公开(公告)号：US07378564B2

公开(公告)日：2008-05-27

申请号：US10502845

申请日：2003-01-22

申请人： Jean-Marie Basset ,  Christophe Coperet ,  Richard Pardy ,  Daravong Soulivong ,  John Glenn Sunley ,  Jean Thivolle-Cazat

发明人： Jean-Marie Basset ,  Christophe Coperet ,  Richard Pardy ,  Daravong Soulivong ,  John Glenn Sunley ,  Jean Thivolle-Cazat

IPC分类号： C07C6/08

CPC分类号： C07C6/10 ,  B01J21/08 ,  B01J31/121 ,  B01J37/0209 ,  C07C2531/12 ,  Y10S585/943

摘要： The present invention relates to a process for the manufacture of alkanes comprising a catalytic reaction resulting from contacting methane with at least one other starting alkane (I) in the presence of a metal compound (C) capable of catalysing a reaction for the splitting and/or recombination of a carbon-carbon bond and/or of a carbon-hydrogen bond and/or of a carbon-metal bond, which catalytic reaction results in the formation of at least one final alkane (II) having a number of carbon atoms equal to or greater than (2). In the process, the contacting operation is carried out under a methane partial pressure equal to or greater than 0.1 MPa, preferably in the range from 0.1 to 100 MPa. The metal compound (C) can be chosen from metal compounds supported on and dispersed over a solid support, metal compounds supported on and grafted to a solid support and non-supported metal compounds. Under these conditions, it was found that the yield of the catalytic reaction was improved, and that the catalytic stability and activity of the metal compound (C) over timer were greatly enhanced.

摘要翻译： 本发明涉及一种制备烷烃的方法，其包括由甲烷与至少一种其它起始烷烃（I）在能够催化分解和/或反应的反应的金属化合物（C）存在下使甲烷接触而产生的催化反应， 或碳 - 碳键和/或碳 - 氢键和/或碳 - 金属键的重组，该催化反应导致至少一个具有多个碳原子的最终烷烃（II）的形成相等 至（2）以上。 在该过程中，接触操作在等于或大于0.1MPa，优选在0.1至100MPa范围内的甲烷分压下进行。 金属化合物（C）可以选自负载在固体载体上并分散在固体载体上的金属化合物，负载在和接枝到固体载体上的金属化合物和非负载的金属化合物。 在这些条件下，发现催化反应的产率提高，金属化合物（C）超过定时器的催化稳定性和活性大大提高。

公开(公告)号：US20050014987A1

公开(公告)日：2005-01-20

申请号：US10502845

申请日：2003-01-22

申请人： Jean-Marie Basset ,  Christophe Coperet ,  Richard Pardy ,  Daravong Soulivong ,  John Sunley ,  Jean Thivolle-Cazat

发明人： Jean-Marie Basset ,  Christophe Coperet ,  Richard Pardy ,  Daravong Soulivong ,  John Sunley ,  Jean Thivolle-Cazat

IPC分类号： B01J21/08 ,  B01J31/12 ,  B01J37/02 ,  C07C6/10 ,  C07C6/08

CPC分类号： C07C6/10 ,  B01J21/08 ,  B01J31/121 ,  B01J37/0209 ,  C07C2531/12 ,  Y10S585/943

摘要： The present invention relates to a process for the manufacture of alkanes comprising a catalytic reaction resulting from contacting methane with at least one other starting alkane (I) in the presence of a metal compound (C) capable of catalysing a reaction for the splitting and/or recombination of a carbon-carbon bond and/or of a carbon-hydrogen bond and/or of a carbon-metal bond, which catalytic reaction results in the formation of at least one final alkane (II) having a number of carbon atoms equal to or greater than (2). In the process, the contacting operation is carried out under a methane partial pressure equal to or greater than 0.1 MPa, preferably in the range from 0.1 to 100 MPa. The metal compound (C) can be chosen from metal compounds supported on and dispersed over a solid support, metal compounds supported on and grafted to a solid support and non-supported metal compounds. Under these conditions, it was found that the yield of the catalytic reaction was improved, ant that the catalytic stability and activity of the metal compound (C) over timer were greatly enhanced.

摘要翻译： 本发明涉及一种制备烷烃的方法，其包括由甲烷与至少一种其它起始烷烃（I）在能够催化分解和/或反应的反应的金属化合物（C）存在下使甲烷接触而产生的催化反应， 或碳 - 碳键和/或碳 - 氢键和/或碳 - 金属键的重组，该催化反应导致至少一个具有多个碳原子的最终烷烃（II）的形成相等 至（2）以上。 在该过程中，接触操作在等于或大于0.1MPa，优选在0.1至100MPa范围内的甲烷分压下进行。 金属化合物（C）可以选自负载在固体载体上并分散在固体载体上的金属化合物，负载在和接枝到固体载体上的金属化合物和非负载的金属化合物。 在这些条件下，发现催化反应的产率提高，催化稳定性和金属化合物（C）与定时器的活性大大提高。