Process and aqueous compositions for treating metal surfaces
    1.
    发明授权
    Process and aqueous compositions for treating metal surfaces 失效
    用于处理金属表面的方法和含水组合物

    公开(公告)号:US4761189A

    公开(公告)日:1988-08-02

    申请号:US53598

    申请日:1987-05-20

    摘要: The invention relates to a process for treating metal surfaces, preferably of aluminum, aluminum alloys and steel, for the subsequent application of organic coating compositions. The metal surfaces are wetted with an aqueous bath solution containing chromium(III)ions, fluoride ions and an organic film former which is soluble or homogeneously dispersible in water, after which the solution applied is dried and converted by heating into a water-insoluble film.The bath solution preferably contains the following constituents and approximate quantities thereof: 0.5 to 10 g/l of chromium(III)ions, 0.55 to 11 g/l of fluoride ions, 0.6 to 12.5 g/l of phosphate ions, and 0.15 to 5.0 g/l of organic film former. The organic film former preferably used is a polymer containing free carboxyl groups, more preferably a homopolymer and/or copolymer of acrylic and/or methacrylic acid.

    摘要翻译: 本发明涉及用于处理金属表面,优选铝,铝合金和钢的方法,用于随后应用有机涂料组合物。 金属表面用含有铬(III)离子,氟离子和可溶于或均匀分散在水中的有机成膜剂的含水浴溶液润湿,之后将所施加的溶液干燥并通过加热转化成水不溶性膜 。 浴溶液优选包含以下成分及其近似量:0.5至10g / l的铬(III)离子,0.55至11g / l的氟离子,0.6至12.5g / l的磷酸根离子和0.15至5.0 g / l有机成膜剂。 优选使用的有机成膜剂是含有游离羧基的聚合物,更优选丙烯酸和/或甲基丙烯酸的均聚物和/或共聚物。

    Phosphating process for zinc-plated metals
    4.
    发明授权
    Phosphating process for zinc-plated metals 失效
    镀锌金属的磷化工艺

    公开(公告)号:US4497668A

    公开(公告)日:1985-02-05

    申请号:US554879

    申请日:1983-11-25

    IPC分类号: C23C22/12 C23C22/13 C23F7/08

    CPC分类号: C23C22/13 C23C22/12

    摘要: A process for phosphating zinc-plated metal articles, particularly electrolytically zinc-plated steel sheets, by treatment thereof for a short period with an acidic phosphating solution which, in addition to zinc and phosphate ions, can contain other metal cations and/or anions of oxygen-containing acids having an accelerating effect, wherein the phosphating solution has a content of Zn.sup.2+ -cations of between about 1 and 2.5 g/l, a free acid content in the range from 0.8 to 3 points, and the acid ratio of total acid to free acid in the range from 5 to 10. The phosphating treatment is carried out for a period of time not in excess of about 5 seconds.

    摘要翻译: 一种通过用酸性磷酸盐溶液处理短时间的镀锌金属制品,特别是电解镀锌钢板的方法,除了锌和磷酸根离子之外,还可以含有其它金属阳离子和/或阴离子 具有促进作用的含氧酸,其中磷酸盐化合物的Zn 2+离子含量在约1至2.5g / l之间,游离酸含量在0.8至3个点之间,而酸的酸的比例 游离酸在5至10的范围内。磷化处理进行不超过约5秒的时间。

    Chromium-free process for the no-rinse treatment of aluminum and its
alloys and aqueous bath solutions suitable for this process
    5.
    发明授权
    Chromium-free process for the no-rinse treatment of aluminum and its alloys and aqueous bath solutions suitable for this process 失效
    用于不冲洗处理铝及其合金和适用于该工艺的水浴溶液的无铬工艺

    公开(公告)号:US5868872A

    公开(公告)日:1999-02-09

    申请号:US722261

    申请日:1996-10-25

    IPC分类号: C23C22/36 C23C22/48

    CPC分类号: C23C22/361

    摘要: Described is a process using a no-rinse technique for the production of a chromium-free conversion layer on the surface of aluminum and its alloys by treating with an aqueous solution having a pH between 1 and 3.5 and containing titanium and/or zirconium plus an organic film-forming agent. The process is characterized in that the surface is brought into contact with a solution containing a) 2.2 to 22.0 g/l of Zr(IV) and/or 1.4 to 14.0 g/l of Ti(IV), b) 2.4 to 24.0 g/l of orthophosphate, c) 3.0 to 30.0 g/l of fluoride, d) 0.15 to 1.5 g/l of a water-soluble or homogeneously water-dispersible organic film former and, after a contact time between 1 and 40 seconds, the wet surface is allowed to dry, without rinsing, at a temperature between 50.degree. and 125.degree. C. Also described are aqueous concentrates for use in the process.

    摘要翻译: PCT No.PCT / EP95 / 01197 Sec。 371日期1996年10月25日第 102(e)日期1996年10月25日PCT 1995年3月31日PCT PCT。 WO95 / 27807 PCT出版物 日期1995年10月19日描述了一种使用无冲洗技术在铝及其合金的表面上生产无铬转化层的方法,其通过用pH为1至3.5的水溶液处理并含有钛和 /或锆加有机成膜剂。 该方法的特征在于使表面与含有a)2.2〜22.0g / l的Zr(IV)和/或1.4〜14.0g / l的Ti(IV)的溶液接触,b)2.4〜24.0g / l的正磷酸盐,c)3.0〜30.0g / l的氟化物,d)0.15〜1.5g / l的水溶性或均匀的水分散性有机成膜剂,并且在1〜40秒的接触时间后, 在50至125℃的温度下,将湿表面干燥,无需漂洗。还描述了用于该方法的含水浓缩物。

    Process for phosphating metallic surfaces
    6.
    发明授权
    Process for phosphating metallic surfaces 失效
    金属表面磷化处理

    公开(公告)号:US5401381A

    公开(公告)日:1995-03-28

    申请号:US129163

    申请日:1993-10-06

    IPC分类号: C25D11/36

    CPC分类号: C25D11/36

    摘要: A process is disclosed for phosphating metallic surfaces, particularly electrolytically or hot dipped galvanized steel strip surfaces, by dip or spray processing the metallic surfaces with acidic aqueous phosphating solutions, wherein the workpieces are cathodically treated at the same time with a direct current. The process is characterized by (a) the use of phosphating solutions that contain the following components: Zn.sup.+2 cations in a range from 0.1 to 5 g/l; PO.sub.4.sup.-3 anions in a range from 5 to 50 g/l; NO.sub.3.sup.- anions in a range from 0.1 to 50 g/l; as well as Ni.sup.+2 cations in a range from 0.1 to 5 g/l and/or Co.sup.+2 cations in a range from 0.1 to 5 g/l; (b) the observance of the following conditions: pH value of the phosphating solutions in a range from 1.5 to 4.5; temperature of the phosphating solutions in a range from 10.degree. to 80.degree. C.; duration of treatment in a range from 1 to 300 sec, (c) simultaneous cathodic treatment of the workpiece during phosphating with a direct current having a density in the range from 0.01 to 100 mA/cm.sup.2.

    摘要翻译: PCT No.PCT / EP92 / 00703 Sec。 371日期:1993年10月6日 102(e)日期1993年10月6日PCT 1991年3月30日PCT公布。 出版物WO92 / 17628 PCT 公开了一种用于磷酸化金属表面,特别是电解或热浸镀锌钢带表面的方法,通过用酸性磷酸盐水溶液浸渍或喷涂处理金属表面,其中工件同时进行阴极处理 用直流电。 该方法的特征在于:(a)使用含有以下组分的磷酸盐溶液:Zn + 2阳离子在0.1至5g / l的范围内; PO4-3阴离子的范围为5〜50g / l; NO3-阴离子在0.1至50g / l的范围内; 以及0.1-5g / l范围内的Ni + 2阳离子和0.1-5g / l范围内的/或Co +2阳离子; (b)遵守以下条件:磷酸盐溶液的pH值在1.5至4.5的范围内; 磷酸盐溶液的温度在10℃至80℃的范围内。 处理持续时间在1至300秒的范围内,(c)在磷酸盐化期间以0.01至100mA / cm 2的密度范围内的直流电同时对工件进行阴极处理。