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公开(公告)号：US06998072B2
公开(公告)日：2006-02-14
申请号：US10270622
申请日：2002-10-16
申请人： Cletus N. Welch , Eric M. King , Lawrence G. Anderson , Randy E. Daughenbaugh , Kevin J. Stewart
发明人： Cletus N. Welch , Eric M. King , Lawrence G. Anderson , Randy E. Daughenbaugh , Kevin J. Stewart
CPC分类号： G02B5/23 , C03C17/32 , C08G18/44 , C08G18/8108 , C08G64/0291 , C09D4/06 , C09K9/02 , Y10S430/163 , C08F290/062
摘要： Described is a polymerizable composition of a photochromic amount of at least one photochromic compound, at least one material having at least one carbonate group and at least one hydroxyl group, and at least one monoisocyanate containing material having at least one unsaturated group. The polymerizable composition optionally contains copolymerizable monomers. Also described are photochromic polymerizates, e.g., photochromic optical elements such as ophthalmic lenses, prepared from the polymerizable composition of the present invention.
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公开(公告)号：US5811503A
公开(公告)日：1998-09-22
申请号：US758620
申请日：1996-11-27
IPC分类号： C08F222/10 , C08F290/06 , C09K9/02 , G02B5/23 , G03C1/685 , G03C1/73
CPC分类号： C09K9/02 , C08F222/1006 , C08F290/062 , G03C1/685 , G02B5/23 , Y10S430/163
摘要： Describes polymerizable organic compositions of from about 30 to 95 weight percent of a first monomer component which is an alkoxylated diol, e.g., alkoxylated bisphenol, having acrylate or methacrylate groups, i.e., dimethacrylate of bisphenol A having an average of 1 to 4 ethoxy units, and from about 5 to 70 weight percent of a second monomer component which is an alkoxylated diol, e.g., alkoxylated bisphenol, having acrylate or methacrylate groups, i.e., dimethacrylate of bisphenol A having 25 to 70 ethoxy units. Optionally there may also be present from about 0 to 65 weight percent of at least one monomer component which is selected from: (i) a monoethylenically unsaturated monomer that is polymerizable by free radical initiation; (ii) a bis�(meth)acryloyl-terminated!polyethylene glycol monomer; and (iii) a monomer having at least three terminal ethylenically-unsaturated groups. Substantially completely cured polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g., lenses, by incorporating a photochromic substance, e.g., by thermal transfer, into the polymerizate.
摘要翻译： 描述了约30至95重量％的第一单体组分（其为烷氧基化二醇）的可聚合有机组合物，例如具有丙烯酸酯或甲基丙烯酸酯基团的烷氧基化双酚，即具有平均1至4个乙氧基单元的双酚A的二甲基丙烯酸酯， 和约5至70重量％的第二单体组分，其为烷氧基化二醇，例如具有丙烯酸酯或甲基丙烯酸酯基团的烷氧基化双酚，即具有25至70个乙氧基单元的双酚A的二甲基丙烯酸酯。 任选地，还可以存在约0至65重量％的至少一种单体组分，其选自：（i）可通过自由基引发聚合的单烯属不饱和单体; （ii）双（（甲基）丙烯酰基封端的]聚乙二醇单体; 和（iii）具有至少三个末端烯属不饱和基团的单体。 通过将这种组合物制备的基本上完全固化的聚合物可以用于通过将光致变色物质例如通过热转移引入到聚合物中来制备光致变色制品，例如镜片。
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公开(公告)号：US08563213B2
公开(公告)日：2013-10-22
申请号：US12719335
申请日：2010-03-08
申请人： Steven E. Bowles , Anu Chopra , Randy E. Daughenbaugh , Dennis L. Faler , M. Frank Haley , Paul H. Lamers , Yunyi Lu , Kevin J. Stewart , Cathy A. Taylor , Feng Wang , Elizabeth A. Zezinka
发明人： Steven E. Bowles , Anu Chopra , Randy E. Daughenbaugh , Dennis L. Faler , M. Frank Haley , Paul H. Lamers , Yunyi Lu , Kevin J. Stewart , Cathy A. Taylor , Feng Wang , Elizabeth A. Zezinka
CPC分类号： G03F7/002 , C08F290/067 , C08G18/3271 , C08G18/3275 , C08G18/672 , C08G18/751 , C08G18/757 , C08G18/758 , C08G18/792 , C08G18/8116 , C08L25/06 , C09D175/04 , C09D175/16 , C09K9/02 , G03C1/733 , G03F7/038 , G03F7/105 , C08G18/0823 , C08L2666/14 , C08L2666/16
摘要： Described are various methods of producing non-aqueous dispersions of photosensitive polymeric microparticles, comprising: (a) preparing one or more aqueous dispersions of a polymerizable component, at least one of which contains a photosensitive material and, wherein the polymerizable components comprise at least one hydrophilic functional group and/or at least one hydrophobic functional group; (b) subjecting the dispersion of (a) to conditions sufficient to form microparticles; (c) at least partially polymerizing the polymerizable component; (d) combining the dispersion with an organic continuous phase comprising an organic solvent; (e) removing water from the dispersion such that the final water content of the non-aqueous dispersion is less than 30 percent by weight; wherein e) is performed before or after d); and (f) reacting any acid functional groups on the surface of the microparticles with a reactive material having at least one epoxy functional group, at least one thiocarbonylthio functional group, at least one alkoxyamine functional group, or at least one halide functional group.
摘要翻译： 描述了生产光敏聚合物微粒非水分散体的各种方法，包括：（a）制备一种或多种可聚合组分的水分散体，其中至少一种含有感光材料，其中可聚合组分包括至少一种 亲水官能团和/或至少一个疏水官能团; （b）使（a）的分散体经受足以形成微粒的条件; （c）至少部分聚合可聚合组分; （d）将分散体与包含有机溶剂的有机连续相组合; （e）从分散体中除去水，使得非水分散体的最终含水量小于30重量％; 其中e）在d）之前或之后进行; 和（f）使微粒表面上的任何酸官能团与具有至少一个环氧官能团，至少一个硫代羰硫基官能团，至少一个烷氧基胺官能团或至少一个卤化物官能团的反应性材料反应。
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公开(公告)号：US5973093A
公开(公告)日：1999-10-26
申请号：US757206
申请日：1996-11-27
IPC分类号： C08F220/28 , C08F222/10 , C08F290/06 , G02B1/04 , G03C1/73 , C08F18/24 , C08L35/02
CPC分类号： G03C1/733 , C08F220/28 , C08F222/1006 , C08F290/062 , G02B1/041 , Y10S430/163
摘要： Describes polymerizable organic compositions of a major amount of a first monomer component which is a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), and from about 2 to 35 weight percent of a second monomer component which is an alkoxylated bisphenol (or hydrogenated bisphenol) having acrylate or methacrylate groups, e.g., dimethacrylate of bisphenol A having 25 to 35 ethoxy units. Substantially completely cured polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g., lenses, by incorporating a photochromic substance, e.g., by thermal transfer, into the polymerizate.
摘要翻译： 描述主要量的作为多元醇（碳酸烯丙酯）的第一单体组分的可聚合有机组合物，例如二甘醇双（碳酸烯丙酯）和约2-35重量％的第二单体组分，其是烷氧基化双酚 （或氢化双酚），其具有丙烯酸酯或甲基丙烯酸酯基团，例如具有25至35个乙氧基单元的双酚A的二甲基丙烯酸酯。 通过将这种组合物制备的基本上完全固化的聚合物可以用于通过将光致变色物质例如通过热转移引入到聚合物中来制备光致变色制品，例如镜片。
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公开(公告)号：US20100221661A1
公开(公告)日：2010-09-02
申请号：US12719335
申请日：2010-03-08
申请人： Steven E. Bowles , Anu Chopra , Randy E. Daughenbaugh , Dennis L. Faler , M. Frank Haley , Paul H. Lamers , Yunyi Lu , Kevin J. Stewart , Cathy A. Taylor , Feng Wang , Elizabeth A. Zezinka
发明人： Steven E. Bowles , Anu Chopra , Randy E. Daughenbaugh , Dennis L. Faler , M. Frank Haley , Paul H. Lamers , Yunyi Lu , Kevin J. Stewart , Cathy A. Taylor , Feng Wang , Elizabeth A. Zezinka
IPC分类号： G03F7/004
CPC分类号： G03F7/002 , C08F290/067 , C08G18/3271 , C08G18/3275 , C08G18/672 , C08G18/751 , C08G18/757 , C08G18/758 , C08G18/792 , C08G18/8116 , C08L25/06 , C09D175/04 , C09D175/16 , C09K9/02 , G03C1/733 , G03F7/038 , G03F7/105 , C08G18/0823 , C08L2666/14 , C08L2666/16
摘要： Described are various methods of producing non-aqueous dispersions of photosensitive polymeric microparticles, comprising: (a) preparing one or more aqueous dispersions of a polymerizable component, at least one of which contains a photosensitive material and, wherein the polymerizable components comprise at least one hydrophilic functional group and/or at least one hydrophobic functional group; (b) subjecting the dispersion of (a) to conditions sufficient to form microparticles; (c) at least partially polymerizing the polymerizable component; (d) combining the dispersion with an organic continuous phase comprising an organic solvent; (e) removing water from the dispersion such that the final water content of the non-aqueous dispersion is less than 30 percent by weight; wherein e) is performed before or after d); and (f) reacting any acid functional groups on the surface of the microparticles with a reactive material having at least one epoxy functional group, at least one thiocarbonylthio functional group, at least one alkoxyamine functional group, or at least one halide functional group.
摘要翻译： 描述了生产光敏聚合物微粒非水分散体的各种方法，包括：（a）制备一种或多种可聚合组分的水分散体，其中至少一种含有感光材料，其中可聚合组分包括至少一种 亲水官能团和/或至少一个疏水官能团; （b）使（a）的分散体经受足以形成微粒的条件; （c）至少部分聚合可聚合组分; （d）将分散体与包含有机溶剂的有机连续相组合; （e）从分散体中除去水，使得非水分散体的最终含水量小于30重量％; 其中e）在d）之前或之后执行; 和（f）使微粒表面上的任何酸官能团与具有至少一个环氧官能团，至少一个硫代羰硫基官能团，至少一个烷氧基胺官能团或至少一个卤化物官能团的反应性材料反应。
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公开(公告)号：US06916537B2
公开(公告)日：2005-07-12
申请号：US10270657
申请日：2002-10-16
申请人： Cletus N. Welch , Eric M. King , Lawrence G. Anderson , Randy E. Daughenbaugh , Kevin J. Stewart
发明人： Cletus N. Welch , Eric M. King , Lawrence G. Anderson , Randy E. Daughenbaugh , Kevin J. Stewart
IPC分类号： C03C17/32 , C08G18/44 , C08G18/81 , C08G64/02 , C09D4/06 , C09K9/02 , D06P1/00 , G02B5/23 , B32B27/36 , C08F12/28 , C08F18/24 , C08F26/02
CPC分类号： D06P1/004 , C03C17/32 , C08G18/44 , C08G18/8108 , C08G64/0291 , C09D4/06 , C09K9/02 , G02B5/23 , Y10T428/31507 , Y10T428/31551 , C08F290/062
摘要： Described is a photochromic article that includes a substrate and at least a partial coating of an at least partially cured polymerizable composition of a photochromic amount of at least one photochromic compound, at least one material having at least one carbonate group and at least one hydroxyl group, and at least one monoisocyanate containing material having at least one unsaturated group. Also described are photochromic optical elements such as ophthalmic lenses, prepared from an optical element substrate coated with the photochromic polymerizable composition.
摘要翻译： 描述了一种光致变色制品，其包括基材和至少部分固化的光致变色量的至少一种光致变色化合物的至少部分固化的可聚合组合物的至少一部分涂层，至少一种具有至少一个碳酸酯基团和至少一个羟基的材料 和至少一种含异氰酸酯的材料具有至少一个不饱和基团。 还描述了由涂有光致变色聚合性组合物的光学元件基材制备的光致变色光学元件如眼镜。
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公开(公告)号：US06506864B1
公开(公告)日：2003-01-14
申请号：US09630074
申请日：2000-08-01
IPC分类号： C08F11636
CPC分类号： C08F18/24 , C08F2218/245
摘要： Describes a polymerizable composition of (a) a first allyl functional monomer, which is selected such that a substantially completely cured polymerizate of the first allyl functional monomer has a 15 second Barcol 934 hardness of at least 40, and (b) a second allyl functional monomer selected from polyether diol bis(allyl carbonate), polylactone diol bis(allyl carbonate) and mixtures thereof. The second allyl functional monomer is present in the composition in an amount to provide a substantially completely cured polymerizate having: (i) improved organic photochromic substance incorporation relative to a substantially completely cured polymerizate of the composition free of monomer (b); and (ii) heat distortion temperature of at least 40° C.
摘要翻译： 描述了（a）第一烯丙基官能单体的可聚合组合物，其被选择为使得第一烯丙基官能单体的基本上完全固化的聚合物具有至少40的15秒钟Barcol 934硬度，和（b）第二烯丙基官能团单体 选自聚醚二醇双（烯丙基碳酸酯），聚内酯二醇二（碳酸烯丙酯）及其混合物的单体。 第二烯丙基官能单体存在于组合物中，其量提供基本上完全固化的聚合物，其具有：（i）相对于不含单体（b）的组合物的基本上完全固化的聚合物改进的有机光致变色物质的掺入; 和（ii）至少40℃的热变形温度
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8.发明授权Thermosetting film-forming compositions that produce atrane-containing cured coatings 有权制备含淀粉固化涂层的热固性成膜组合物公开(公告)号：US08742012B2
公开(公告)日：2014-06-03
申请号：US13277601
申请日：2011-10-20
申请人： Michael Zalich , Susan Donaldson , Gregory J. McCollum , Randy E. Daughenbaugh , Kurt G. Olson , Nathan J. Silvernail
发明人： Michael Zalich , Susan Donaldson , Gregory J. McCollum , Randy E. Daughenbaugh , Kurt G. Olson , Nathan J. Silvernail
IPC分类号： C08L83/00 , C09D143/04 , C09D163/00 , C09D7/12
CPC分类号： C09D133/14
摘要： The invention includes a thermosetting film-forming composition comprising a polytrialkanolamine reacted with a crosslinking agent composition. The composition forms a three-dimensional crosslinked network having atrane-containing linkages.
摘要翻译： 本发明包括含有与交联剂组合物反应的聚三链烷醇胺的热固性成膜组合物。 该组合物形成具有含起源的键的三维交联网络。
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9.发明申请THERMOSETTING FILM-FORMING COMPOSITIONS THAT PRODUCE ATRANE-CONTAINING CURED COATINGS 有权生产含ATRANE固化涂料的热成膜成型组合物公开(公告)号：US20120101189A1
公开(公告)日：2012-04-26
申请号：US13277601
申请日：2011-10-20
申请人： Michael Zalich , Susan Donaldson , Gregory J. McCollum , Randy E. Daughenbaugh , Kurt G. Olson , Nathan J. Silvernail
发明人： Michael Zalich , Susan Donaldson , Gregory J. McCollum , Randy E. Daughenbaugh , Kurt G. Olson , Nathan J. Silvernail
IPC分类号： C09D163/00 , C09D133/14 , C09D7/12 , C09D143/04
CPC分类号： C09D133/14
摘要： The invention includes a thermosetting film-forming composition comprising a polytrialkanolamine reacted with a crosslinking agent composition. The composition forms a three-dimensional crosslinked network having atrane-containing linkages.
摘要翻译： 本发明包括含有与交联剂组合物反应的聚三链烷醇胺的热固性成膜组合物。 该组合物形成具有含起源的键的三维交联网络。
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