公开(公告)号：USRE39127E1

公开(公告)日：2006-06-13

申请号：US10067191

申请日：2002-02-04

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hatori

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hatori

IPC分类号： A61K31/44 ,  A61K31/4439 ,  A61K31/506 ,  C07D401/06 ,  C07D417/06

CPC分类号： C07D401/06 ,  A01N47/40 ,  C07D277/28 ,  C07D403/06 ,  C07D413/06 ,  C07D417/06

摘要： Novel heterocyclic compounds of the formula wherein, R1 represents a hydrogen atom or an alkyl group, A represents an ethylene group which may be substituted by alkyl or a trimethylene group which may be substituted by alkyl, X represents an oxygen or sulfur atom or the group in which R2 represents a hydrogen atom of an optionally substituted alkyl, an alkenyl, an alkynyl or an acyl group, and R3 represents a hydrogen atom or an alkyl group, and Z represents an optionally sibstituted 5- or 6-membered heterocyclic group which contains at least two hetero atoms selected from oxygen, sulfur and nitrogen atoms, or an optionally substituted 3- or 4-pyridyl group. The above defined novel heterocyclic compounds of formula (I) exhibit powerful insecticidal properties.

摘要翻译： 下式的新型杂环化合物其中R 1表示氢原子或烷基，A表示可以被可被烷基取代的烷基或三亚甲基取代的亚乙基，X表示 氧或硫原子或其中R 2表示任选取代的烷基，烯基，炔基或酰基的氢原子的基团，R 3表示 氢原子或烷基，Z表示含有至少两个选自氧，硫和氮原子的杂原子的任选取代的5-或6-元杂环基，或任选取代的3-或4-吡啶基。 上述定义的式（I）新颖杂环化合物具有强大的杀虫性能。

公开(公告)号：US5472960A

公开(公告)日：1995-12-05

申请号：US291236

申请日：1994-08-16

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

IPC分类号： A01N43/90 ,  A01N47/12 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D498/04 ,  C07D513/04 ,  A01N33/18 ,  A01N43/86

CPC分类号： C07D471/04 ,  A01N43/90 ,  A01N47/18 ,  C07D487/04 ,  C07D513/04

摘要： Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic group containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.

摘要翻译： 式（I）的硝基取代的杂环化合物其中R是氢或烷基，Z是任选取代的芳基或含有至少一个选自N，O和S的原子的任选取代的杂环基，A是 任选取代的乙烯或任选取代的三亚甲基，B代表与相邻C原子和N-原子一起形成的杂环的2或3个成员，并且所述成员中的至少一个可以表示杂原子，并且可以是 任选取代，条件是当B代表3个成员时，其中两个是碳原子，另一个是位于三个成员中间的氮原子，则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。

公开(公告)号：US5366976A

公开(公告)日：1994-11-22

申请号：US126950

申请日：1993-09-27

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

IPC分类号： A01N43/90 ,  A01N47/12 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D498/04 ,  C07D513/04

CPC分类号： C07D471/04 ,  A01N43/90 ,  A01N47/18 ,  C07D487/04 ,  C07D513/04

摘要： Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic group containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.

摘要翻译： 式（I）的硝基取代的杂环化合物其中R是氢或烷基，Z是任选取代的芳基或含有至少一个选自N，O和S的原子的任选取代的杂环基，A是 任选取代的乙烯或任选取代的三亚甲基，B代表与相邻C原子和N-原子一起形成的杂环的2或3个成员，并且所述成员中的至少一个可以表示杂原子，并且可以是 任选取代，条件是当B代表3个成员时，其中两个是碳原子，另一个是位于三个成员中间的氮原子，则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。

公开(公告)号：US5288029A

公开(公告)日：1994-02-22

申请号：US785262

申请日：1991-10-30

申请人： Ichirou Ishibashi ,  Toshio Kubota ,  Niichi Toyama ,  Shoko Sasaki ,  Yukihito Ono ,  Akihiko Tada

发明人： Ichirou Ishibashi ,  Toshio Kubota ,  Niichi Toyama ,  Shoko Sasaki ,  Yukihito Ono ,  Akihiko Tada

IPC分类号： B05B5/16 ,  B05B12/14 ,  B05B5/02

CPC分类号： B05B5/1675 ,  B05B5/1625 ,  B05B12/14

摘要： An apparatus for electrostatically spray-coating a workpiece with conductive paint which includes a color changeover valve mechanism for selectively supplying conductive paint, cleaning liquid and air. A flush valve mechanism is provided for selectively supplying the cleaning liquid and the air. A first directional control valve includes an outlet and inlets. The inlets are connected to feed lines extending from the color changeover valve mechanism and the flush valve mechanism, respectively. A block line is made of an insulating material and has a first end connected to the outlet of the first directional control valve. The block line includes a second end in communication with the first end. A second directional control valve is provided having outlets and an inlet. The inlet is connected to the second end of the block line. An intermediate reservoir is connected via a feed line to one of outlets of the second directional control valve. A waste-liquid tank is connected via a first discharge line to a second outlet of the second directional control valve. A spray gun is connected via a delivery line to the intermediate reservoir. A second discharge line is branched from the delivery line via a changeover valve. A discharge line cleaning mechanism is provided for selectively supplying at least cleaning liquid and air to the second discharge line. A high voltage is applied to the conductive paint between the second directional control valve and the spray gun.

摘要翻译： 一种用导电涂料对工件进行静电喷涂的装置，其包括用于选择性地供应导电涂料，清洁液体和空气的颜色转换阀机构。 提供了一种冲洗阀机构，用于选择性地供应清洗液和空气。 第一方向控制阀包括出口和入口。 入口分别连接到从颜色切换阀机构和冲洗阀机构延伸的供给管线。 块线由绝缘材料制成，并且具有连接到第一方向控制阀的出口的第一端。 块线包括与第一端连通的第二端。 提供具有出口和入口的第二方向控制阀。 入口连接到块线的第二端。 中间储存器经由进料管线连接到第二方向控制阀的出口之一。 废液槽经由第一排出管线连接到第二方向控制阀的第二出口。 喷枪通过输送管线连接到中间储存器。 第二排出管线通过切换阀从输送管线分支。 提供排出线清洁机构，用于至少选择性地向第二排出管线提供清洗液和空气。 向第二方向控制阀和喷枪之间的导电涂料施加高电压。

公开(公告)号：US5231098A

公开(公告)日：1993-07-27

申请号：US823240

申请日：1992-01-21

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

IPC分类号： A01N43/90 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D498/04 ,  C07D513/04

CPC分类号： C07D471/04 ,  A01N43/90 ,  A01N47/18 ,  C07D487/04 ,  C07D513/04

摘要： Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl, Z is an optionally substituted aryl or optionally substituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.

摘要翻译： 硝基取代的式（I）的杂环化合物其中R是氢或烷基，Z是任选取代的芳基或含有至少一个选自N，O和S的原子的任选取代的杂环化合物，A是 任选取代的乙烯或任选取代的三亚甲基，B代表与相邻C原子和N-原子一起形成的杂环的2或3个成员，并且所述成员中的至少一个可以表示杂原子，并且可以是 任选取代，条件是当B代表3个成员时，其中两个是碳原子，另一个是位于三个成员中间的氮原子，则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。

公开(公告)号：US4960780A

公开(公告)日：1990-10-02

申请号：US353370

申请日：1989-05-17

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

IPC分类号： A01N43/90 ,  A01N47/12 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D498/04 ,  C07D513/04

CPC分类号： C07D471/04 ,  A01N43/90 ,  A01N47/18 ,  C07D487/04 ,  C07D513/04

摘要： Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.

公开(公告)号：US4876263A

公开(公告)日：1989-10-24

申请号：US208421

申请日：1988-06-17

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

IPC分类号： A01N43/90 ,  A01N47/12 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D498/04 ,  C07D513/04

CPC分类号： C07D471/04 ,  A01N43/90 ,  A01N47/18 ,  C07D487/04 ,  C07D513/04

摘要： Nitro-subsliluted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl, Z is an optionally substituted aryl or optionally subtituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-aom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.

摘要翻译： 硝基亚稀释的式（I）的杂环化合物其中R是氢或烷基，Z是任选取代的芳基或含有至少一个选自N，O和S的原子的任选取代的杂环化合物，A是 任选取代的乙烯或任选取代的三亚甲基，B代表杂环的2或3个成员，其与相邻的C原子和N-aom一起形成，并且所述成员中的至少一个可以表示杂原子，并且可以是 任选取代，条件是当B代表3个成员时，其中两个是碳原子，另一个是位于三个成员中间的氮原子，则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。

公开(公告)号：USRE39140E1

公开(公告)日：2006-06-20

申请号：US10067190

申请日：2002-02-04

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hatori

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hatori

IPC分类号： A61K31/44 ,  A61K31/4439 ,  C07D401/06 ,  C07D417/06

摘要： Novel heterocyclic compounds of the formula wherein, R1 represents a hydrogen atom or an alkyl group, A represents an ethylene group which may be substituted by alkyl or a trimethylene group which may be substituted by alkyl, X represents an oxygen or sulfur atom or the group in which R2 represents a hydrogen atom of an optionally substituted alkyl, an alkenyl, an alkynyl or an acyl group, and R3 represents a hydrogen atom or an alkyl group, and Z represents an optionally substituted 5- or 6-membered heterocyclic group which contains at least two hetero atoms selected from oxygen, sulfur and nitrogen atoms, or an optionally substituted 3- or 4-pyridyl group. The above defined novel heterocyclic compounds of formula (I) exhibit powerful insecticidal properties.

摘要翻译： 下式的新型杂环化合物其中R 1表示氢原子或烷基，A表示可以被可被烷基取代的烷基或三亚甲基取代的亚乙基，X表示 氧或硫原子或其中R 2表示任选取代的烷基，烯基，炔基或酰基的氢原子的基团，R 3表示 氢原子或烷基，Z表示含有至少两个选自氧，硫和氮原子的杂原子的任选取代的5元或6元杂环基，或任选取代的3-或4-吡啶基。 上述定义的式（I）新颖杂环化合物具有强大的杀虫性能。

公开(公告)号：USRE39130E1

公开(公告)日：2006-06-13

申请号：US08254202

申请日：1994-06-06

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hatori

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shinzo Kagabu ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hatori

IPC分类号： A61K31/44 ,  A61K31/4439 ,  C07D401/06 ,  C07D417/06

摘要： Novel heterocyclic compounds of the formula wherein, R1 represents a hydrogen atom or an alkyl group, A represents an ethylene group which may be substituted by alkyl or a trimethylene group which may be substituted by alkyl, X represents an oxygen or sulfur atom or the group in which R2 represents a hydrogen atom of an optionally substituted alkyl, an alkenyl, an alkynyl or an acyl group, and R3 represents a hydrogen atom or an alkyl group, and Z represents an optionally substituted 5- or 6-membered heterocyclic group which contains at least two hetero atoms selected from oxygen, sulfur and nitrogen atoms, or an optionally substituted 3- or 4-pyridyl group. The above defined novel heterocyclic compounds of formula (I) exhibit powerful insecticidal properties.

公开(公告)号：US5290779A

公开(公告)日：1994-03-01

申请号：US998337

申请日：1992-12-30

申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

IPC分类号： A01N43/90 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D498/04 ,  C07D513/04 ,  A61K31/505

CPC分类号： A01N43/90 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D513/04

摘要： Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-aom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a xeto group. Such compounds being useful as insecticides.

摘要翻译： 硝基取代的式（I）的杂环化合物其中R是氢或烷基，Z是任选取代的芳基或含有至少一个选自N，O和S的原子的任选取代的杂环化合物，A是 任选取代的乙烯或任选取代的三亚甲基，B代表杂环的2或3个成员，其与相邻的C原子和N-aom一起形成，并且所述成员中的至少一个可以表示杂原子，并且可以是 任选取代，条件是当B代表3个成员时，其中两个是碳原子，另一个是位于三个成员中间的氮原子，则所述两个碳原子中的至少一个必须被 一个xeto组。 这些化合物可用作杀虫剂。