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1.发明申请公开(公告)号：US20100018900A1
公开(公告)日：2010-01-28
申请号：US12179542
申请日：2008-07-24
IPC分类号： C10G35/02
CPC分类号： C10G35/04
摘要： One exemplary embodiment can be a process for producing a reformate by combining a stream having an effective amount of n-butane and a stream having an effective amount of naphtha for reforming. Generally, the naphtha has not less than about 95%, by weight, of one or more compounds having a boiling point of about 38—about 260° C. as determined by ASTM D86-07. The process can include introducing the combined stream to a reforming reaction zone. Typically, the combined stream has an n-butane:naphtha mass ratio of about 0.10:1.00—about 1.00:1.00.
摘要翻译： 一个示例性实施方案可以是通过将具有有效量的正丁烷的流和具有有效量的石脑油的流组合用于重整来生产重整产品的方法。 通常，根据ASTM D86-07测定，石脑油具有不小于约95重量％的一种或多种沸点为约38-约260℃的化合物。 该方法可以包括将组合的流引入重整反应区。 通常，组合物流的正丁烷：石脑油质量比为约0.10:1.00-约1.00:1.00。
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2.发明申请公开(公告)号：US20090326295A1
公开(公告)日：2009-12-31
申请号：US12552682
申请日：2009-09-02
申请人： STEVEN L. KRUPA , JILL M. MEISTER
发明人： STEVEN L. KRUPA , JILL M. MEISTER
CPC分类号： C07C5/2506 , C07C2/08 , C07C2/14 , C07C6/04 , C07C7/163 , C07C11/02 , C07C11/06 , C10G2300/1092 , C10G2400/20 , C10G2400/22 , C07C11/08
摘要： Disclosed is a process for integrating a butene dimerization process with a metathesis process to remove isobutene from the feed stream to the metathesis reactor. The isobutene is preferentially dimerized in the dimerization process to leave n-butenes for metathesis with ethylene. An upstream selective hydrogenation process also isomerizes 1-butenes to 2-butenes which is the preferred butene reagent in the metathesis process. A common fractionator column for the dimerization and hydrogenation processes is also described.
摘要翻译： 公开了一种将丁烯二聚过程与复分解方法结合以将异丁烯从进料流中除去至复分解反应器的方法。 异二烯在二聚过程中优先被二聚化，以留下正丁烯用于与乙烯复分解。 上游选择性氢化方法还将1-丁烯异构化为2-丁烯，其为复分解过程中优选的丁烯试剂。 还描述了用于二聚和氢化方法的普通分馏塔。
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公开(公告)号：US6107526A
公开(公告)日：2000-08-22
申请号：US99163
申请日：1998-06-18
CPC分类号： C07C41/42 , C07C41/06 , Y02P20/127
摘要： A catalytic distillation process for producing high purity ethyl tertiary butyl ether that contains less than 0.6 weight percent ethanol, and preferably less than 0.07 weight percent ethanol, has been developed. The high purity ethyl tertiary butyl ether is withdrawn directly from a catalytic distillation column; no downstream processing is necessary to remove excess ethanol from the ether product. A stream containing largely normal butane is generated by a C.sub.4 distillation column along with a stream containing isobutane. The stream containing isobutane is dehydrogenated to form a stream containing isobutylene. Ethanol, the stream containing isobutylene, and the stream containing largely normal butane are introduced to an etherification zone containing a catalytic distillation column. The catalytic distillation column is operated under conditions which result in the reaction of the ethanol with the isobutylene to form ethyl tertiary butyl ether. Excess ethanol forms an azeotrope with the normal butane and is distilled with other hydrocarbons into an overhead stream. The ethyl tertiary butyl ether and no more than 0.6 weight percent ethanol are distilled into a bottoms stream and withdrawn directly from the catalytic distillation column.
摘要翻译： 已经开发了用于生产含有小于0.6重量％乙醇，优选小于0.07重量％乙醇的高纯度乙基叔丁基醚的催化蒸馏方法。 高纯度乙基叔丁基醚直接从催化蒸馏塔中取出; 不需要下游处理来从醚产物中除去过量的乙醇。 含有大量正丁烷的料流是由C4蒸馏塔和含有异丁烷的料流产生的。 含有异丁烷的物流被脱氢以形成含有异丁烯的物流。 将含有异丁烯的物流和含有大量正丁烷的物流引入含有催化蒸馏塔的醚化区。 催化蒸馏塔在乙醇与异丁烯反应形成乙基叔丁基醚的条件下运行。 过量的乙醇与正丁烷形成共沸物，并与其他烃一起蒸馏成塔顶物流。 将乙基叔丁基醚和不超过0.6重量％的乙醇蒸馏到塔底物流中，直接从催化蒸馏塔中取出。
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公开(公告)号：US07459593B1
公开(公告)日：2008-12-02
申请号：US11283353
申请日：2005-11-18
申请人： Steven L. Krupa , Jill M. Meister
发明人： Steven L. Krupa , Jill M. Meister
CPC分类号： C07C5/2506 , C07C2/08 , C07C2/14 , C07C6/04 , C07C7/163 , C07C11/02 , C07C11/06 , C10G2300/1092 , C10G2400/20 , C10G2400/22 , C07C11/08
摘要： Disclosed is a process for integrating a butene dimerization process with a metathesis process to remove isobutene from the feed stream to the metathesis reactor. The isobutene is preferentially dimerized in the dimerization process to leave n-butenes for metathesis with ethylene. An upstream selective hydrogenation process also isomerizes 1-butenes to 2-butenes which is the preferred butene reagent in the metathesis process. A common fractionator column for the dimerization and hydrogenation processes is also described.
摘要翻译： 公开了一种将丁烯二聚过程与复分解方法结合以将异丁烯从进料流中除去至复分解反应器的方法。 异二烯在二聚过程中优先被二聚化，以留下正丁烯用于与乙烯复分解。 上游选择性氢化方法还将1-丁烯异构化为2-丁烯，其为复分解过程中优选的丁烯试剂。 还描述了用于二聚和氢化方法的普通分馏塔。
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5.发明授权
公开(公告)号：US5990361A
公开(公告)日：1999-11-23
申请号：US99162
申请日：1998-06-18
CPC分类号： C07C41/42 , C07C41/06 , Y02P20/127
摘要： A low pressure catalytic distillation process for producing high purity ethyl tertiary butyl ether that contains less than 0.6 weight percent ethanol, and preferably less than 0.07 weight percent ethanol, has been developed. The high purity ethyl tertiary butyl ether is withdrawn directly from a catalytic distillation column. No downstream processing is necessary to remove excess ethanol from the ether product. A stream containing a significant amount of one or more inert azeotropic agents such as normal butane, isopentane, and isobutane is introduced along with the isobutylene and ethanol reactants into an etherification zone containing a catalytic distillation column. The catalytic distillation column is operated under low pressure conditions which result in the reaction of the ethanol with the isobutylene to form ethyl tertiary butyl ether. The inert azeotropic agent must be present at the inlet to the catalytic distillation column in an amount sufficient to azeotrope excess ethanol and cause the excess ethanol to distill into an overhead stream under the conditions of operation. The preferred azeotropic agent is isopentane. Excess ethanol forms an azeotrope with the azeotropic agent and is distilled with other hydrocarbons into an overhead stream. The ethyl tertiary butyl ether and no more than 0.6 weight percent ethanol are distilled into a bottoms stream and withdrawn directly from the catalytic distillation column.
摘要翻译： 已经开发了用于生产含有小于0.6重量％乙醇，优选小于0.07重量％乙醇的高纯度乙基叔丁基醚的低压催化蒸馏方法。 高纯度乙基叔丁基醚直接从催化蒸馏塔中取出。 不需要下游处理来从醚产物中除去过量的乙醇。 将含有大量一种或多种惰性共沸剂如正丁烷，异戊烷和异丁烷的物流与异丁烯和乙醇反应物一起引入含有催化蒸馏塔的醚化区。 催化蒸馏塔在低压条件下运行，导致乙醇与异丁烯的反应形成乙基叔丁基醚。 惰性共沸剂必须以足以共沸过量乙醇的量存在于催化蒸馏塔的入口处，并使得过量的乙醇在操作条件下蒸馏成塔顶物流。 优选的共沸剂是异戊烷。 过量的乙醇与共沸剂形成共沸物，并与其他烃一起蒸馏成塔顶馏出物。 将乙基叔丁基醚和不超过0.6重量％的乙醇蒸馏到塔底物流中，直接从催化蒸馏塔中取出。
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公开(公告)号：US07601309B2
公开(公告)日：2009-10-13
申请号：US12263879
申请日：2008-11-03
申请人： Steven L. Krupa , Jill M. Meister
发明人： Steven L. Krupa , Jill M. Meister
CPC分类号： C07C5/2506 , C07C2/08 , C07C2/14 , C07C6/04 , C07C7/163 , C07C11/02 , C07C11/06 , C10G2300/1092 , C10G2400/20 , C10G2400/22 , C07C11/08
摘要： Disclosed is a process for integrating a butene dimerization process with a metathesis process to remove isobutene from the feed stream to the metathesis reactor. The isobutene is preferentially dimerized in the dimerization process to leave n-butenes for metathesis with ethylene. An upstream selective hydrogenation process also isomerizes 1-butenes to 2-butenes which is the preferred butene reagent in the metathesis process. A common fractionator column for the dimerization and hydrogenation processes is also described.
摘要翻译： 公开了一种将丁烯二聚过程与复分解方法结合以将异丁烯从进料流中除去至复分解反应器的方法。 异二烯在二聚过程中优先被二聚化，以留下正丁烯用于与乙烯复分解。 上游选择性氢化方法还将1-丁烯异构化为2-丁烯，其为复分解过程中优选的丁烯试剂。 还描述了用于二聚和氢化方法的普通分馏塔。
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7.发明授权公开(公告)号：US08753503B2
公开(公告)日：2014-06-17
申请号：US12179524
申请日：2008-07-24
IPC分类号： C10G35/00
CPC分类号： C10G35/04
摘要： One exemplary embodiment can be a process for producing a reformate by combining a stream having an effective amount of isopentane and a stream having an effective amount of naphtha for reforming. Generally, the naphtha has not less than about 95%, by weight, of one or more compounds having a boiling point of about 38-about 260° C. as determined by ASTM D86-07. The process may include introducing the combined stream to a reforming reaction zone. The combined stream can have an isopentane:naphtha mass ratio of about 0.10:1.00-about 1.00:1.00.
摘要翻译： 一个示例性实施方案可以是通过将具有有效量的异戊烷的物流和具有有效量的石脑油的物流混合以重整来生产重整产品的方法。 通常，根据ASTM D86-07测定，石脑油具有不小于约95重量％的一种或多种沸点为约38-约260℃的化合物。 该方法可以包括将组合的流引入重整反应区。 合并的流可以具有约0.10:1.00-约1.00:1.00的异戊烷：石脑油质量比。
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公开(公告)号：US08193111B2
公开(公告)日：2012-06-05
申请号：US12509182
申请日：2009-07-24
IPC分类号： B01J38/56 , B01J38/04 , B01J38/42 , C10M175/00 , C07C5/05
CPC分类号： C07C2/56 , B01J20/18 , B01J20/3408 , B01J20/3458 , B01J2220/56
摘要： One exemplary embodiment can be a process for desorbing an adsorbent bed. The process can include passing a desorbent stream through the adsorbent bed to remove at least one of a nitrile compound and an oxygenate compound. Generally, the desorbent stream after desorbing is combined with a feed stream for an alkylation zone after a selective hydrogenation zone.
摘要翻译： 一个示例性实施方案可以是用于解吸吸附剂床的方法。 该方法可以包括使解吸剂流通过吸附床以除去腈化合物和含氧化合物中的至少一种。 通常，解吸后的解吸流与选择氢化区之后的烷基化区的进料流合并。
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9.发明申请公开(公告)号：US20100018899A1
公开(公告)日：2010-01-28
申请号：US12179524
申请日：2008-07-24
IPC分类号： C10G35/00
CPC分类号： C10G35/04
摘要： One exemplary embodiment can be a process for producing a reformate by combining a stream having an effective amount of isopentane and a stream having an effective amount of naphtha for reforming. Generally, the naphtha has not less than about 95%, by weight, of one or more compounds having a boiling point of about 38—about 260° C. as determined by ASTM D86-07. The process may include introducing the combined stream to a reforming reaction zone. The combined stream can have an isopentane:naphtha mass ratio of about 0.10:1.00—about 1.00:1.00.
摘要翻译： 一个示例性实施方案可以是通过将具有有效量的异戊烷的物流和具有有效量的石脑油的物流混合以重整来生产重整产品的方法。 通常，根据ASTM D86-07测定，石脑油具有不小于约95重量％的一种或多种沸点为约38-约260℃的化合物。 该方法可以包括将组合的流引入重整反应区。 合并的流可以具有约0.10:1.00-约1.00:1.00的异戊烷：石脑油质量比。
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公开(公告)号：US20090062589A1
公开(公告)日：2009-03-05
申请号：US12263879
申请日：2008-11-03
申请人： Steven L. Krupa , Jill M. Meister
发明人： Steven L. Krupa , Jill M. Meister
CPC分类号： C07C5/2506 , C07C2/08 , C07C2/14 , C07C6/04 , C07C7/163 , C07C11/02 , C07C11/06 , C10G2300/1092 , C10G2400/20 , C10G2400/22 , C07C11/08
摘要： Disclosed is a process for integrating a butene dimerization process with a metathesis process to remove isobutene from the feed stream to the metathesis reactor. The isobutene is preferentially dimerized in the dimerization process to leave n-butenes for metathesis with ethylene. An upstream selective hydrogenation process also isomerizes 1-butenes to 2-butenes which is the preferred butene reagent in the metathesis process. A common fractionator column for the dimerization and hydrogenation processes is also described.
摘要翻译： 公开了一种将丁烯二聚过程与复分解方法结合以将异丁烯从进料流中除去至复分解反应器的方法。 异二烯在二聚过程中优先被二聚化，以留下正丁烯用于与乙烯复分解。 上游选择性氢化方法还将1-丁烯异构化为2-丁烯，其为复分解过程中优选的丁烯试剂。 还描述了用于二聚和氢化方法的普通分馏塔。
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