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公开(公告)号：US06630062B1
公开(公告)日：2003-10-07
申请号：US09631911
申请日：2000-08-04
IPC分类号： G01N27407
CPC分类号： G01N27/4077
摘要： The poison resistant sensor comprises a sensing electrode (4) having a first and second side; a reference electrode (7) having a first and second side; an electrolyte (1) disposed between and in intimate contact with the first side of the sensing electrode and the first side of the reference electrode; a first side of a protective layer (3) disposed adjacent to the second side of the sensing electrode; and a protective coating (17), comprising alpha alumina and gamma alumina, disposed in physical contact with the second side of the protective layer.
摘要翻译： 耐药传感器包括具有第一和第二侧的感测电极（4） 具有第一和第二侧的参考电极（7）; 电解质（1），其设置在所述感测电极的第一侧和所述参考电极的第一侧之间并与之紧密接触; 与感测电极的第二侧相邻设置的保护层（3）的第一侧; 以及与所述保护层的第二侧物理接触地设置的包括α氧化铝和γ氧化铝的保护涂层（17）。
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公开(公告)号：US06514397B2
公开(公告)日：2003-02-04
申请号：US09747369
申请日：2000-12-21
申请人： William J. LaBarge , Darrell H. Eldridge , Paul Casey Kikuchi , Richard Eugene Fouts , Richard Frederick Beckmeyer
发明人： William J. LaBarge , Darrell H. Eldridge , Paul Casey Kikuchi , Richard Eugene Fouts , Richard Frederick Beckmeyer
IPC分类号： G01N27407
CPC分类号： G01N27/4073
摘要： An exhaust gas sensor includes a first electrode, a second electrode, and an electrolyte disposed between the first electrode and the second electrode. The electrolyte includes a first portion disposed at least in partial physical contact and in ionic communication with a second portion. The first portion has a first portion grain size which is different than a second portion grain size. Further, a method for manufacturing a gas sensor includes forming a multiple portion electrolyte. The electrolyte is formed with a first portion having one grain size, and a second portion at least in partial physical contact and in ionic contact with the first portion, the second portion having a second portion grain size different from the first portion grain size. The electrolyte may be fired before or after application of an electrode in ionic contact with the first portion and a second electrode in ionic contact with said second portion.
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公开(公告)号：US06320317B1
公开(公告)日：2001-11-20
申请号：US09451782
申请日：1999-12-01
IPC分类号： H01J1346
摘要： A resistor seal composition useful in resistor spark plugs, comprises glass, at least one metal oxide, at least one filler material, and a branched or straight chained zirconium carboxylate. The glass comprises a strontium borate glass and/or a borosilicate glass. Metal oxides include aluminum oxide, zinc oxide, and zirconium oxide. Filler materials include silicon dioxide and mullite.
摘要翻译： 可用于电阻火花塞的电阻器密封组合物包括玻璃，至少一种金属氧化物，至少一种填料和支链或直链状的羧酸锆。 玻璃包括硼酸锶玻璃和/或硼硅酸盐玻璃。 金属氧化物包括氧化铝，氧化锌和氧化锆。 填充材料包括二氧化硅和莫来石。
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4.发明授权Method of associating precious metals with specific oxides in mixed oxide systems for use as catalysts 失效将贵金属与混合氧化物体系中的特定氧化物缔合作为催化剂的方法
公开(公告)号：US5753581A
公开(公告)日：1998-05-19
申请号：US579027
申请日：1995-12-18
CPC分类号： B01J37/0242 , B01J23/894
摘要： This invention provides a very low cost effective method to alter the association of precious metal catalysts with specific support oxides in mixed oxide systems. The invention includes two discoveries: 1) that the isoelectric points for the three normally-used gasoline catalyst components are significantly different and the surface charges present have significant magnitude to promote attraction and repulsion of ions or charged radicals; and 2) ammine-chloride or ammine-nitrate salts both dissociate into positively charged precious metal radicals and are stable over a very wide pH range. The pH of the impregnation solution is controlled such that the surface charge of the oxide is opposite to the charge on the precious metal radical if the metal is to be supported on that oxide, and to control the pH such that all charges on the oxide to be avoided are the same as the precious metal radical.
摘要翻译： 本发明提供了一种非常低成本有效的方法来改变贵金属催化剂与混合氧化物体系中特定载体氧化物的缔合。 本发明包括两个发现：1）三种常用汽油催化剂组分的等电点显着不同，并且存在的表面电荷具有显着的量级，以促进离子或带电基团的吸引和排斥; 和2）氨氯化铵或氨 - 硝酸盐都解离成带正电荷的贵金属自由基，并且在非常宽的pH范围内是稳定的。 控制浸渍溶液的pH，使得如果要将金属负载在该氧化物上，氧化物的表面电荷与贵金属自由基上的电荷相反，并且控制pH使得氧化物上的所有电荷 避免与贵重金属激进相同。
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5.发明授权Method of making a ceramic catalytic converter open cell substrate with rounded corners 失效制造具有圆角的陶瓷催化转化器开孔电池基板的方法
公开(公告)号：US5731562A
公开(公告)日：1998-03-24
申请号：US781306
申请日：1997-01-13
CPC分类号： B01D53/9454 , B01D53/885 , B01J35/04 , B01J37/0009 , B28B3/269 , F01N3/2828 , Y02T10/22 , Y10T428/24165
摘要： A ceramic catalytic converter is made by first creating an electrode by cutting space apart holes through an electrode block, threading an electrode wire through each hole in the block and performing wire cutting electrical discharge machining to form a cutting surface with a plurality of cell walls converging at rounded corners. The electrode is used to cut an extrusion die, a feedhole is provided in the die (preferably connected to a corner of the cell), and ceramic material is extruded through the extrusion die to form an extruded substrate having a plurality of open cells defined by adjacent walls converging in a rounded corner to form the ceramic catalytic converter. The rounded corner cell walls allows a more uniform deposit of washcoat and precious metals and reduces the amount of precious metals necessary in the ceramic catalytic converter.
摘要翻译： 陶瓷催化转化器通过首先通过电极块切割空间分隔孔来产生电极，将电极丝穿过块中的每个孔，并进行线切割放电加工以形成具有会聚的多个电池壁的切割表面 在圆角。 该电极用于切割挤出模具，在模具中提供进料孔（优选连接到电池的角部），并且陶瓷材料通过挤出模头挤出以形成挤出的基材，该基材具有由 相邻的壁会聚在圆角处以形成陶瓷催化转化器。 圆角的圆角壁允许更均匀地沉积修补基面涂层和贵金属，并减少陶瓷催化转化器中所需的贵金属的量。
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公开(公告)号：US5714228A
公开(公告)日：1998-02-03
申请号：US573778
申请日：1995-12-18
CPC分类号： B01D53/9454 , B01D53/885 , B01J35/04 , B01J37/0009 , B28B3/269 , F01N3/2828 , Y02T10/22 , Y10T428/24165
摘要： The invention includes a ceramic catalytic converter substrate having cell walls with rounded corners. The cell walls have a honeycomb or hexagonal shape with rounded corners. The cell walls may be manufactured with very thin walls from 0.003-0.005 inches. There is provided increased structural strength of the substrate due to rounded corners of cell walls into honeycomb or hexagonal shaped walls. The rounded corners of the cell walls also substantially increases the strength of the substrate. The honeycomb shape of the substrate uniformly dissipates any force applied to the substrate. The rounded corner cell walls allows a more uniform deposit of washcoat and precious metals and reduces the amount of precious metals necessary which coat the substrate along with reducing additional backpressure of the exhaust system caused by the washcoat which normally forms fillets in corners of squared-celled substrates.
摘要翻译： 本发明包括具有圆角的孔壁的陶瓷催化转化器基板。 细胞壁具有带圆角的蜂窝状或六边形形状。 细胞壁可以用0.003-0.005英寸的非常薄的壁制造。 由于细胞壁的圆角变成蜂窝状或六边形的壁，提供了增加的基底的结构强度。 细胞壁的圆角也基本上增加了基底的强度。 基板的蜂窝形状均匀地散发施加到基板的任何力。 圆形的角细胞壁允许更均匀地沉积修补基面涂层和贵金属，并减少涂覆基底所需的贵金属的量，同时减少由洗涂层引起的排气系统的额外背压，其通常在平方边角形成圆角 底物。
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