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    Attenuated superactive multimetallic catalytic composite
    3.
    发明授权
    Attenuated superactive multimetallic catalytic composite 失效
    衰减超活性多金属催化复合材料

    公开(公告)号：US4312789A

    公开(公告)日：1982-01-26

    申请号：US197044

    申请日：1980-10-15

    申请人： George J. Antos

    发明人： George J. Antos

    IPC分类号： B01J23/656 ,  C10G35/09 ,  B01J27/08 ,  B01J23/62 ,  B01J27/10

    CPC分类号： C10G35/09 ,  B01J23/6567 ,  C07C2521/04 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/656 ,  C07C2527/126

    摘要： A novel attenuated superactive multimetallic catalytic composite especially useful for converting hydrocarbons comprises a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, and of a tin component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, tin component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.005 to about 5 wt. % tin and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a tin component and of a platinum group component maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent.

    摘要翻译： 特别适用于转化烃的新型减毒超活性多金属催化复合物包括催化有效量的热解铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的组合，其保持在 在羰基铼组分和锡组分的引入和热解期间的元素金属状态。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，锡组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.005至约5wt。 ％锡和约0.1至约3.5重量％ ％卤素。 与本发明的催化复合材料的制备相关的主要特征是羰基钌合物与含有均匀分散的锡组分和保持在元素状态的铂族组分的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。

    Hydrocarbon conversion with an attenuated superactive multimetallic catalytic composite
    4.
    发明授权
    Hydrocarbon conversion with an attenuated superactive multimetallic catalytic composite 失效
    用减弱的超多活性多金属催化复合材料进行烃转化

    公开(公告)号：US4256566A

    公开(公告)日：1981-03-17

    申请号：US68278

    申请日：1979-08-20

    申请人： George J. Antos

    发明人： George J. Antos

    IPC分类号： B01J23/656 ,  C10G35/09 ,  C10G35/08

    CPC分类号： B01J23/6567 ,  C10G35/09 ,  C07C2521/04 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/656 ,  C07C2527/126

    摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonylcomponent with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, and of a tin component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, tin component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.005 to about 5 wt. % tin and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a tin component and of a platinum group component maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the attenuated superactive multimetallic catalytic composite at reforming conditions.

    摘要翻译： 碳氢化合物通过在烃转化条件下与它们接触来转化，所述新型减毒超活性多金属催化复合材料包含催化有效量的热解铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的组合 ，其在羰基铼组分和锡组分的引入和热解过程中保持在元素金属状态。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，锡组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.005至约5wt。 ％锡和约0.1至约3.5重量％ ％卤素。 与本发明的催化复合材料的制备相关的主要特征是羰基钌合物与含有均匀分散的锡组分和保持在元素状态的铂族组分的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。 本文公开的烃转化方法的具体实例是低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与减弱的超活性多金属催化复合材料接触。

    Dehydrogenation method
    6.
    发明授权
    Dehydrogenation method 失效
    脱氢法

    公开(公告)号：US4104317A

    公开(公告)日：1978-08-01

    申请号：US775079

    申请日：1977-03-07

    申请人： George J. Antos

    发明人： George J. Antos

    IPC分类号： B01J23/656 ,  C07C5/32 ,  C07C5/333 ,  C07C5/367 ,  C07C15/00 ,  C07B3/00

    CPC分类号： C07C5/3337 ,  B01J23/6567 ,  C07C5/325 ,  C07C5/367 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/656 ,  Y02P20/52

    摘要： Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, a rhodium component, and a rhenium component with a porous carrier material. A specific example of the nonacidic catalytic composite disclosed herein is a combination of a platinum or palladium component, a rhodium component, a rhenium component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum or palladium, about 0.01 to about 2 wt. % rhodium, about 0.01 to about 2 wt. % rhenium and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal. A preferred modifying component for the disclosed catalytic composites is a sulfiding reagent.

    摘要翻译： 可脱氢烃通过在脱氢条件下与包含催化有效量的铂或钯组分，铑组分和铼组分的组合的催化复合物与多孔载体材料接触而脱氢。 本文公开的非酸催化复合物的具体实例是铂或钯组分，铑组分，铼组分和碱金属或碱土金属组分与多孔载体材料的组合，其量足以导致含有约 0.01至约2wt。 ％铂或钯，约0.01至约2重量％ ％铑，约0.01至约2wt。 ％铼和约0.1至约5wt。 ％碱金属或碱土金属。 所公开的催化复合材料的优选改性组分是硫化试剂。