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    Process for production of a metal hydride
    1.
    发明授权
    Process for production of a metal hydride 有权
    金属氢化物的制备方法

    公开(公告)号：US08802051B2

    公开(公告)日：2014-08-12

    申请号：US13053350

    申请日：2011-03-22

    申请人： Nathan Tait Allen ,  Robert Butterick, III ,  Arthur Achhing Chin ,  Dean Michael Millar ,  David Craig Molzahn

    发明人： Nathan Tait Allen ,  Robert Butterick, III ,  Arthur Achhing Chin ,  Dean Michael Millar ,  David Craig Molzahn

    IPC分类号： C01B6/04

    CPC分类号： C01B6/04

    摘要： A process for production of a metal hydride compound MHx, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R1O)xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MHx. R1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R1O)xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

    摘要翻译： 一种制备金属氢化物化合物MHx的方法，其中x为一个或两个，M为碱金属Be或Mg。 该方法包括将式（R1O）xM化合物与铝，氢和至少一种选自钛，锆，铪，铌，钒，钽和铁的金属组合以制备式MHx的化合物。 R 1是被至少一个烷基或烷氧基取代的苯基或苯基。 铝与（R1O）xM的摩尔比为0.1:1至1:1。 以铝的重量计，催化剂的含量至少为200ppm。

    PROCESS FOR PRODUCTION OF A BOROHYDRIDE COMPOUND
    4.
    发明申请
    PROCESS FOR PRODUCTION OF A BOROHYDRIDE COMPOUND 有权
    生产硼氢化合物的方法

    公开(公告)号：US20110236286A1

    公开(公告)日：2011-09-29

    申请号：US13053355

    申请日：2011-03-22

    申请人： Nathan Tait Allen ,  Robert Butterick, III ,  Arthur Achhing Chin ,  Dean Michael Millar ,  David Craig Molzahn

    发明人： Nathan Tait Allen ,  Robert Butterick, III ,  Arthur Achhing Chin ,  Dean Michael Millar ,  David Craig Molzahn

    IPC分类号： C01B6/04

    CPC分类号： C01B6/21

    摘要： A process for production of a borohydride compound M(BH4)y. The process has three steps. The first step combines a compound of formula (R1O)yM with aluminum, hydrogen and a metallic catalyst containing at least one metal selected from the group consisting of titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula M(AlH3OR1)y, wherein R1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group; M is an alkali metal, Be or Mg; and y is one or two; wherein the catalyst is present at a level of at least 200 ppm based on weight of aluminum. The second step combines the compound of formula M(AlH3OR1)y with a borate, boroxine or borazine compound to produce M(BH4)y and a byproduct mixture containing alkali metal and aluminum aryloxides. The third step separates M(BH4)y from the byproduct mixture.

    摘要翻译： 制备硼氢化合物M（BH4）y的方法。 该过程有三个步骤。 第一步是将式（R1O）yM的化合物与铝，氢和含有选自钛，锆，铪，铌，钒，钽和铁中的至少一种金属的金属催化剂组合以制备式 M（AlH 3 OR 1）y，其中R 1是苯基或被至少一个烷基或烷氧基取代的苯基; M是碱金属，Be或Mg; y是一两个; 其中所述催化剂以基于铝的重量的至少200ppm的含量存在。 第二步将式M化合物（AlH 3 OR 1）y与硼酸盐，环硼氧烷或环硼氮烷化合物结合，生成M（BH4）y和含有碱金属和铝酰氧化物的副产物混合物。 第三步骤将M（BH4）y与副产物混合物分离。

    PROCESS FOR PRODUCTION OF A METAL HYDRIDE
    5.
    发明申请
    PROCESS FOR PRODUCTION OF A METAL HYDRIDE 有权
    生产金属氢化物的方法

    公开(公告)号：US20110236300A1

    公开(公告)日：2011-09-29

    申请号：US13053350

    申请日：2011-03-22

    申请人： Nathan Tait Allen ,  Robert Butterick, III ,  Arthur Achhing Chin ,  Dean Michael Millar ,  David Craig Molzahn

    发明人： Nathan Tait Allen ,  Robert Butterick, III ,  Arthur Achhing Chin ,  Dean Michael Millar ,  David Craig Molzahn

    IPC分类号： C01B6/04

    CPC分类号： C01B6/04

    摘要： A process for production of a metal hydride compound MHx, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R1O)xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MHx. R1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R1O)xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

    摘要翻译： 一种制备金属氢化物化合物MHx的方法，其中x为一个或两个，M为碱金属Be或Mg。 该方法包括将式（R1O）xM化合物与铝，氢和至少一种选自钛，锆，铪，铌，钒，钽和铁的金属组合以制备式MHx的化合物。 R 1是被至少一个烷基或烷氧基取代的苯基或苯基。 铝与（R1O）xM的摩尔比为0.1:1至1:1。 以铝的重量计，催化剂的含量至少为200ppm。

    Process for production of a borohydride compound
    6.
    发明授权
    Process for production of a borohydride compound 有权
    硼氢化合物的制备方法

    公开(公告)号：US08808662B2

    公开(公告)日：2014-08-19

    申请号：US13053355

    申请日：2011-03-22

    申请人： Nathan Tait Allen ,  Robert Butterick, III ,  Arthur Achhing Chin ,  Dean Michael Millar ,  David Craig Molzahn

    发明人： Nathan Tait Allen ,  Robert Butterick, III ,  Arthur Achhing Chin ,  Dean Michael Millar ,  David Craig Molzahn

    IPC分类号： C01B6/04 ,  C01B6/21

    CPC分类号： C01B6/21

    摘要： A process for production of a borohydride compound M(BH4)y. The process has three steps. The first step combines a compound of formula (R1O)yM with aluminum, hydrogen and a metallic catalyst containing at least one metal selected from the group consisting of titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula M(AlH3OR1)y, wherein R1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group; M is an alkali metal, Be or Mg; and y is one or two; wherein the catalyst is present at a level of at least 200 ppm based on weight of aluminum. The second step combines the compound of formula M(AlH3OR1)y with a borate, boroxine or borazine compound to produce M(BH4)y and a byproduct mixture containing alkali metal and aluminum aryloxides. The third step separates M(BH4)y from the byproduct mixture.

    摘要翻译： 制备硼氢化合物M（BH4）y的方法。 该过程有三个步骤。 第一步是将式（R1O）yM的化合物与铝，氢和含有选自钛，锆，铪，铌，钒，钽和铁中的至少一种金属的金属催化剂组合以制备式 M（AlH 3 OR 1）y，其中R 1是苯基或被至少一个烷基或烷氧基取代的苯基; M是碱金属，Be或Mg; y是一两个; 其中所述催化剂以基于铝的重量的至少200ppm的含量存在。 第二步将式M化合物（AlH 3 OR 1）y与硼酸盐，环硼氧烷或环硼氮烷化合物结合，生成M（BH4）y和含有碱金属和铝酰氧化物的副产物混合物。 第三步骤将M（BH4）y与副产物混合物分离。

    Ligand Synthesis
    8.
    发明申请
    Ligand Synthesis 有权
    配体合成

    公开(公告)号：US20070287847A1

    公开(公告)日：2007-12-13

    申请号：US11457996

    申请日：2006-07-17

    申请人： Nathan Tait Allen ,  Brian Leslie Goodall ,  Thomas Cleveland Kirk ,  Lester Howard McIntosh

    发明人： Nathan Tait Allen ,  Brian Leslie Goodall ,  Thomas Cleveland Kirk ,  Lester Howard McIntosh

    IPC分类号： C07F9/70

    CPC分类号： C07F9/5022

    摘要： Ligand synthesis methods for the preparation of ligands having the formula wherein Q is selected from phosphorus, arsenic and antimony; wherein X1, X2 and X3 are carbon anions; and, wherein R15 is selected from —SO3, —SO2N(R18), —CO2, —PO3, —AsO3, —SiO2, —C(CF3)2O; where R18 is selected from a hydrogen, a halogen, a hydrocarbyl group and a substituted hydrocarbyl group, are disclosed. Also disclosed are methods of complexing the ligands with late transition metals to form catalyst complexes that catalyze polymerization reactions and/or Heck coupling reactions.

    摘要翻译： 用于制备具有下式的配体的配体合成方法其中Q选自磷，砷和锑; 其中X 1，X 2和X 3是碳阴离子; 和其中R 15选自-SO 3，-SO 2 N（R 18）， - CO 2，-PO 3，-AsO 3，-SiO 2，-C（CF 3）2， 3 O 2; 其中R 18选自氢，卤素，烃基和取代的烃基。 还公开了使配体与后过渡金属络合以形成催化聚合反应和/或Heck偶联反应的催化剂络合物的方法。

    Ligand synthesis
    10.
    发明授权
    Ligand synthesis 有权
    配体合成

    公开(公告)号：US07339075B2

    公开(公告)日：2008-03-04

    申请号：US11457996

    申请日：2006-07-17

    申请人： Nathan Tait Allen ,  Brian Leslie Goodall ,  Thomas Cleveland Kirk ,  Lester Howard McIntosh, III

    发明人： Nathan Tait Allen ,  Brian Leslie Goodall ,  Thomas Cleveland Kirk ,  Lester Howard McIntosh, III

    IPC分类号： C07F5/02

    CPC分类号： C07F9/5022

    摘要： Ligand synthesis methods for the preparation of ligands having the formula wherein Q is selected from phosphorus, arsenic and antimony; wherein X1, X2 and X3 are carbon anions; and, wherein R15 is selected from —SO3, —SO2N(R18), —CO2, —PO3, —AsO3, —SiO2, —C(CF3)2O; where R18 is selected from a hydrogen, a halogen, a hydrocarbyl group and a substituted hydrocarbyl group, are disclosed. Also disclosed are methods of complexing the ligands with late transition metals to form catalyst complexes that catalyze polymerization reactions and/or Heck coupling reactions.

    摘要翻译： 用于制备具有下式的配体的配体合成方法其中Q选自磷，砷和锑; 其中X 1，X 2和X 3是碳阴离子; 和其中R 15选自-SO 3，-SO 2 N（R 18）， - CO 2，-PO 3，-AsO 3，-SiO 2，-C（CF 3）2， 3 O 2; 其中R 18选自氢，卤素，烃基和取代的烃基。 还公开了使配体与后过渡金属络合以形成催化聚合反应和/或Heck偶联反应的催化剂络合物的方法。