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公开(公告)号：US20060178539A1
公开(公告)日：2006-08-10
申请号：US10549140
申请日：2004-03-20
IPC分类号： C07C31/18
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is brought into contact in the presence of hydrogen with a shaped article which can be produced in a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and at least one of the oxides of lanthanum, tungsten, molybdenum, titanium or zirconium is prepared, (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to a shaped article.
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公开(公告)号：US06828464B2
公开(公告)日：2004-12-07
申请号：US10718795
申请日：2003-11-24
IPC分类号： C07C4554
CPC分类号： B01J23/04 , C07C45/48 , Y02P20/582 , C07C49/597
摘要： The present invention provides a process for preparing 2-cyclopentenones of the general formula: where R1 to R4 are each hydrogen atoms or are alkyl or alkenyl radicals having from 1 to 12 carbon atoms, cycloalkyl or cycloalkenyl radicals having from 5 to 7 carbon atoms, aralkylene or aryl radicals, by converting hexenedioic acids and/or their esters of the general formulae where R1 to R4 are each as defined above and R5 and R6 are each hydrogen atoms or are alkyl radicals having from 1 to 12 carbon atoms, cycloalkyl radicals having 5 or 6 carbon atoms, aralkyl or aryl radicals, at temperatures of from 150 to 450° C., over solid, oxidic catalysts, wherein the catalysts on an oxidic support material comprise from 0.01 to 5% by weight of at least one alkali metal oxide.
摘要翻译： 本发明提供一种制备以下通式的2-环戊烯酮的方法：其中R 1至R 4各自为氢原子或具有1至12个碳原子的烷基或烯基，环烷基或环烯基具有 5-7个碳原子的亚芳基或芳基，通过将通式R 1至R 4的通式所示的己烯二酸和/或它们的酯各自如上所定义，R 5和R 6各自为 氢原子或具有1至12个碳原子的烷基，具有5或6个碳原子的环烷基，芳烷基或芳基，在150-450℃的温度下，在固体，氧化催化剂上，其中催化剂在 氧化载体材料包含0.01至5重量％的至少一种碱金属氧化物。
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公开(公告)号：US07884046B2
公开(公告)日：2011-02-08
申请号：US12608125
申请日：2009-10-29
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.
摘要翻译： 氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在成型制品存在下氢化，所述成型制品包含（i）包含氧化铜，氧化铝和氧化镧的氧化物质和（ii ）粉末状金属铜，铜薄片，水泥粉末，石墨或其混合物。
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公开(公告)号：US07663003B2
公开(公告)日：2010-02-16
申请号：US11937537
申请日：2007-11-09
IPC分类号： B01J23/70 , B01J23/00 , C07C27/04 , C07C27/00 , C07C305/00
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is brought into contact in the presence of hydrogen with a shaped article which can be produced in a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and at least one of the oxides of lanthanum, tungsten, molybdenum, titanium or zirconium is prepared, (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to a shaped article.
摘要翻译： 氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在氢气存在下与成形制品接触，成形制品可以在以下工艺中制备，其中（i）包含铜的氧化物质 氧化物，氧化铝和镧，钨，钼，钛或锆的氧化物中的至少一种，（ii）将粉末状金属铜，铜片，粉末状水泥，石墨或其混合物加入氧化物中， （iii）由（ii）得到的混合物成型为成型制品。
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公开(公告)号：US07510591B2
公开(公告)日：2009-03-31
申请号：US10549140
申请日：2004-03-20
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is brought into contact in the presence of hydrogen with a shaped article which can be produced in a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and at least one of the oxides of lanthanum, tungsten, molybdenum, titanium or zirconium is prepared, (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to a shaped article.
摘要翻译： 氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在氢气存在下与成形制品接触，成形制品可以在以下工艺中制备，其中（i）包含铜的氧化物质 氧化物，氧化铝和镧，钨，钼，钛或锆的氧化物中的至少一种，（ii）将粉末状金属铜，铜片，粉末状水泥，石墨或其混合物加入氧化物中， （iii）由（ii）得到的混合物成型为成型制品。
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公开(公告)号：US20080064882A1
公开(公告)日：2008-03-13
申请号：US11937537
申请日：2007-11-09
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is brought into contact in the presence of hydrogen with a shaped article which can be produced in a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and at least one of the oxides of lanthanum, tungsten, molybdenum, titanium or zirconium is prepared, (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to a shaped article.
摘要翻译： 氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在氢气存在下与成形制品接触，成形制品可以在以下工艺中制备，其中（i）包含铜的氧化物质 氧化物，氧化铝和镧，钨，钼，钛或锆的氧化物中的至少一种，（ii）将粉末状金属铜，铜片，粉末状水泥，石墨或其混合物加入氧化物中， （iii）由（ii）得到的混合物成型为成型制品。
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7.发明申请Catalyst and method for producing alcohol by hydrogenation on said catalyst 审中-公开在所述催化剂上通过氢化制备醇的催化剂和方法公开(公告)号：US20060030743A1
公开(公告)日：2006-02-09
申请号：US10534457
申请日：2003-11-06
申请人： Markus Schubert , Sylvia Huber-Dirr , Michael Hesse , Jochen Pfeifer , Rolf-Hartmuth Fischer , Markus Rosch , Nils Bottke , Alexander Weck , Gunther Windecker , Gunnar Heydrich
发明人： Markus Schubert , Sylvia Huber-Dirr , Michael Hesse , Jochen Pfeifer , Rolf-Hartmuth Fischer , Markus Rosch , Nils Bottke , Alexander Weck , Gunther Windecker , Gunnar Heydrich
IPC分类号： B01J23/656 , C07C29/14 , C07C29/136
CPC分类号： C07C29/149 , B01J23/6567 , B01J37/0205 , C07B41/02 , C07C29/177 , C07C31/207 , C07C31/20
摘要： The invention relates to a catalyst containing from 0.1 to 20 mass % rhenium and 0.05 to 10 mass % platinum in relation to the total mass thereof. The inventive method for producing a support for said catalyst consists in a) treating a support which can be eventually pre-treated with the aid of a solution of rhenium compound, b) drying and annealing said support at a temperature ranging from 80 to 600° C., and c) impregnating the support with a solution of platinum compound and in drying it. The inventive method for producing alcohol by catalytic hydrogenation of carbonyl compound on said catalyst is also disclosed.
摘要翻译： 本发明涉及相对于其总质量含有0.1〜20质量％铼和0.05〜10质量％铂的催化剂。 用于制备所述催化剂载体的本发明方法在于：a）处理可以最终借助铼化合物溶液预处理的载体，b）在80至600℃的温度下干燥和退火所述载体 C.和c）用铂化合物溶液浸渍载体并干燥。 还公开了通过催化氢化羰基化合物在所述催化剂上生产醇的本发明方法。
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公开(公告)号：US20100056364A1
公开(公告)日：2010-03-04
申请号：US12608125
申请日：2009-10-29
IPC分类号： B01J21/18
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.
摘要翻译： 氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在成型制品存在下氢化，所述成型制品包含（i）包含氧化铜，氧化铝和氧化镧的氧化物质和（ii ）粉末状金属铜，铜薄片，水泥粉末，石墨或其混合物。
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