公开(公告)号：US3953521A

公开(公告)日：1976-04-27

申请号：US590930

申请日：1975-06-27

申请人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

发明人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

IPC分类号： C07C409/12 ,  C07C179/06

CPC分类号： C07C409/12 ,  C07C407/00 ,  C07C407/003

摘要： Meta-and/or paradiisopropylbenzene dihydroperoxides are continuously produced by oxidizing meta-and/or paradiisopropylbenzenes in liquid phase through contact with oxygen or a gas containing oxygen, while keeping the concentration of meta-and/or paradiisopropylbenzene monohydroperoxides of the oxidation product solution in a range of 20 to 40% by weight.

摘要翻译： 通过在与氧气或含氧气体接触的情况下液相氧化间位和/或对二异丙基苯，同时将氧化产物溶液的间 - 和/或对二甲基异丙基苯单氢过氧化物的浓度保持在一定范围内，从而连续制备元和/或对二异丙基苯二氢过氧化物 范围为20〜40重量％。

公开(公告)号：US3950431A

公开(公告)日：1976-04-13

申请号：US399248

申请日：1973-09-20

申请人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

发明人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

IPC分类号： C07C409/12 ,  B01D11/04 ,  C07C67/00 ,  C07C407/00 ,  C07C179/02

CPC分类号： C07C45/80 ,  B01D11/0488 ,  C07C407/00 ,  C07C407/003

摘要： Impurities, that is, by-products, in an oxidation product solution obtained by oxidation of diisopropylbenzene by molecular oxygen or in the oxidation product solution freed from diisopropylbenzene dihydroperoxide, are removed by extracting the by-products such as carbinols, ketones and styrenes from the solution with a mixture of an aqueous alkaline solution and at least one of alcohols having 1 to 3 carbon atoms such as methanol, ethanol, and isopropanol, as an extracting reagent at a temperature of 20.degree. to 80.degree.C.

摘要翻译： 通过用分子氧氧化二异丙基苯或通过从二异丙基苯二氢过氧化物中除去的氧化产物溶液获得的氧化产物溶液中的杂质，即副产物，通过从副产物溶液中提取副产物，例如甲醇，酮和苯乙烯 溶液与碱性水溶液和至少一种具有1至3个碳原子的醇的混合物如甲醇，乙醇和异丙醇作为萃取剂，在20至80℃的温度下进行。

公开(公告)号：US3932528A

公开(公告)日：1976-01-13

申请号：US391873

申请日：1973-08-27

申请人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

发明人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

IPC分类号： C07C409/12 ,  C07C67/00 ,  C07C407/00 ,  C07C179/02

CPC分类号： C07C407/006 ,  C07C407/003

摘要： Dihydroperoxides of dialkylaromatic hydrocarbons are separated in high yield from an aqueous alkaline solutions of hydroperoxides containing the dihydroperoxides by adding 0.01 to 1 % by weight of a compound having a nitrogen base, such as ammonia and aromatic amines, to the solution, based on the weight of the solution, thereby stabilizing the dihydroperoxides in the solution, and separating the dihydroperoxides therefrom by extraction.

摘要翻译： 基于重量，通过向溶液中加入0.01至1重量％的具有氮碱的化合物（例如氨和芳族胺），将二烷基芳烃的二氢​​过氧化物以高产率与含有二氢过氧化物的氢过氧化物的碱性水溶液分离。 的溶液，从而稳定溶液中的二氢过氧化物，并通过萃取从其中分离二氢过氧化物。

公开(公告)号：US3969420A

公开(公告)日：1976-07-13

申请号：US375920

申请日：1973-07-02

申请人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

发明人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

IPC分类号： C07C27/00 ,  C07C37/72 ,  C07C37/84 ,  C07C39/08 ,  C07C67/00 ,  C07C37/24

CPC分类号： C07C37/72 ,  C07C37/685 ,  C07C37/84

摘要： Resorcinol and hydroquinone are recovered in mixture at a high purity from a solution containing resorcinol and hydroquinone, especially, a solution resulting from cleavage of oxidation products of isopropylbenzene and successive distillation of the cleavage product thereby to remove lower and higher boiling components therefrom, by adding 0.5 to 20 parts by weight of at least one solvent selected from aromatic hydrocarbons, aromatic hydrocarbons having lower alkyl substituent groups, and aliphatic hydrocarbons having 7 to 10 carbon atoms to one part by weight of said solution, if necessary, together with 1 to 30% by weight of at least one compound selected from ketones having 3 to 10 carbon atoms, alcohols having 1 to 5 carbon atoms and aliphatic esters having 3 to 5 carbon atoms, based on the weight of the organic solvent, dissolving the solution into the organic solvent by heating, separating a mixture of resorcinol and hydroquinone as a solid phase from the organic solvent layer after slow cooling, and recovering the solid phase as a product. The resorcinol and hydroquinone in the organic solvent layer are further recovered through extraction with water. When water is used together with the organic solvent from the beginning of extraction, the resorcinol and hydrocarbon are obtained in an aqueous layer.

摘要翻译： 间苯二酚和氢醌以高纯度从含有间苯二酚和氢醌的溶液中回收，特别是从裂解异丙苯的氧化产物产生的溶液，并连续蒸馏裂解产物，从而通过加入从其中除去较低沸点和较高沸点的组分 0.5至20重量份的至少一种选自芳族烃，具有低级烷基取代基的芳族烃和具有7至10个碳原子的脂族烃的溶剂相对于所述溶液的1重量份，如果需要，连同1至30个 至少一种选自具有3至10个碳原子的化合物，具有1至5个碳原子的醇和3至5个碳原子的脂肪族酯的化合物，基于有机溶剂的重量，将该溶液溶解在有机溶剂中 溶剂，从有机溶剂层af分离作为固相的间苯二酚和氢醌的混合物 缓慢冷却，并回收作为产品的固相。 有机溶剂层中的间苯二酚和氢醌通过水提取进一步回收。 当水从开始开始与有机溶剂一起使用时，在水层中获得间苯二酚和烃。

公开(公告)号：US3933921A

公开(公告)日：1976-01-20

申请号：US370673

申请日：1973-06-18

申请人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

发明人： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

IPC分类号： C07C67/00 ,  C07C407/00 ,  C07C409/08 ,  C07C409/10 ,  C07C409/12 ,  C07C179/02 ,  C07C179/04

CPC分类号： C07C409/08 ,  C07C407/00 ,  C07C409/10 ,  C07C409/12

摘要： In a process for the production of hydroperoxides by the oxidation of an aromatic hydrocarbon having at least one tertiary carbon atom with oxygen or an oxygen containing gas in the presence of an aqueous alkaline solution, an improvement is made in that the oxidation is effected in an emulsion phase which is caused by powerfully mixing all or a part of the materials to be brought into the oxidation reaction only by the aid of the hydroperoxides formed in the reaction, whereby enhancing the reaction rate with safety.

摘要翻译： 在碱性水溶液存在下，通过氧化具有至少一个叔碳原子的芳族烃与含氧气体生产氢过氧化物的方法中，氧化是在 乳液相是仅通过在反应中形成的氢过氧化物的有力地混合要进入氧化反应的全部或一部分材料而引起的，从而以安全性提高反应速率。