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公开(公告)号：US20140200359A1
公开(公告)日：2014-07-17
申请号：US14161822
申请日：2014-01-23
申请人： Richard G. Blair
发明人： Richard G. Blair
IPC分类号： C07C45/32 , C07C51/373
CPC分类号： C07C45/32 , C07C45/27 , C07C51/373 , C11C3/006 , C07C47/54 , C07C47/02 , C07C59/147 , C07C59/153 , C07C47/21
摘要： Provided are processes for the oxidative cleavage of a double bond in an unsaturated carboxylic acid. The process includes contacting the unsaturated carboxylic acid with a mild oxidizing agent and agitating the unsaturated carboxylic acid and the mild oxidizing agent for a time sufficient to cleave a double bond of the unsaturated carboxylic acid and produce a product comprising an aldehyde. The process is typically carried out in a mill, such as a ball, hammer, attrition, or jet mill.
摘要翻译： 提供了在不饱和羧酸中双键氧化裂解的方法。 该方法包括使不饱和羧酸与温和的氧化剂接触，并搅拌不饱和羧酸和温和的氧化剂一段足以裂解不饱和羧酸的双键并产生包含醛的产物的时间。 该方法通常在诸如球，锤，磨耗或喷射磨的研磨机中进行。
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公开(公告)号：US20130330477A1
公开(公告)日：2013-12-12
申请号：US13882326
申请日：2011-10-28
申请人： Richard G. Blair
发明人： Richard G. Blair
IPC分类号： C01B31/04
CPC分类号： D06M11/74 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/182 , C01B32/184 , C01B32/192 , C01B32/23 , C09D1/00 , C09D5/24 , D01F8/18 , D01F9/14 , D01F9/16 , D01F9/21 , D06M2101/40
摘要： A mechanochemical oxidation process that allows relatively benign oxidizers to be used for the production of at least partially oxidized graphite, and a method of preparing a carbon fiber using oxidized graphite and a fiber component. Partially oxidized graphite is fully dispersible in water and can be used to prepare thin films with conductivities rivaling pure graphite. This offers the potential for improved electronic displays, solar cells, and lithium ion batteries. A carbon nanotube and a method of making the same is also provided.
摘要翻译： 允许相对良性氧化剂用于生产至少部分氧化的石墨的机械化学氧化方法，以及使用氧化石墨和纤维成分制备碳纤维的方法。 部分氧化石墨完全分散在水中，可用于制备与纯石墨相当的导电性的薄膜。 这提供了改进的电子显示器，太阳能电池和锂离子电池的潜力。 还提供了一种碳纳米管及其制造方法。
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公开(公告)号：US20100113764A1
公开(公告)日：2010-05-06
申请号：US12621741
申请日：2009-11-19
IPC分类号： C12P19/04
摘要： Provided are methods for the solubilization of cellulose into soluble sugars without the need for high temperatures, high pressures, strong acid solutions, and/or added water. The produced sugars can be fermented into ethanol. In one embodiment, the method comprises contacting a cellulose-containing material with a solid acid material and agitating the cellulose-containing material and the solid acid material for a time sufficient to produce an aqueous solution comprising a quantity of soluble sugars.
摘要翻译： 提供了将纤维素溶解在可溶性糖中的方法，而不需要高温，高压，强酸溶液和/或添加的水。 产生的糖可以发酵成乙醇。 在一个实施方案中，该方法包括使含纤维素材料与固体酸性材料接触并搅拌含纤维素材料和固体酸性材料足以产生包含一定量可溶性糖的水溶液的时间。
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公开(公告)号：US09114999B2
公开(公告)日：2015-08-25
申请号：US13882326
申请日：2011-10-28
申请人： Richard G. Blair
发明人： Richard G. Blair
CPC分类号： D06M11/74 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/182 , C01B32/184 , C01B32/192 , C01B32/23 , C09D1/00 , C09D5/24 , D01F8/18 , D01F9/14 , D01F9/16 , D01F9/21 , D06M2101/40
摘要： A mechanochemical oxidation process that allows relatively benign oxidizers to be used for the production of at least partially oxidized graphite, and a method of preparing a carbon fiber using oxidized graphite and a fiber component. Partially oxidized graphite is fully dispersible in water and can be used to prepare thin films with conductivities rivaling pure graphite. This offers the potential for improved electronic displays, solar cells, and lithium ion batteries. A carbon nanotube and a method of making the same is also provided.
摘要翻译： 允许相对良性氧化剂用于生产至少部分氧化的石墨的机械化学氧化方法，以及使用氧化石墨和纤维成分制备碳纤维的方法。 部分氧化石墨完全分散在水中，可用于制备与纯石墨相当的导电性的薄膜。 这提供了改进的电子显示器，太阳能电池和锂离子电池的潜力。 还提供了一种碳纳米管及其制造方法。
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公开(公告)号：US08969603B2
公开(公告)日：2015-03-03
申请号：US14161822
申请日：2014-01-23
申请人： Richard G. Blair
发明人： Richard G. Blair
IPC分类号： C07C45/27 , C07C51/16 , C07C45/32 , C07C51/373 , C11C3/00
CPC分类号： C07C45/32 , C07C45/27 , C07C51/373 , C11C3/006 , C07C47/54 , C07C47/02 , C07C59/147 , C07C59/153 , C07C47/21
摘要： Provided are processes for the oxidative cleavage of a double bond in an unsaturated carboxylic acid. The process includes contacting the unsaturated carboxylic acid with a mild oxidizing agent and agitating the unsaturated carboxylic acid and the mild oxidizing agent for a time sufficient to cleave a double bond of the unsaturated carboxylic acid and produce a product comprising an aldehyde. The process is typically carried out in a mill, such as a ball, hammer, attrition, or jet mill.
摘要翻译： 提供了在不饱和羧酸中双键氧化裂解的方法。 该方法包括使不饱和羧酸与温和的氧化剂接触，并搅拌不饱和羧酸和温和的氧化剂一段足以裂解不饱和羧酸的双键并产生包含醛的产物的时间。 该方法通常在诸如球，锤，磨耗或喷射磨的研磨机中进行。
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公开(公告)号：US08871739B2
公开(公告)日：2014-10-28
申请号：US12621741
申请日：2009-11-19
IPC分类号： C12P19/12 , C07H3/04 , C07H3/02 , A61K31/7016 , A61K31/70
摘要： Provided are methods for the solubilization of cellulose into soluble sugars without the need for high temperatures, high pressures, strong acid solutions, and/or added water. The produced sugars can be fermented into ethanol. In one embodiment, the method comprises contacting a cellulose-containing material with a solid acid material and agitating the cellulose-containing material and the solid acid material for a time sufficient to produce an aqueous solution comprising a quantity of soluble sugars.
摘要翻译： 提供了将纤维素溶解在可溶性糖中的方法，而不需要高温，高压，强酸溶液和/或加入的水。 产生的糖可以发酵成乙醇。 在一个实施方案中，该方法包括使含纤维素材料与固体酸性材料接触并搅拌含纤维素材料和固体酸性材料足以产生包含一定量可溶性糖的水溶液的时间。
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公开(公告)号：US08669385B2
公开(公告)日：2014-03-11
申请号：US13501666
申请日：2010-10-12
申请人： Richard G. Blair
发明人： Richard G. Blair
IPC分类号： C07C51/16
CPC分类号： C07C51/373 , B01J8/10 , B01J8/16 , B01J2219/182 , B01J2219/1946 , C07C45/36 , C07C47/02 , C07C47/54 , C07C47/21 , C07C59/74 , C07C59/147 , C07C59/153
摘要： Provided are processes for the oxidative cleavage of a double bond in an unsaturated carboxylic acid. The process includes contacting the unsaturated carboxylic acid with a mild oxidizing agent and agitating the unsaturated carboxylic acid and the mild oxidizing agent for a time sufficient to cleave a double bond of the unsaturated carboxylic acid and produce a product comprising an aldehyde. The process is typically carried out in a mill, such as a ball, hammer, attrition, or jet mill.
摘要翻译： 提供了在不饱和羧酸中双键氧化裂解的方法。 该方法包括使不饱和羧酸与温和的氧化剂接触，并搅拌不饱和羧酸和温和的氧化剂一段足以裂解不饱和羧酸的双键并产生包含醛的产物的时间。 该方法通常在诸如球，锤，磨耗或喷射磨的研磨机中进行。
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公开(公告)号：US20120264956A1
公开(公告)日：2012-10-18
申请号：US13501666
申请日：2010-10-12
申请人： Richard G. Blair
发明人： Richard G. Blair
IPC分类号： C07C51/373 , C07C59/74 , C07C59/147
CPC分类号： C07C51/373 , B01J8/10 , B01J8/16 , B01J2219/182 , B01J2219/1946 , C07C45/36 , C07C47/02 , C07C47/54 , C07C47/21 , C07C59/74 , C07C59/147 , C07C59/153
摘要： Provided are processes for the oxidative cleavage of a double bond in an unsaturated carboxylic acid. The process includes contacting the unsaturated carboxylic acid with a mild oxidizing agent and agitating the unsaturated carboxylic acid and the mild oxidizing agent for a time sufficient to cleave a double bond of the unsaturated carboxylic acid and produce a product comprising an aldehyde. The process is typically carried out in a mill, such as a ball, hammer, attrition, or jet mill.
摘要翻译： 提供了在不饱和羧酸中双键氧化裂解的方法。 该方法包括使不饱和羧酸与温和的氧化剂接触，并搅拌不饱和羧酸和温和的氧化剂一段足以裂解不饱和羧酸的双键并产生包含醛的产物的时间。 该方法通常在诸如球，锤，磨耗或喷射磨的研磨机中进行。
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公开(公告)号：US08062428B2
公开(公告)日：2011-11-22
申请号：US11935712
申请日：2007-11-06
IPC分类号： C13K1/02
CPC分类号： C07H1/06
摘要： Provided are methods for the solubilization of cellulose into soluble sugars without the need for high temperatures, high pressures, strong acid solutions, and/or added water. The produced sugars can be fermented into ethanol. In one embodiment, the method comprises contacting a cellulose-containing material with a solid acid material and agitating the cellulose-containing material and the solid acid material for a time sufficient to produce an aqueous solution comprising a quantity of soluble sugars.
摘要翻译： 提供了将纤维素溶解在可溶性糖中的方法，而不需要高温，高压，强酸溶液和/或加入的水。 产生的糖可以发酵成乙醇。 在一个实施方案中，该方法包括使含纤维素材料与固体酸性材料接触并搅拌含纤维素材料和固体酸性材料足以产生包含一定量可溶性糖的水溶液的时间。
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公开(公告)号：US20160017537A1
公开(公告)日：2016-01-21
申请号：US14805580
申请日：2015-07-22
申请人： Richard G. Blair
发明人： Richard G. Blair
CPC分类号： D06M11/74 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/182 , C01B32/184 , C01B32/192 , C01B32/23 , C09D1/00 , C09D5/24 , D01F8/18 , D01F9/14 , D01F9/16 , D01F9/21 , D06M2101/40
摘要： A mechanochemical oxidation process that allows relatively benign oxidizers to be used for the production of at least partially oxidized graphite, and a method of preparing a carbon fiber using oxidized graphite and a fiber component. Partially oxidized graphite is fully dispersible in water and can be used to prepare thin films with conductivities rivaling pure graphite. This offers the potential for improved electronic displays, solar cells, and lithium ion batteries. A carbon nanotube and a method of making the same is also provided.
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