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1.发明申请Process for the production of expanded plastic materials, in particular PVC-based polymeric foams and a formulation of a polymeric blend for effecting said process 有权用于生产膨胀塑料材料的方法，特别是PVC基聚合物泡沫体和用于实现所述方法的聚合物共混物的制剂公开(公告)号：US20130267620A1
公开(公告)日：2013-10-10
申请号：US13703327
申请日：2011-06-24
IPC分类号： C08J9/00
CPC分类号： C08J9/0061 , B29C44/3415 , B29K2027/06 , C08J9/10 , C08J2327/06 , C08J2475/00
摘要： A perfected process for the production of expanded plastic materials, comprising a hot moulding phase of a starting polymeric blend inside a mould, wherein the heating of said blend is effected by making the same a heat source, by triggering an exothermic reaction in its interior. With respect to the known art in the field, the process of the invention allows an improvement in the heating of the polymeric mass inside the mould, reducing the times necessary for effecting it and homogenizing the thermal values inside this mass.
摘要翻译： 一种用于生产膨胀塑料材料的完善方法，其包括在模具内部的起始聚合物共混物的热模塑相，其中所述共混物的加热通过使其在其内部引发放热反应而制成热源来实现。 对于本领域已知的技术，本发明的方法允许改进模具内的聚合物质的加热，减少实现其所需的时间并使该物质内的热值均匀化。
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2.发明授权Formulations for cellular, foamed-polymer products based on polyvinyl chloride, improved cellular, foamed-polymer products based on polyvinyl chloride and a process for producing said improved cellular foamed-polymer products 有权基于聚氯乙烯的细胞，泡沫聚合物产品的制剂，基于聚氯乙烯的改进的细胞，泡沫聚合物产品和用于生产所述改进的细胞泡沫聚合物产品的方法公开(公告)号：US08168293B2
公开(公告)日：2012-05-01
申请号：US12227929
申请日：2007-06-05
CPC分类号： C08G18/6275 , B23K20/10 , B23K2101/38 , C08G18/341 , C08G18/797 , C08J9/0061 , C08J9/102 , C08J9/103 , C08J2327/06 , C08J2475/00 , Y10T428/24992 , Y10T428/249953
摘要： Formulation for cellular, foamed-polymer product based on polyvinyl chloride, comprising: a polyvinyl chloride homopolymer having a K-value of from 60 to 85 and a pH value of the aqueous extract ranging of from 8 to 12; at least one isocyanate selected from isomers and homologues of diphenylmethane-4,4′-diisocyanate and modified diphenylmethane-4,4-diisocyanate s and mixtures thereof; at least one anhydride selected from the group of succinic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, methyl-tetrahydrophthalic anhydride, 4-methyl-hexahydrophthalic anhydride, cyclohexane-1,2-dicarboxylic anhydride, methyl-endomethylene tetrahydrophthalic anhydride, dodecenyl succinic anhydride, trimellitic anhydride and mixtures thereof; at least a surfactant; at least a foaming agent.
摘要翻译： 基于聚氯乙烯的泡沫聚合物产品的配方，包括：K值为60至85的聚氯乙烯均聚物和水提取物的pH值为8至12; 选自二苯基甲烷-4,4'-二异氰酸酯和改性二苯基甲烷-4,4-二异氰酸酯的异构体和同系物中的至少一种异氰酸酯及其混合物; 选自琥珀酸酐，四氢邻苯二甲酸酐，六氢邻苯二甲酸酐，甲基 - 四氢邻苯二甲酸酐，4-甲基 - 六氢邻苯二甲酸酐，环己烷-1,2-二羧酸酐，甲基 - 内亚甲基四氢邻苯二甲酸酐，十二碳烯基琥珀酸酐，偏苯三酸酐 酸酐及其混合物; 至少一种表面活性剂; 至少发泡剂。
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3.发明授权Enhanced process for the production of expanded PVC and plastic materials based on expanded PVC obtained therewith 有权用于生产基于由其获得的膨胀PVC的膨胀PVC和塑料材料的增强方法公开(公告)号：US08492446B2
公开(公告)日：2013-07-23
申请号：US13697516
申请日：2011-06-07
CPC分类号： C08J3/246 , B29C44/02 , B29C44/0415 , B29C44/3411 , B29K2027/06 , B29K2105/04 , B29K2105/165 , C08J9/0061 , C08J9/04 , C08J9/32 , C08J2327/06 , C08J2375/00 , C08J2427/06
摘要： A process for the production of expanded PVC of the type includes heating a mass of polymeric mixture inside a closed mold; controlling the expansion of the mass in an environment having a constant volume defined by the closed mold, control being performed by the presence, in the mass of polymeric mixture, of microparticles of a compressible material, suitable for being contracted, under the action of the pressure generated by the formation and expansion of microcells of expanding gas in the same mass, from an initial form having a larger volume, to a form having a smaller volume; and expanding the microparticles, from their configuration to the initial configuration, the density of the expanded material thus obtained being determined by the contemporary presence of both microcells of expanding gas and the microparticles in their configuration having a larger volume.
摘要翻译： 用于生产这种类型的膨胀PVC的方法包括在封闭模具内加热聚合物混合物; 在由闭合模具限定的具有恒定体积的环境中控制质量的膨胀，控制是通过在聚合物混合物的质量下存在适合于收缩的可压缩材料的微粒， 由具有较大体积的初始形式的相同质量的膨胀气体的微细胞的形成和膨胀产生的压力形成具有较小体积的形式; 并且将微粒从其构型扩展到初始构型，由此获得的膨胀材料的密度由发泡气体的微细胞和具有较大体积的微结构的当前存在来确定。
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4.发明授权Process for the production of expanded plastic materials, in particular PVC-based polymeric foams and a formulation of a polymeric blend for effecting said process 有权用于生产膨胀塑料材料的方法，特别是PVC基聚合物泡沫体和用于实现所述方法的聚合物共混物的制剂公开(公告)号：US08895634B2
公开(公告)日：2014-11-25
申请号：US13703327
申请日：2011-06-24
CPC分类号： C08J9/0061 , B29C44/3415 , B29K2027/06 , C08J9/10 , C08J2327/06 , C08J2475/00
摘要： A perfected process for the production of expanded plastic materials, comprising a hot molding phase of a starting polymeric blend inside a mold, wherein the heating of said blend is effected by making the same a heat source, by triggering an exothermic reaction in its interior. With respect to the known art in the field, the process of the invention allows an improvement in the heating of the polymeric mass inside the mold, reducing the times necessary for effecting it and homogenizing the thermal values inside this mass.
摘要翻译： 一种用于生产膨胀塑料材料的完善方法，其包括在模具内部的起始聚合物共混物的热模塑相，其中所述共混物的加热通过使其在其内部引发放热反应而制成热源来实现。 对于本领域已知的技术，本发明的方法允许改进模具内的聚合物质的加热，减少实现其所需的时间并使该物质内的热值均匀化。
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公开(公告)号：US20130150474A1
公开(公告)日：2013-06-13
申请号：US13697516
申请日：2011-06-07
CPC分类号： C08J3/246 , B29C44/02 , B29C44/0415 , B29C44/3411 , B29K2027/06 , B29K2105/04 , B29K2105/165 , C08J9/0061 , C08J9/04 , C08J9/32 , C08J2327/06 , C08J2375/00 , C08J2427/06
摘要： A process for the production of expanded PVC of the type includes heating a mass of polymeric mixture inside a closed mold; controlling the expansion of the mass in an environment having a constant volume defined by the closed mold, control being performed by the presence, in the mass of polymeric mixture, of microparticles of a compressible material, suitable for being contracted, under the action of the pressure generated by the formation and expansion of microcells of expanding gas in the same mass, from an initial form having a larger volume, to a form having a smaller volume; and expanding the microparticles, from their configuration to the initial configuration, the density of the expanded material thus obtained being determined by the contemporary presence of both microcells of expanding gas and the microparticles in their configuration having a larger volume.
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6.发明申请Formulations for Cellular, Foamed-Polymer Products Based on Polyvinyl Chloride,Improved Cellular, Foamed-Polymer Products Based on Polyvinyl Chloride and a Process for Producing Said Improved Cellular Foamed-Polymer Products 有权基于聚氯乙烯的蜂窝状泡沫聚合物制品，改进的基于聚氯乙烯的泡沫聚合物产品和生产所述改进的蜂窝发泡聚合物产品的方法公开(公告)号：US20100068487A1
公开(公告)日：2010-03-18
申请号：US12227929
申请日：2007-06-05
CPC分类号： C08G18/6275 , B23K20/10 , B23K2101/38 , C08G18/341 , C08G18/797 , C08J9/0061 , C08J9/102 , C08J9/103 , C08J2327/06 , C08J2475/00 , Y10T428/24992 , Y10T428/249953
摘要： Formulation for cellular, foamed-polymer product based on polyvinyl chloride, comprising: a polyvinyl chloride homopolymer having a K-value of from 60 to 85 and a pH value of the aqueous extract ranging of from 8 to 12; at least one isocyanate selected from isomers and homologues of diphenylmethane-4,4′-diisocyanate and modified diphenylmethane-4,4-diisocyanate s and mixtures thereof; at least one anhydride selected from the group of succinic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, methyl-tetrahydrophthalic anhydride, 4-methyl-hexahydrophthalic anhydride, cyclohexane-1,2-dicarboxylic anhydride, methyl-endomethylene tetrahydrophthalic anhydride, dodecenyl succinic anhydride, trimellitic anhydride and mixtures thereof; at least a surfactant; at least a foaming agent.
摘要翻译： 基于聚氯乙烯的泡沫聚合物产品的配方，包括：K值为60至85的聚氯乙烯均聚物和水提取物的pH值为8至12; 选自二苯基甲烷-4,4'-二异氰酸酯和改性二苯基甲烷-4,4-二异氰酸酯的异构体和同系物中的至少一种异氰酸酯及其混合物; 选自琥珀酸酐，四氢邻苯二甲酸酐，六氢邻苯二甲酸酐，甲基 - 四氢邻苯二甲酸酐，4-甲基 - 六氢邻苯二甲酸酐，环己烷-1,2-二羧酸酐，甲基 - 内亚甲基四氢邻苯二甲酸酐，十二碳烯基琥珀酸酐，偏苯三酸酐 酸酐及其混合物; 至少一种表面活性剂; 至少发泡剂。
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