摘要:
The invention concerns a process for synthesising aluminas with a controlled porosity in which the pore diameter is in the range 0.6 nm to 80 nm. This process is carried out in a plurality of steps including at least one step a) in which an alumina precursor is prepared by hydrolysis of at least one anionic inorganic source of aluminium in the presence of at least one surfactant. Step a) of the process is carried out in an essentially aqueous medium the pH of which is generally higher than the isoelectric point of the alumina. The process of the invention also comprises at least one step b) in which the precipitate obtained is dried in air at a temperature of about 40° C. to 110° C. for a period of about 2 to 30 hours, and at least one step c) in which the dried precipitate is calcined at a temperature which is sufficient to eliminate the molecules of surfactant present in the precursor.
摘要:
Process of depositing nanoparticles of a metal or of an alloy of said metal, said metal being chosen from the metals from columns VIIIB and IB of the Periodic Table, dispersed on a substrate by chemical vapour deposition (CVD), from one or more precursors, in which the deposition is carried out in the presence of a gas comprising more than 50 vol % of a reactive oxidizing gas.Substrate comprising at least one surface, dispersed on which are nanoparticles made of a metal or of an alloy of metals, for example made of silver or a silver alloy.Use of the substrate to catalyse a chemical reaction, for example an NOx elimination reaction.
摘要:
Hydrated aluminium compounds of the present invention are represented by the general formula nS, mM, Al2O3, xH2O where S is a surfactant or a group of surfactants, n is the number of moles of S, M is an alkaline cation, preferably selected from the group formed by Na+, K+, NH4+, m is the number of moles of M and x is the number of moles of water. The hydrated compounds are obtained from inorganic aluminium sources which are in the form of cation-monomers and/or cation-oligomers. The surfactants are anionic and/or non-ionic surfactants. When the group of surfactants comprises at least one anionic surfactant, at least one cationic surfactant can optionally be added.
摘要:
Process of depositing nanoparticles of a metal or of an alloy of said metal, said metal being chosen from the metals from columns VIIIB and IB of the Periodic Table, dispersed on a substrate by chemical vapour deposition (CVD), from one or more precursors, in which the deposition is carried out in the presence of a gas comprising more than 50 vol % of a reactive oxidizing gas.Substrate comprising at least one surface, dispersed on which are nanoparticles made of a metal or of an alloy of metals, for example made of silver or a silver alloy.Use of the substrate to catalyse a chemical reaction, for example an NOx elimination reaction.
摘要翻译:沉积金属或所述金属的合金的纳米颗粒的工艺,所述金属选自由化学气相沉积(CVD)分散在基材上的来自一种或多种前体的元素周期表第VIIIB和IB栏的金属, 其中在包含大于50体积%的活性氧化气体的气体的存在下进行沉积。 包含至少一个表面的基板,其上分散有由金属或金属合金制成的纳米颗粒,例如由银或银合金制成。 使用底物来催化化学反应,例如NO x X消除反应。