公开(公告)号：US5981608A

公开(公告)日：1999-11-09

申请号：US123711

申请日：1998-07-28

Applicant: Jacobus Johannes Cornelis Geerlings ,  Marinus Franciscus Goes ,  Hans Michiel Huisman ,  Jean-Paul Lange ,  Heiko Oosterbeek ,  Paulus Johannes Maria Rek ,  David Schaddenhorst

Inventor： Jacobus Johannes Cornelis Geerlings ,  Marinus Franciscus Goes ,  Hans Michiel Huisman ,  Jean-Paul Lange ,  Heiko Oosterbeek ,  Paulus Johannes Maria Rek ,  David Schaddenhorst

IPC: B01J23/847 ,  B01J23/889 ,  C07B61/00 ,  C07C1/00 ,  C07C1/04 ,  C07C27/00 ,  B01J21/08 ,  B01J23/00 ,  B01J23/32 ,  B01J23/40

CPC classification number: B01J37/0201 ,  B01J23/8472 ,  B01J23/8892 ,  C07C1/0435 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/22 ,  C07C2523/34 ,  C07C2523/656 ,  C07C2523/75 ,  C07C2523/847 ,  C07C2523/889

Abstract: The present invention relates to a catalyst for use in a process for the preparation of hydrocarbons comprising cobalt and manganese and/or vanadium, supported on a carrier, wherein the cobalt:(manganese+vanadium) atomic ratio is at least 12:1. Preferably, the cobalt:(manganese+vanadium) atomic ratio is at most 1500:1. The invention further relates to a process for the preparation of hydrocarbons which comprises contacting a mixture of hydrogen and carbon monoxide at elevated temperature and pressure with a catalyst as described hereinbefore. Typically, at least part of the cobalt is present in the metallic state.

Abstract translation: 本发明涉及一种用于制备负载在载体上的包含钴和锰和/或钒的烃的方法的催化剂，其中钴（（锰+钒））原子比至少为12:1。 钴：（锰+钒）原子比优选为1500：1以下。 本发明还涉及制备烃的方法，其包括在升高的温度和压力下用如上所述的催化剂使氢气和一氧化碳的混合物接触。 通常，钴的至少一部分以金属状态存在。

公开(公告)号：US6011186A

公开(公告)日：2000-01-04

申请号：US67373

申请日：1998-04-27

Applicant: Hongwei Wang ,  Jacob Peenstra ,  Paulus Johannes Maria Rek ,  Petrus Joannes Josephus Tromp ,  Arian Van Mourik

Inventor： Hongwei Wang ,  Jacob Peenstra ,  Paulus Johannes Maria Rek ,  Petrus Joannes Josephus Tromp ,  Arian Van Mourik

IPC: B01J19/24 ,  B01J19/26 ,  C07C17/10 ,  C07C21/067 ,  C07C17/02

CPC classification number: C07C17/10 ,  B01J19/2435 ,  B01J2219/1945

Abstract: A process for manufacturing allylhalide from gaseous propene and a gaseous halogen comprising introducing propene into a tubular loop reactor (2) through an inlet nozzle (3); introducing gaseous halogen into the tubular loop reactor (2) through several axially spaced groups (6) of radially placed inlet openings (4); allowing the propene and the halogen to react; and removing reaction effluent from the tubular loop reactor (2) through an outlet opening (9), wherein the concentration of halogen in any reactor volume-element is maintained below 3% by mass based on the total gas mixture, and wherein the linear gas velocity of the propene exiting the inlet nozzle is at least sufficient to maintain a continuous circulation within the tubular loop reactor (2) and equipment to be used for said process.

Abstract translation: 包括从气态丙烯和气态卤素制造烯丙基卤的方法，包括通过入口喷嘴（3）将丙烯引入管状回路反应器（2）中; 通过径向放置的入口开口（4）的几个轴向间隔开的组（6）将气态卤素引入管状回路反应器（2）中。 使丙烯和卤素反应; 以及通过出口开口（9）除去来自管状回路反应器（2）的反应流出物，其中任何反应器体积元素中的卤素浓度基于总气体混合物保持在3质量％以下，并且其中线性气体 离开入口喷嘴的丙烯的速度至少足以保持管状回路反应器（2）内的连续循环和用于所述方法的设备。