公开(公告)号：US4336377A

公开(公告)日：1982-06-22

申请号：US116196

申请日：1980-01-28

Applicant: Jean-Marie Adam ,  Pierre Galafassi

Inventor： Jean-Marie Adam ,  Pierre Galafassi

IPC: C09B19/00 ,  C09B19/02 ,  C09B62/44 ,  C09B69/00

CPC classification number: C09B19/02 ,  C09B69/001

Abstract: Novel dioxazine compounds of the formula ##STR1## in which Z is a basic group, which can be quaternized, Y is an anionic group and X and X.sub.1 independently of one another are identical or different substituents from the category comprising: hydrogen, halogen, CN, substituted or unsubstituted alkyl (C.sub.1 -C.sub.4); substituted or unsubstituted phenyl; NHCOR.sub.1 in which R.sub.1 is alkyl (C.sub.1 -C.sub.4), cycloalkyl, substituted or unsubstituted aryl or a heterocyclic radical; and OCOR.sub.2 in which R.sub.2 is substituted or unsubstituted alkyl (C.sub.1 -C.sub.4) or cycloalkyl; or X and X.sub.1 are the group ##STR2## in which R.sub.4 and R.sub.5 independently of one another are: hydrogen, substituted or unsubstituted alkyl (C.sub.1 -C.sub.4), cycloalkyl or aryl, or R.sub.4 together with R.sub.5 and with the inclusion of the N atom forms a heterocyclic ring, or X and X.sub.1 are the group COOR.sub.6, in which R.sub.6 is hydrogen, substituted or unsubstituted alkyl or cycloalkyl; n is a number from 1 to 4 and m is a number from 0 to 2, with the proviso that the number m is smaller than n, and in which the benzo radicals A and A.sub.1 can be identical or different and can have one or more further substituents, their preparation and their use as dyes, in particular for dyeing and printing natural and regenerated cellulose materials without the addition of salt, are described.

Abstract translation: 式（Ⅰ）的新型二嗪类化合物，其中Z为碱性基团，其可季铵化，Y为阴离子基团，X和X1彼此独立地为相同或不同的取代基，其类别包括：氢， 卤素，CN，取代或未取代的烷基（C1-C4）; 取代或未取代的苯基; NHCOR1，其中R1是烷基（C1-C4），环烷基，取代或未取代的芳基或杂环基; 和OCOR2，其中R2是取代或未取代的烷基（C1-C4）或环烷基; 或者X和X 1是其中R 4和R 5彼此独立的基团是：氢，取代或未取代的烷基（C 1 -C 4），环烷基或芳基，或R 4与R 5一起并包括N原子 形成杂环，或X和X 1为COOR 6基团，其中R 6为氢，取代或未取代的烷基或环烷基; n是1至4的数，m是0至2的数，条件是数m小于n，其中苯并基A和A1可以相同或不同，并且可以具有一个或多个 描述了进一步的取代基，它们的制备及其作为染料的用途，特别是用于染色和印刷天然和再生纤维素材料而不添加盐的用途。

公开(公告)号：US4233028A

公开(公告)日：1980-11-11

申请号：US871918

申请日：1978-01-24

Applicant: Josef Koller ,  Ulrich Horn ,  Peter Moser ,  Manfred Motter ,  Pierre Galafassi

Inventor： Josef Koller ,  Ulrich Horn ,  Peter Moser ,  Manfred Motter ,  Pierre Galafassi

IPC: D06P1/66 ,  D06P3/76 ,  D06P1/41 ,  D06P5/00

CPC classification number: D06P3/76 ,  D06P1/66 ,  Y10S534/01

Abstract: Described is a process for the level dyeing of polyacrylonitrile materials of slow, normal and rapid absorptive capacity with an aqueous dye liquor, which process comprises using a liquor containing at least one migrating cationic dye as well as, if required, further additives; and adding to the liquor, before, during or after dyeing, at least one organic cationic migration auxiliary.This process renders possible by the use of organic migration auxiliaries the obtainment of level single-shade and, in particular, combination-shade dyeings at normal dyeing temperatures.Particularly suitable migrating cationic dyestuffs are those having a more or less delocalized positive charge, the cation weight of which dyestuffs is smaller than 310, the parachor smaller than 750 and the log P (relative lipophil property) smaller than 3.6.Particularly suitable organic migration auxiliaries are those of which the cation weight is smaller than 250, the parachor smaller than 700 and the log P smaller than 6.4.

Abstract translation: 描述了一种使用含水染料液进行慢，正常和快速吸收能力的聚丙烯腈材料的水平染色的方法，该方法包括使用含有至少一种迁移阳离子染料的液体，以及如果需要的话，还可添加其它添加剂; 并在染色之前，期间或之后向酒中加入至少一种有机阳离子迁移助剂。 该方法可以通过使用有机迁移助剂获得水平单色，特别是在正常染色温度下的组合色调染色。 特别合适的迁移性阳离子染料是具有或多或少的离域正电荷，其中染料的阳离子重量小于310，脱酰胺小于750，对数P（相对亲脂性）小于3.6的那些。 特别合适的有机迁移助剂是阳离子重量小于250，助溶剂小于700，对数P小于6.4的有机迁移助剂。

公开(公告)号：US4181499A

公开(公告)日：1980-01-01

申请号：US829832

申请日：1977-09-01

Applicant: Joseph Koller ,  Manfred Motter ,  Peter Moser ,  Ulrich Horn ,  Pierre Galafassi

Inventor： Joseph Koller ,  Manfred Motter ,  Peter Moser ,  Ulrich Horn ,  Pierre Galafassi

IPC: D06P1/66 ,  D06P3/76 ,  D06P1/41 ,  C09B19/00 ,  C09B29/38

CPC classification number: D06P1/66 ,  D06P3/76

Abstract: Described is a process for the level dyeing of polyacrylonitrile materials, in which process there is used for dyeing polyacrylonitrile materials that have varying substantivity an aqueous dye liquor containing at least one migrating cationic dyestuff and electrolyte, as well as, optionally, at least one migrating cationic retarder and further additives. This process renders possible a level dyeing of all fibre types of polyacrylonitrile materials by one and the same dyeing method. Generally, no addition of a migrating cationic retarder is necessary. Only in the case of a light-colored dyeing is a very minor addition thereof required. Particularly suitable migrating cationic dyestuffs are those having a more or less delocalized positive charge, the cation weight of which dyestuffs is smaller than 310, the parachor smaller than 750 and the log P (relative lipophil property) smaller than 3.6.

Abstract translation: 描述了一种用于对聚丙烯腈材料进行水平染色的方法，其中用于染色具有不同亲和性的聚丙烯腈材料的方法是含有至少一种迁移阳离子染料和电解质的含水染料液，以及任选地至少一种迁移 阳离子缓凝剂和其它添加剂。 该方法可以通过一种相同的染色方法对所有纤维类型的聚丙烯腈材料进行染色。 通常，不需要添加迁移的阳离子缓凝剂。 只有在浅色染色的情况下才需要很少的添加。 特别合适的迁移性阳离子染料是具有或多或少的离域正电荷，其中染料的阳离子重量小于310，脱酰胺小于750，对数P（相对亲脂性）小于3.6的那些。

公开(公告)号：US5356440A

公开(公告)日：1994-10-18

申请号：US96143

申请日：1993-07-22

Applicant: Pierre Galafassi ,  Jean-Marie Adam

Inventor： Pierre Galafassi ,  Jean-Marie Adam

IPC: C09B62/503 ,  D06P3/24 ,  D06P1/384 ,  C09B62/527 ,  C09B62/53

CPC classification number: C09B62/503 ,  D06P3/248

Abstract: The invention relates to a process for the dyeing of synthetic polyamide fibre materials, which comprises dyeing these fibre materials with a reactive dye of the formulaHO.sub.3 S--Fa--X--SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H).sub.m(1),in which Fa is a dye radical, X is a direct bond or a radical of the formula --CONHCH.sub.2 CH.sub.2 -- and m is the number 1 or 2, the dye of the formula (1) containing only one sulfo group, from an aqueous liquor at a pH of 5 to 9 and, to set the dyeing temperature, raising the temperature from 80.degree. C. to at least 95.degree. C. over a period of at least 20 minutes. The process according to the invention produces level dyeings on synthetic polyamide fibre materials.

Abstract translation: 本发明涉及一种染色合成聚酰胺纤维材料的方法，其中包括使用式HO3S-Fa-X-SO2CH2CH2OSO3H）m（1）的活性染料染色这些纤维材料，其中Fa是染料基团，X 是式-CONHCH 2 CH 2 - 的直接键或基团，m为1或2，式（1）的染料仅含有一个磺基，pH为5至9的含水液体，以及 设定染色温度，在至少20分钟的时间内将温度从80℃提高至至少95℃。 根据本发明的方法在合成聚酰胺纤维材料上产生高级染色。

公开(公告)号：US5071442A

公开(公告)日：1991-12-10

申请号：US638253

申请日：1991-01-04

Applicant: Jean P. Luttringer ,  Athanassios Tzikas ,  Pierre Galafassi

Inventor： Jean P. Luttringer ,  Athanassios Tzikas ,  Pierre Galafassi

IPC: C09B67/22 ,  D06P1/38 ,  D06P1/382 ,  D06P3/66

CPC classification number: D06P3/663 ,  C09B67/0047 ,  D06P1/382 ,  Y10S8/918

Abstract: A process for dyeing or printing cellulosic textile fibre materials by the trichromatic technique, which process comprises dyeing or printing said materials from an aqueous liquor with at least one red or reddish brown dyeing dye of formula ##STR1## and at least one yellow or orange dyeing dye of formula ##STR2## and at least one blue dyeing dye of formula ##STR3## wherein A.sub.1, A.sub.2, (B.sub.2).sub.1-3, R.sub.1, R.sub.2, R.sub.3, (R.sub.4).sub.1-2, (X).sub.1-2, (T.sub.1).sub.1-2, (T.sub.2).sub.1-2, (Y).sub.1-3 and Z in formulae (1) to (7) are as defined in claim 1.The process of this invention is suitable for dyeing or printing cellulosic fibre materials.

Abstract translation: 一种通过三色技术染色或印刷纤维素纺织纤维材料的方法，该方法包括用水性液体用至少一种红色或红褐色染色染料染色或印刷所述材料，所述染色剂具有式（IMAGE）（1）或

公开(公告)号：US4736021A

公开(公告)日：1988-04-05

申请号：US417153

申请日：1982-09-13

Applicant: Jean-Marie Adam ,  Pierre Galafassi

Inventor： Jean-Marie Adam ,  Pierre Galafassi

IPC: C09B44/02 ,  D21H21/28 ,  C09B44/08 ,  D06P1/41 ,  D21H1/46

CPC classification number: D21H21/28 ,  C09B44/02

Abstract: There are described azo compounds of the formula ##STR1## wherein K is an optionally quaternized basic group,X is the radical COOR, in which R is an alkyl group or a substituted or unsubstituted phenyl group, or X is the radical CONHR', in which R' is an alkyl group or a substituted or unsubstituted phenyl group; and wherein the benzene rings B and/or D can be further substituted;and the use thereof as dyes for the dyeing of textile materials, and particularly for the dyeing of paper of all types, especially bleached, lignin-free, unsized paper.

Abstract translation: 描述了式IMA的偶氮化合物，其中K是任选季铵化的碱基，X是基团COOR，其中R是烷基或取代或未取代的苯基，或X是基团CONHR'，其中 其中R'为烷基或取代或未取代的苯基; 并且其中苯环B和/或D可以进一步被取代; 以及其作为纺织材料染色的染料的用途，特别是用于所有类型的纸张的染色，特别是漂白的无木质素的未定型纸。

公开(公告)号：US4395545A

公开(公告)日：1983-07-26

申请号：US292970

申请日：1981-08-14

Applicant: Jean-Marie Adam ,  Pierre Galafassi

Inventor： Jean-Marie Adam ,  Pierre Galafassi

IPC: C09B19/00 ,  C09B19/02 ,  C09B62/44 ,  C09B62/465 ,  C09B62/523 ,  C09B69/00 ,  D21H19/10 ,  C07D498/22

CPC classification number: C09B19/02 ,  C09B69/001

Abstract: The invention discloses novel basic dioxazine compounds of the formula ##STR1## wherein each of X.sub.1 and X.sub.2 independently is an unbranched or branched alkyl group of 1 to 4 carbon atoms, an unsubstituted or substituted phenyl group, halogen, hydrogen, cyano, a phenylamino group which is unsubstituted or substituted in the phenyl nucleus, the CONH.sub.2 group, the CONH-phenyl group which can be substituted in the phenyl moiety, or a COO--C.sub.1 -C.sub.4 alkyl group; Z is a non-quaternized or quaternized basic group, Y is an anionic group, each B independently is a fused ring system containing 2 to 4 carbocyclic and/or heterocyclic rings and which, in addition to containing the substituents Z and Y, can be further substituted; n is 1 to 4 and m is 0 to 2, with the proviso that m is not greater than n. Processes for obtaining these compounds and their use as dyes for coloring and printing in particular cellulosic fabrics, without the addition of salt, are also disclosed.

Abstract translation: 本发明公开了式（I）的新型基本二恶嗪化合物，其中X1和X2各自独立地是1至4个碳原子的未支化或支链烷基，未取代或取代的苯基，卤素，氢，氰基， 在苯基中未取代或取代的苯基氨基，CONH 2基，可在苯基部分取代的CONH-苯基或COO-C 1 -C 4烷基; Z是非季铵化或季铵化的碱性基团，Y是阴离子基团，每个B独立地是含有2至4个碳环和/或杂环的稠环体系，并且除了含有取代基Z和Y之外，它们可以是 进一步取代; n为1〜4，m为0〜2，条件是m不大于n。 还公开了获得这些化合物的方法及其作为染料用于特别是纤维素织物着色和印刷的用途，而不添加盐。

公开(公告)号：US4292037A

公开(公告)日：1981-09-29

申请号：US116379

申请日：1980-01-29

Applicant: Pierre Galafassi ,  Jean-Marie Adam ,  Peter Loew ,  Hans Scheidegger

Inventor： Pierre Galafassi ,  Jean-Marie Adam ,  Peter Loew ,  Hans Scheidegger

IPC: C09B47/32 ,  C09B69/00 ,  D06P3/60 ,  C09B67/00 ,  C09B44/00

CPC classification number: C09B47/32 ,  C09B69/001 ,  D06P3/6016 ,  Y10S8/918 ,  Y10S8/919

Abstract: There is described a process for dyeing paper or, in particular, cellulose containing fibre material with an aqueous dye liquor, which dye liquor contains at least one cationic or basic dye which(a) has available at least one system of delocalized .pi.-electrons, which system consists of at least 9 conjugated double bonds lying in one plane, and(b) possesses a planar molecular structure, the said material being treated, before or during dyeing, with at least one cationic or basic levelling agent; there is no necessity to add salt additionally to the dye bath, and there are obtained by this process level dyeings which exhibit a high degree of exhaustion of the dye, and which are characterized by good fastness properties, especially by good fastness to wet processing.

Abstract translation: 描述了一种用水性染料液对纸或特别是含纤维素纤维材料进行染色的方法，该染料液含有至少一种阳离子或碱性染料，（a）具有至少一种离域π电子系统， 该系统由位于一个平面中的至少9个共轭双键组成，（b）具有平面分子结构，所述材料在染色之前或期间用至少一种阳离子或碱性流平剂进行处理; 不需要在染浴中添加盐，并且通过该染色处理水平的染色得到，染色的耗尽度高，特征在于具有良好的牢度特性，特别是耐湿牢度好的特征。