公开(公告)号：US20060051872A1

公开(公告)日：2006-03-09

申请号：US10528967

申请日：2003-10-06

申请人： Michael Sailor ,  William Trogler ,  Honglae Sohm ,  Sarah Toal

发明人： Michael Sailor ,  William Trogler ,  Honglae Sohm ,  Sarah Toal

IPC分类号： C07F7/08 ,  C07F7/04 ,  G01N33/00

CPC分类号： C08G79/00 ,  C07F7/0896 ,  C07F7/30 ,  C08G77/60 ,  G01N21/643 ,  G01N33/0049 ,  G01N2021/6432 ,  G01N2021/7786

摘要： A dehydrocoupling polycondensation method for synthesizing polymetalloles including obtaining a dihydrometallole that includes silicon or germanium atoms, designating a reducing agent for preparation of dihydrometallole monomer, measuring a predetermined molar percentage of the reducing agent corresponding to a molar amount of the dihydrometallole, selecting a catalyst, and reacting the catalyst with the dihydrometallole to obtain a polymetallole. A method for detecting an analyte that may be present in ambient air or complex aqueous media including providing a polymer or copolymer containing a metalloid-metalloid backbone, exposing the polymer or copolymer to a suspected analyte or a system suspected of including the analyte, and measuring a quenching of photoluminescence of the metallole polymer or copolymer exposed to the system.

摘要翻译： 一种用于合成多元醇的脱氢缩合缩聚方法，包括获得包含硅或锗原子的二羟基醇，指定用于制备二羟基醇单体的还原剂，测量对应于二羟基醇的摩尔量的预定摩尔百分数的还原剂，选择催化剂， 并使催化剂与二水合醇反应以获得多元醇。 用于检测可能存在于环境空气或复合水性介质中的分析物的方法，包括提供含有准金属 - 准金属主链的聚合物或共聚物，将聚合物或共聚物暴露于可疑分析物或怀疑包含分析物的体系，并测量 暴露于体系的金属聚合物或共聚物的光致发光淬灭。