth)acrylic acid homopolymer or copolymer having a side chain comprising an esterified alkyl group, (c) a basic substance and (d) water or a hydrophilic substance, and a process for producing the same.

摘要翻译： 本发明的目的是提供一种聚烯烃树脂分散体组合物，其中分散的树脂对水或亲水物质是稳定的，并且对非极性基材具有粘合性，特别是表面具有粘合性的聚烯烃类基材 未经处理，涂布性优异，无论温度低还是高，在宽范围的温度下通过干燥和加热粘合而具有优异的粘合性，耐水性和耐汽油醇性优异，为 少发粘 也就是说，本发明提供了包含（a）聚烯烃树脂的分散树脂组合物，（b）具有侧链的（甲基）丙烯酸均聚物或共聚物，其包含酯化的烷基，（c）碱性物质和（d ）水或亲水性物质，及其制造方法。

公开(公告)号：US20070224435A1

公开(公告)日：2007-09-27

申请号：US11597916

申请日：2005-05-31

申请人： Eiji Nishijima ,  Koji Masumoto ,  Takayuki Hirose ,  Naosuke Komoto ,  Hironori Muramoto ,  Kensho Okayama

发明人： Eiji Nishijima ,  Koji Masumoto ,  Takayuki Hirose ,  Naosuke Komoto ,  Hironori Muramoto ,  Kensho Okayama

IPC分类号： C08F8/20 ,  C08F8/46 ,  C08L23/28 ,  C09D11/00 ,  C09D123/28

CPC分类号： C08F8/20 ,  C08F255/023 ,  C08L23/10 ,  C08L51/06 ,  C09D11/102 ,  C09D11/106 ,  C09D123/28 ,  C09D151/06 ,  C09J123/28 ,  C09J151/06 ,  Y10T428/3154 ,  Y10T428/31855 ,  C08F220/06

摘要： A novel binder resin which attains good adhesion to various substrates such as polyolefin resins, vinyl chloride resins, polycarbonate resins, polyethylene terephthalate resins, acrylonitrile/butadiene/styrene resins, and nylon resins even by low-temperature baking and has excellent solubility in solvent. Namely, a chlorinated propylene random copolymer produced by subjecting a propylene random copolymer which is obtained by copolymerizing propylene with other alpha-olefins by using a metallocene catalyst as the polymerization catalyst and which has a melting point (Tm) of less than 115° C. as determined with a differential scanning calorimeter (DSC) to thermally kneaded preferably at a temperature ranging from the melting point of the copolymer to 350° C. and chlorination successively.

摘要翻译： 即使通过低温烘烤也能够对各种基材例如聚烯烃树脂，氯乙烯树脂，聚碳酸酯树脂，聚对苯二甲酸乙二醇酯树脂，丙烯腈/丁二烯/苯乙烯树脂和尼龙树脂具有良好的粘附性并且在溶剂中具有优异的溶解性的新型粘结剂树脂。 即，通过使用茂金属催化剂作为聚合催化剂并且熔点（Tm）小于115℃的丙烯与其它α-烯烃共聚得到的丙烯无规共聚物制备的氯化丙烯无规共聚物。 如用差示扫描量热计（DSC）测定的，优选在从共聚物的熔点至350℃的温度下进行热捏合，并依次进行氯化。

公开(公告)号：US20110112229A1

公开(公告)日：2011-05-12

申请号：US13002077

申请日：2009-08-14

申请人： Naoko Nagaoka ,  Kenshou Okayama ,  Masanori Tanaka ,  Naosuke Komoto

发明人： Naoko Nagaoka ,  Kenshou Okayama ,  Masanori Tanaka ,  Naosuke Komoto

IPC分类号： C09D123/00 ,  C08K5/17

CPC分类号： C09D5/027 ,  C08L2666/06 ,  C08L2666/14 ,  C09D5/002 ,  C09D11/14 ,  C09J123/0869 ,  C09J123/26 ,  C09J151/06

摘要： It is an object of the present invention to provide: a dispersion resin composition for use in a paint, an ink, an adhesive, or a primer that each contains an alcohol or an ether, and which exhibits excellent water dispersibility and can maintain excellent dispersion stability, even when the dispersion resin composition is added to a material containing an organic solvent such as an alcohol or an ether, or even when an organic solvent is added to the dispersion resin composition; and a composition of a paint, an ink, an adhesive or a primer that each contains the dispersion resin composition.In other words, the present invention provides a dispersion resin composition for use in a paint, an ink, an adhesive, or a primer that each contains an alcohol and/or an ether comprising: (a) a polyolefin-based resin containing a polymer mainly composed of olefin monomer units, (b) a nitrogen-containing polyoxyalkylene derivative, (c) a basic substance and (d) water, and also provides a composition of a paint, an ink, an adhesive or a primer, each of which contains the dispersion resin composition.

摘要翻译： 本发明的目的是提供：用于涂料，油墨，粘合剂或底漆中的各自含有醇或醚的分散树脂组合物，其表现出优异的水分散性并且可以保持优异的分散性 即使将分散树脂组合物添加到含有醇或醚等有机溶剂的材料中，或者即使在分散树脂组合物中添加有机溶剂的情况下也能够稳定地进行。 以及各自含有分散树脂组合物的油漆，油墨，粘合剂或底漆的组合物。 换句话说，本发明提供一种用于油漆，油墨，粘合剂或底漆中的各自含有醇和/或醚的分散树脂组合物，其包含：（a）含有聚合物的聚烯烃基树脂 主要由烯烃单体单元组成，（b）含氮聚氧化烯衍生物，（c）碱性物质和（d）水），并且还提供涂料，油墨，粘合剂或底漆的组合物， 含有分散树脂组合物。

公开(公告)号：US07635520B2

公开(公告)日：2009-12-22

申请号：US11597916

申请日：2005-05-31

申请人： Eiji Nishijima ,  Koji Masumoto ,  Takayuki Hirose ,  Naosuke Komoto ,  Hironori Muramoto ,  Kensho Okayama

发明人： Eiji Nishijima ,  Koji Masumoto ,  Takayuki Hirose ,  Naosuke Komoto ,  Hironori Muramoto ,  Kensho Okayama

IPC分类号： B32B27/00 ,  C08L23/00 ,  C08L23/04 ,  C08F259/02 ,  C08F265/02 ,  C08F267/02

CPC分类号： C08F8/20 ,  C08F255/023 ,  C08L23/10 ,  C08L51/06 ,  C09D11/102 ,  C09D11/106 ,  C09D123/28 ,  C09D151/06 ,  C09J123/28 ,  C09J151/06 ,  Y10T428/3154 ,  Y10T428/31855 ,  C08F220/06

摘要： A novel binder resin which attains good adhesion to various substrates such as polyolefin resins, vinyl chloride resins, polycarbonate resins, polyethylene terephthalate resins, acrylonitrile/butadiene/styrene resins, and nylon resins even by low-temperature baking and has excellent solubility in solvent. Namely, a chlorinated propylene random copolymer produced by subjecting a propylene random copolymer which is obtained by copolymerizing propylene with other alpha-olefins by using a metallocene catalyst as the polymerization catalyst and which has a melting point (Tm) of less than 115° C. as determined with a differential scanning calorimeter (DSC) to thermally kneaded preferably at a temperature ranging from the melting point of the copolymer to 350° C. and chlorination successively.

摘要翻译： 即使通过低温烘烤也能够对各种基材例如聚烯烃树脂，氯乙烯树脂，聚碳酸酯树脂，聚对苯二甲酸乙二醇酯树脂，丙烯腈/丁二烯/苯乙烯树脂和尼龙树脂具有良好的粘附性并且在溶剂中具有优异的溶解性的新型粘结剂树脂。 即，通过使用茂金属催化剂作为聚合催化剂并且熔点（Tm）小于115℃的丙烯与其它α-烯烃共聚得到的丙烯无规共聚物制备的氯化丙烯无规共聚物。 如用差示扫描量热计（DSC）测定的，优选在从共聚物的熔点至350℃的温度下进行热捏合，并依次进行氯化。

公开(公告)号：US20060025533A1

公开(公告)日：2006-02-02

申请号：US10500111

申请日：2002-12-20

申请人： Naosuke Komoto ,  Hidetoshi Yoshioka

发明人： Naosuke Komoto ,  Hidetoshi Yoshioka

IPC分类号： C08F251/00 ,  C08F10/00

CPC分类号： C08F8/22 ,  C08F8/50 ,  C08F255/02 ,  C08F255/023 ,  C08L51/06 ,  C08F10/06 ,  C08F220/08

摘要： The invention provides a novel binder resin composition with good adherence onto prime materials of polyolefin, poly (vinyl chloride), polycarbonate, PET, ABS and nylon, and also with excellent solvent solubility. A binder resin composition characterized by being chlorinated propylenic random copolymer with weight average molecular weight of 3000 to 250000, wherein propylenic random copolymer with melting point (Tm) measured by differential scanning calorimeter (DSC) of 115 to 165° C. obtained by copolymerizing propylene with other α-olefin in the coexistence of metallocene type catalyst is chlorinated to chlorine content of 10 to 40% by weight, after thermal degradation or directly without thermal degradation, and/or a binder resin composition characterized by containing carboxyl group-containing chlorinated propylenic random copolymer with weight average molecular weight of 30000 to 220000, wherein propylenic random copolymer with melting point (Tm) measured by differential scanning calorimeter (DSC) of 115 to 165° C. obtained by copolymerizing propylene with other α-olefin in the coexistence of metallocene type catalyst is grafted with α,β-unsaturated carboxylic acid or its anhydride in amounts of 0.1 to 20% by weight, after thermal degradation or directly without thermal degradation, and then chlorinated to chlorine content of 10 to 40% by weight, stabilizer and organic solvent.

摘要翻译： 本发明提供了对聚烯烃，聚（氯乙烯），聚碳酸酯，PET，ABS和尼龙的主要材料具有良好粘附性的新型粘合剂树脂组合物，并且还具有优异的溶剂溶解性。 一种粘合剂树脂组合物，其特征在于重均分子量为3000〜250000的氯化丙烯酸无规共聚物，其中通过差示扫描量热计（DSC）测定的熔点（Tm）为115〜165℃的丙烯无规共聚物，其通过使丙烯 与茂金属型催化剂共存的其它α-烯烃氯化成氯含量为10〜40重量％，热降解后或直接不进行热降解，和/或以含羧基的氯化丙烯酸为特征的粘合剂树脂组合物 重均分子量为30000至220000的无规共聚物，其中通过差示扫描量热计（DSC）测量的熔点（Tm）为115至165℃的丙烯无规共聚物通过共聚丙烯与其它α-烯烃共聚获得 茂金属型催化剂用α，β-不饱和羧酸或其a 二氢化钠的量为0.1〜20重量％，经热降解后直接进行无热降解，氯化至氯含量为10〜40重量％的稳定剂和有机溶剂。

公开(公告)号：US06670414B2

公开(公告)日：2003-12-30

申请号：US09968031

申请日：2001-10-02

申请人： Kazunori Shiraishi ,  Naosuke Komoto ,  Takaaki Ueda ,  Keiji Urata

发明人： Kazunori Shiraishi ,  Naosuke Komoto ,  Takaaki Ueda ,  Keiji Urata

IPC分类号： C08K308

CPC分类号： C08L23/0853 ,  C08L23/0846 ,  C08L51/06 ,  Y10T428/256 ,  Y10T428/31576 ,  Y10T428/31913 ,  C08L2666/24 ,  C08L2666/04

摘要： A binder resin containing a mixture of carboxyl group containing chlorinated polyolefins and an ethylene-vinyl acetate copolymer. The binder resin is incorporated in primer formulations for application on substrates including polyolefinic materials.